Two new diterpenes from Euphorbia kansuensis

Two new lathyrane diterpenes, 3 beta,5 alpha-dihydroxy-15 beta-cinnamonyloxy-14-oxoladiyra-6Z, 12E- diene (1) and 3 beta,5 alpha,20-trihydroxy-15 beta-cinnamoyloxy-14-oxolathyra-6Z, 12E-diene (2), were isolated from the roots of Euphorbia kansuensis. Their structures were determined by spectroscopic methods. (C) 2008 Elsevier B.V. All rights reserved.

Electric field-induced conformational transition of bovine serum albumin from alpha-helix to beta-sheet

The irreversible conformational transition of bovine serum albumin (BSA) from alpha-helix to beta-sheet, induced by electric field near the electrode surface, was monitored by circular dichroism (CD) with a long optical path thin layer cell (LOPTLC).

5,7-Dihydroxy-5,6,7,8-tetrahydro-1H-azocin-2-one from a marine-derived Streptomyces sp.

In the course of a screening program, we have isolated the new natural product, 5,7-dihydroxy-5,6,7,8-tetrahydroazocin-2(IH)-one (1), from the staurosporine producing marine-derived Streptomyces sp. strain QD518. Here we report the isolation and structure elucidation of 1 and the artifacts 3 and 4 resulting from I by acid catalyzed intra- and inter-molecular reactions.

SYNTHESIS AND CHARACTERIZATION OF ALPHA,BETA-TRIINDIUM SUBSTITUTED HETEROPOLYTUNGSTATES

The complexes of alpha,beta-K(a)H(b)XW(9)O(37)(InH2O)(3) . xH(2)O (X = Si, Ge; a+b = 7) were synthesized from their lacunary precursors alpha,beta-XW(9)O(34)(10-) (X = Si, Ge) and characterized by elemental analysis, W-183 NMR, IR and UV spectroscopy and polarography. W-183 NMR spectra of the title complexes consist of two lines with intensity ratio 2:1, as expected for the C-3 nu structure of trisubstituted A alpha- and A beta-Keggin anions.

Chemical Constituents of a Marine-Derived Endophytic Fungus Penicillium commune G2M

Cultivation of the endophytic fungus Penicillium commune, which was isolated from the semi-mangrove plant Hibiscus tiliaceus, afforded one new compound 1-O-(2,4-dihydroxy-6-methylbenzoyl)-glycerol (1) along with thirteen known products, including 1-O-acetylglycerol (2), N-acetyltryptophan (3), 3-indolylacetic acid methyl ester (4), 1-(2,4-dihydroxy-3,5-dimethylphenyl)ethanone (5), 2-(2,5-dihydroxyphenyl)acetic acid (6), (4R,5S)-5-hydroxyhexan-4-olide (7), thymidine (8), uracil (9), thymine (10), ergosterol (11), beta-sitosterol (12), beta-daucosterol (13), and ergosta-7,22-dien-3 beta,5 alpha,6 beta-triol (14). The structures of these compounds were established by detailed NMR spectroscopic analysis, as well as by comparison with literature data or with authentic samples.

Vc二步发酵新组合菌系B_(15-14)的筛选及其条件优化

筛选出了一组Vc二步发酵的新组合菌系(命名为B15-14),研究了环境因子对新菌系产酸的影响。结果显示:新组合菌系的最适底糖浓度为7%;温度为29~33℃,31℃为最适;适当增加通气量(20~30 mL装液量,250 mL三角瓶)有利于产酸;起始pH值范围为6.0~7.5;以B t菌做伴生菌时,发酵40 h就已达到终点,明显缩短了发酵时间。

Structure characterization and physical properties of a complex with supramolecular architectures Co-2(2,6-DPC2Co(H2O)5 center dot 2H(2)O (DPC=2,6-pyridinedicarboxylate)

Reaction of 2,6-pyridinedicarboxylic with CoCl2 . 6H(2)O in aqueous solution give rise to a three-dimensional Complex CO2(2,6-DPC)(2)Co(H2O)(5).2H(2)O (DPC = 2,6-pyridinedicarboxylate) 1. It has been characterized by elemental analyses, infrared spectra (IR) spectrum, thermogravimetric (TG) analysis, EPR spectrum, and single crystal X-ray diffraction. The complex crystallizes in the P2(1)/c space group with a = 8.3906(3) Angstrom, b = 27.4005(8) Angstrom, c = 9.6192(4) A, alpha = 90.00degrees, beta = 98.327(2)degrees, gamma = 90.00degrees, V = 2188.20(14) Angstrom(3), Z = 4. There are two types of cobalt environments: Co(1) is coordinated by four oxygen atoms from four carboxyl groups and two nitrogen 2 atoms which are all from pdc(2). Co(2) is coordinated by six oxygen atoms, five from coordinated water molecules and one from a carboxyl of pdc(2) - of which the other oxygen atom is linked to the Co(1). The extensive intermolecular hydrogen bonds are formed in the crystal by means of the five coordinated water molecules.

