室温和350℃下注Mn的GaAs/AlGaAs超晶格的磁学性质

通过室温和350℃注Mn后热退火,在GaAs/AlGaAs超晶格中引入了不同的亚微米磁性颗粒.利用原子力显微镜、能量散射X射线谱、X射线衍射和交变梯度磁强计研究了该颗粒膜材料的结构和磁学性质.通过比较这些颗粒的饱和磁化强度、剩余磁化强度、矫顽力和剩磁比,发现350℃注Mn的样品含有MnGa和MnAs两种磁性颗粒,而室温注Mn的样品主要含有MnAs颗粒.

350-450nm范围的氧离子激发光谱的实验测量

在2×1.7串列加速器上,利用装有CCD的Spectrapro-500i光谱单色仪的测量装置,采用束-箔方法,在2 MeV束能下研究350-450 nm波长范围的离化态氧原子光谱。本文报道在350-450 nm范围已确定的182条光谱线,这些谱线大都属于O II到O IV原子的n、1能级间的跃迁的弱谱线。实验结果与现有的一些理论一致。实验发现,有28条谱线在以前的文献中没有报道。

Molybdenum L-shell X-ray production by 350-600 keV Xeq+ (q=25-30) ions

Molybdenum L-shell X-rays were produced by Xeq+ (q = 25-30) bombardment at low energies from 2.65 to 4.55 keV/amu (350-600 keV). We observed a kinetic energy threshold of Mo L-shell ionization down to 2.65-3.03 keV/amu (350-400 keV). The charge state effect of the incident ions was not observed which shows that the ions were neutralized, reaching an equilibrium charge state and losing their initial charge state memory before production of L-shell vacancies resulted in X-ray production. The experimental ionization cross sections were compared with those from Binary Encounter Approximation theory. Taking into account projectile deflection in the target nuclear Coulomb field, the ionization cross section of Mo L-shell near the kinetic energy threshold was well described. (C) 2010 Published by Elsevier B.V.

A new hydrometallurgical process for extracting rare earths from apatite using solvent extraction with P-350

In this paper, a new process is proposed to recover rare earths from nitric acid leaching of apatite without interfering with the normal route for fertilizer production using solvent extraction with dimethyl heptyl methyl phosphonate CH3P(O)(OC8H17)(2) (P-350, B). In the present work, the leaching conditions are studied. In selected condition, apatite was dissolved in 20% (v/v) nitric acid solution at 60-70 degrees C while agitating. The most suitable acidity for extraction is 0.4 M HNO3. More than 98% of rare earths in apatite can be recovered using countercurrent extraction process with six stages when phase ratio = 0.5, and defluorination is unnecessary. The influences of phase ratio, stage number, acidity and salting-out agent on extractabilities Of P-350 are studied. The results show that rare earths can be separated with P-350 from Ca, P, Fe and other impurities. Mixed rare earth oxides (REO) of which purity is more than 95% with yield over 98% can be obtained.

P_(350)从硝酸介质中萃取Nd(Ⅲ)的动力学研究

本文采用恒界面池法研究了诸因素对甲基磷酸二甲庚酯(P_(350))从硝酸体系中萃取Nd(Ⅲ)动力学的影响,求得反应的表观活化能为11.8kJ/mol,从实验结果推论出萃取过程为界面化学反应的控制机理,得出萃取反应速率方程,并提出中性磷氧萃取剂在萃取金属离子过程中可能存在阳离子交换反应机理。

海洋平台吸力式基础的研究与进展

吸力式基础平台是近年开发的一种新型海洋平台，由于多种优越性而受到各国石油部门的重视，并引起许多研究人员的关注。对有关吸力式基础的沉贯，稳定性以及与分析密切相关的冰激振动，土的动载下的本构研究进展进行了综述。并在最后针对海洋地区的条件提出了今后研究的重点问题。包括：沉贯阻力特性，动载下基础的软化特性和液化可能性，合适的土动力本构关系和数值方法，实验方法及模型律等。

Magnetic properties and magnetic domain structure of bulk glass forming Nd60Al10Fe20Co10 alloy

The transition from hard to soft magnetic behaviour with increasing quenching rate is shown for Nd60WAl10Fe20Co10 melt-spun ribbons with different thickness. Microstructure and magnetic domain structure of ribbons were studied by magnetic force microscopy (MFM). Particle sizes < 5 nm decreasing gradually with increasing quenching rate were deduced from topographic images which differ from large-scale magnetic domains with a periodicity of about 350 nm in all ribbons irrespective the coercivity. This indicates that the magnetic properties of the alloy are governed by interaction of small magnetic particles. It is concluded that the presence of short-range-ordered structures with a local ordering similar to the Al metastable Nd-Fe binary phase is responsible for the hard magnetic properties in samples subjected to relatively low quenching rate.

Formation Of Dendritic Nanostructures In Pyrex Glass Anodically Bonded To Silicon Coated With An Aluminum Thin Film

Anodic bonding with thin films of metal or alloy as an intermediate layer, finds increasing applications in micro/nanoelectromechanical systems. At the bonding temperature of 350 degrees C, voltage of 400 V, and 30 min duration, the anodic bonding is completed between Pyrex glass and crystalline silicon coated with an aluminum thin film with a thickness comprised between 50 and 230 nm. Sodium-depleted layers and dendritic nanostructures were observed in Pyrex 7740 glass adjacent to the bonding interface. The sodium depletion width does not increase remarkably with the thickness of aluminum film. The dendritic nanostructures result from aluminum diffusion into the Pyrex glass. This experimental research is expected to enhance the understanding of how the depletion layer and dendritic nanostructures affect the quality of anodic bonding. (C) 2007 Elsevier B.V. All rights reserved.