Three new diterpenoids from Euphorbia wallichii

Three new abietane diterpene lactones, 3alpha-hydroxyjolkinolide A (1), ent-8alpha,14beta-dihydroxy-13(15)-ene-16(12alpha)-abietanolide (2) and ent-8alpha,14alpha-dihydroxy-13(15)-ene-16(12alpha)-abietanolide (3) as well as a known abietane diterpene jolkinolide A (4) were isolated from the roots of Euphorbia wallichii. Their structures were elucidated on the basis of spectroscopic analysis.

理性力学基础

《理性力学基础》为《中国科学院研究生教学丛书》之一。
    《理性力学基础》系统地介绍了理性力学的主要科学体系和基本理论。《理性力学基础》由四部分，共十五章组成。第一部分综合介绍了理性力学的科学意义、方法和特点，从理性力学角度概括论述变形几何学与运动学、力学基本定律与场方程以及本构方程的一般原理。着重阐明张量和场方程的时空无差异原理，以及本构方程所应遵循的客观性原理。第二部分着重介绍简单物质的理论体系。作为典型范例进一步阐明弹性物质和简单流体的本构方程以及弹性体有限变形边值问题的分析方法。第三部分详细介绍黏弹性物质、弹塑性物质及晶体塑性的基本理论。第四部分主要介绍含缺陷物质的本构理论。
    《理性力学基础》可作为力学、应用数学、理论物理等专业的研究生教材，也可供力学工作者及高等院校力学专业教师参考。

目录 

第一章 绪论
1·1 理性力学目的和意义
1·2 理性力学的特点与体系
1·3 理性力学的方法
1·4 符号
第二章 变形几何学和运动学
2·1 直角坐标系的张量
2·2 物体的构形与运动
2·3 变形梯度
2·4 应变度量和面元、体元变形
2·5 应变率
第三章 基本定律与场方程
3·1 质量守恒定律
3·2 应力原理与动量守恒定律
3·3 能量守恒定律和熵定律
3·4 功共轭与应力度量
3·5 场方程
3·6 随体坐标系
第四章 本构方程的一般原理
4·1 时空系的变换
4·2 基本定律的客观性
4·3 本构方程的一般原理
第五章 简单物质
5·1 张量函数
5·2 张量函数表示定理
5·3 简单物质的本构方程
5·4 本构方程的简化形式
5·5 各向同性物质
5·6 简单固体
5·7 简单流体和流晶
5·8 内部约束
5·9 特殊类型物质
5·10 衰退记忆
第六章 弹性物质
6·1 弹性物质的本构方程
6·2 物质对称性
6·3 各向同性弹性固体
6·4 超弹性物质
6·5 各向同性超弹性物质
6·6 主轴表示
6·7 储能函数表示式
6·8 二次弹性
6·9 均匀变形场
6·10 储能函数的实验确定
第七章 弹性体有限变形边值问题
7·1 边值问题的提法
7·2 若干典型问题
7·3 平面应变问题
7·4 不可压缩各向同性弹性体
第八章 简单流体
8·1 直线流动
8·2 曲线流动
8·3 伸长历史恒定运动
8·4 定常测黏流动
8·5 Poiseuille流动
8·6 Couette流动
8·7 圆锥-平板流动
8·8 端部正应力效应
8·9 Stokes流体测黏流动
8·10 定常拉伸流动
第九章 黏弹性物质
9·1 线性黏弹性理论
9·2 非线性黏弹性固体
9·3 本构泛函展开
9·4 非线性黏弹性流体
第十章 弹塑性物质
10·1 微小变形塑性理论
10·2 张量的时间导数
10·3 有限塑性变形的本构方程
10·4 塑性大变形基本方程
10·5 Drucker公设与有限塑性变形
第十一章 晶体塑性理论
11·1 晶体塑性变形运动学
11·2 硬化规律
11·3 硬化系数表示式
11·4 晶体塑性本构关系
11·5 滑移剪切率γ(α)的存在性与惟一性
11·6 率相关流动规律
第十二章 缺陷连续统的线性理论
12·1 张量场的微分运算
12·2 协调条件
12·3 缺陷的几何意义
12·4 位错弹性理论
12·5 位错塑性理论
12·6 一般缺陷塑性理论
12·7 晶体塑性位错理论
12·8 Nye张量及缺陷塑性理论小结
12·9 位错塑性理论二维公式及算例
第十三章 非黎曼几何及流形简介
13·1 Euler空间张量场的绝对微分
13·2 曲率张量
13·3 线性空间
13·4 仿射联络空间
13·5 非完整变换
13·6 拓扑空间
13·7 微分流形
第十四章 缺陷连续统的非线性理论
14·1 非Niemann物质流形的构造
14·2 缺陷的几何意义
14·3 缺陷连续统的弹性理论
14·4 缺陷连续统的塑性理论
14·5 晶体塑性位错理论
第十五章 理性力学若干应用
15·1 有限变形的精确描述
15·2 曲线坐标的相应公式
15·3 本构方程的客观性原理
15·4 物质对称性
15·5 主轴法
15·6 客观应力率
附录 曲线坐标
1 基向量与度量张量
2 逆变导数
3 应力张
4 运动方程

 

Growth of beta barium borate (beta-BaB2O4) thin films on alpha barium borate (alpha-BaB2O4) substrates

Crystalline beta-BBO thin films have been successfully prepared on (001)-oriented Sr2+-doped alpha-BBO substrates using liquid phase epitaxy and pulsed laser deposition techniques. The films were characterized by X-ray diffraction and X-ray rocking curve (XRC). The present results manifest that the beta-BBO thin films grown on Sr2+-doped alpha-BBO substrates have larger degree of orientation f-value and smaller XRC FWHM than the ones grown on other reported substrates. Compared with other substrates, alpha-BBO has the same UV cutoff and the similar structure to beta-BBO. These results reveal that alpha-BBO single crystal may be a promising substrate proper to the growth of beta-BBO films. (c) 2005 Elsevier B.V. All rights reserved.

尖吻蝮蛇蛇毒出血毒素DaHT-3的纯化与性质

通过Sephadex G-75,DEAE-Sephadex A-50,Sephadex G-200和两次PBE聚焦层析,从尖吻蝮蛇(Dienagkistrodon acutus)蛇毒中纯化到一个分子量为56 000的出血毒素(DaHT-3),经氨基酸组成测定计算,由487个氨基酸残基组成。此成分在SDS-PAGE上显示出一条均一的蛋白染色带,用等电聚焦电泳测定,其pI为5.50。该出血成分的最小出血剂量是2.6#mu#g,具有蛋白水解酶活力,其活力为3.68,但没有精氨酸酯酶和磷脂酶A_(2)活力。用红外光谱仪研究DaHT-3在溶液中酰胺Ⅰ带的吸收谱,该毒素含有31.8%的#alpha#螺旋、56.1%的#beta#折叠和12.1%的转角;当加入EDTA螯合剂去除金属离子后,它们的#alpha#螺旋、#beta#折叠、转角和无规卷曲分别变为11%、26.4%、46.2%和16.5%,而出血活力和蛋白水解酶活力均丧失,表明该出血毒素是金属蛋白酶。

Synthesis, crystal structure, and magnetic properties of {[Cu(oxbe)]Mn(H2O)[Cu(oxbe)(DMF)]}(n)center dot nDMF center dot nH(2)O: From dissymmetrical mononuclear entities to a 3D heterometallic supramolecular coordination polymer

Self-assembly of the building block [Cu(oxbe)](-) with Mn(II) led to a novel coordination polymer {[Cu(oxbe)]Mn(H2O)(Cu(oxbe)(DMF)]}(n).nDMF.nH(2)O, where H(3)oxbe is a new dissymmetrical ligand N-benzoato-N'-(2-aminoethyl)-oxamido and DMF = dimethylformamide. The crystal forms in the triclinic system, space group P(1)over-bar, with a = 9.260(4) angstorm, b = 12.833(5) angstrom, c = 15.274(6) angstrom , alpha = 76.18(3)degrees, beta = 82.7(3)degrees, gamma = 82.31(3)degrees, and Z = 2. The crystal structure of the title complex reveals that the two-dimensional bimetallic layers are constructed of (CuMnII)-Mn-II-Cu-II chains linked together by carboxylate bridge and hydrogen bonds help to produce a novel three-dimensional channel-like structure. The magnetic susceptibility measurements (5-300 K) were analyzed by means of the Hamiltonian (H)over-cap = -2J(S)over-cap (Mn)((S)over-cap(Cu1) + (S)over-cap(Cu2)), leading to J = -17.4 cm(-1).

Electrode characteristics and microstructure of AB(2)-AB(5) composite hydrogen storage alloy formed by ball-milling process

For improving the electrode characteristics of the Zr-based AB(2)-type alloy, a new kind of composite hydrogen Zr0.9Ti0.1(Ni0.50Mn0.35V0.15)(2)(represented as AB(2)) with a rare storage alloy was successfully prepared by ball-milling I earth-based AB(5)-type alloy (represented as AB(5)) which worked as a surface modifier. Effects of ball-milling on the electrode characteristics and microstructure of Zr0.9Ti0.1(Ni0.50Mn0.35V0.15)(2) alloy and mixtures of AB(2) with AB(5) alloy were investigated. After milling the mixed AB(2) and AB(5) powders (9: 1 in mass ratio) for 10min, XRD and SEM analysis showed that AB(2) and AB(5) maintained their original crystalline states, respectively, some AB(5) particles were adhered onto the surface of AB(2), and some fresh surfaces were formed. It was found that the activation cycles of AB(2)-AB(5) composite alloy was shortened from 14 to 7 and the maximum discharge capacity was increased from 330mAh . g(-1) to 347mAh . g(-1) as compared with AB(2) alloy. The discharge rate capability of AB(2) alloy was also improved by ball milling AB(2) with AB(5) alloy process. The combined effect of ball-milling and mixing with AB(5) alloy is superior to that of sole treatment. It was believed that AB(5) alloy works not only as a regular hydrogen storage alloy, but also as a surface modifier to catalyze the hydriding/ dehydriding process of AB(2) alloy.

Novel hydrogen-bonded three-dimensional networks encapsulating one-dimensional covalent chains: [M(4,4 '-bipy)(H2O)4](4-abs)2 center dot nH(2)O (4,4 '-bipy=4,4 '-Bipyridine; 4-abs=4-aminobenzenesulfonate) (M=Co, n=1; M=Mn, n=2)

Two novel compounds, [Co(4,4'-bipy)(H2O)(4)](4-abS)(2).H2O (1) and [Mn(4,4'-bipy)(H2O)(4)](4-abs)(2).2H(2)O (2) (4,4'-bipy = 4,4'-bipyridine; 4-abs = 4-aminobenzenesulfonate), have been synthesized in aqueous solution and characterized by single-crystal X-ray diffraction, elemental analyses, UV-vis and IR spectra, and TG analysis. X-ray structural analysis revealed that 1 and 2 both possess unusual hydrogen-bonded three-dimensional (3-D) networks encapsulating one-dimensional (1-D) covalently bonded infinite [M(4,4'-bipy)(H2O)(4)](2+) (M = Co, Mn) chains. The 4-abs anions in 1 form 1-D zigzag chains through hydrogen bonds. These chains are further extended through crystallization water molecules into 3-D hydrogen-bonded networks with 1-D channels, in which the [Co(4,4'-bipy)(H2O)(4)](2+) linear covalently bonded chains are located. Crystal data for 1: C22H30CoN4O11S2, monoclinic P2(1), a = 11.380(2) Angstrom, b = 8.0274(16) Angstrom, c = 15.670(3) Angstrom, alpha = gamma = 90degrees, beta = 92.82(3)degrees, Z = 2. Compound 2 contains interesting two-dimensional (2-D) honeycomb-like networks formed by 4-abs anions and lattice water molecules via hydrogen bonding, which are extended through other crystallization water molecules into three dimensions with 1-D hexagonal channels. The [Mn(4,4'-bipy)(H2O)(4)](2+) linear covalent chains exist in these channels. Crystal data for 2: C22H32WN4O12S2, monoclinic P2(1)/c, a = 15.0833(14) Angstrom, b = 8.2887(4) Angstrom, c = 23.2228(15) Angstrom, alpha = gamma = 90degrees, beta = 95.186(3)degrees, Z = 4.

Morphology and structure of nylon-2,14 single crystals from dilute solution

A perfect single crystal of nylon-2,14 was prepared from 0.02% (w/v) 1,4-butanediol solution by a "self-seeding" technique and isothermal crystallization at 120 and 145 degreesC. The morphology and structure features were examined by transmission electron microscopy with both image and diffraction modes, atomic force microscopy, and wide-angle X-ray diffraction (WAXD). The nylon-2,14 single crystal grown from 1,4-butanediol at 145 degreesC inhabited a lathlike shape with a lamellar thickness of about 9 nm. Electron diffraction and WAXD data indicated that nylon-2,14 crystallized in a triclinic system with lattice dimensions a = 0.49 nm, b = 0.51 nm, c = 2.23 nm, alpha = 60.4degrees, beta = 77degrees, and gamma = 59degrees. The crystal structure is different from that of nylon-6,6 but similar to that of other members of nylon-2Y.