第3届全国复合材料学术会议

<正> 会议于1984年11月2—7日在杭州举行,由中国宇航学会、中国航空学会和中国力学学会共同主办,全国科研、设计、生产部门和大专院校13个学院87个单位的221名代表参加了会议,大会收到学术报告312篇,接受了182篇,会前即预印了论文集,120篇论文分别在材料工艺、性能测试与应用、静动态力学性能、结构设计分析以及金属基复合材料五个组

长白山北坡植物群落复杂性的海拔梯度变化(英文)

应用梯度格局法在长白山北坡海拔700m-2600m的坡面上每100 m海拔设置一样地,共计20块样地,通过对同一群落各样方间的相异性测定,对各海拔植物群落的复杂性进行了分析。结果表明,以主林层乔木种的二元数据计算的结果,除亚高山岳桦林外,其它各海拔群落的样方间均表现出较高的相异性,特别是低海拔的阔叶红松林平均相异系数达0.74,明显高于其它植被类型;暗针叶林各群落间差异不大,相对而言1400 m群落样方间的相异性略高于其它群落,表现出过渡性群落树种组成的复杂性;岳桦林树种组成简单,样[(\267\275\274\344\322\262\261\355\317\326\263\366\275\317\270\337\265\304\\317\340\313\306\320\324\241\243)-0.1(\322\324\271\340\304\276\326\326\265\304\266\376\324\252\312\375\276\335\\274\306\313\343\265\304\310\272)]落内的相异性,虽低海拔的阔叶红松林总体上高于其它群落,但差异趋势并不像乔木种那么明显。以各草本植物与所有植物种的二元数据计算的各海拔群落内样方间的相异性,表现出非常相近的趋势,群落内样方间草本植物及所有植物种均以阔叶红松林及高山冻原差异最大,暗针叶林基本稳定于比较相近的水平。图3表1参8。

Kinetics of extraction and stripping of y(III) by Cyanex 272 as an acidic extractant using a constant interfacial cell with laminar flow

The extraction and stripping kinetics of yttrium(III) with bis(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272, HA) dissolved in heptane as an acid extractant have been investigated by constant interfacial cell with laminar flow. The experimental hydrodynamic conditions have been chosen so that the contribution of diffusion to the measured rate of reaction is minimized. The plot of interfacial area on the rate has shown a linear relationship, which makes the interface the most probable local for the chemical reactions. At the same time, the extraction thermodynamic and kinetic methods are compared to determine the equilibrium extraction constant. A rate equation and the rate-determining step of the extraction and stripping of yttrium(III) have also been obtained, respectively.

Kinetics of ytterbium(III) extraction with Cyanex 272 using a constant interfacial cell with laminar flow

Studies have been made on the kinetics of ytterbium(III) with bis-(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272, HA) in n-heptane using a constant interfacial cell with laminar flow. The stiochiometry and the equilibrium constant of the extracted complex formation reaction between Yb3+ and Cyanex 272 are determined. The extraction rate is dependent of the stirring rate. This fact together with the Ea value suggests that the mass transfer process is a mixed chemical reaction-diffusion controlled at lower temperature, whereas it is entirely diffusion controlled at higher temperature. The rate equations for the ytterbium extraction with Cyanex 272 have been obtained. The rate-determining step is also made by predictions derived from interfacial reaction models, and through the approximate solutions of the flux equation, diffusion parameters and thickness of the diffusion film have been calculated.

Mass transfer kinetics of yttrium(III) using a constant interfacial cell with laminar flow. Part II. Extraction with Cyanex 272

The yttrium(III) extraction kinetics and mechanism with bis-(2,4,4-trimethyl-pentyl) phosphinic acid (Cyanex 272, HA) dissolved in heptane have been investigated by constant interfacial cell with laminar flow. The data has been analyzed in terms of pseudo-first order constants. Studies on the effects of stirring rate, temperature, acidity in aqueous phase, and extractant concentration on the extraction rate show that the extraction regime is dependent on the extraction conditions. The plot of interfacial area on the rate has shown a linear relationship. This fact together with the strong surface activity of Cyanex 272 at heptane-water interfaces has made the interface the most probable location for the chemical reactions. The forward, reverse rate equations and extraction rate constant for the yttrium extraction with Cyanex 272 have been obtained under the experimental conditions. The rate-determining step has been also predicted from interfacial reaction models. The predictions have been found to be in good agreement with the rate equations obtained from experimental data, confirming the basic assumption that the chemical reaction is located at the liquid-liquid interface.

Kinetics of Y(III) stripping for the system Y/HCl/Cyanex 272-P507/heptane with constant interfacial area cell with laminar flow

Kinetics and mechanism of stripping of yttrium(III) previously extracted by mixtures of bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272, HA), and 2-ethylhexyl phosphonic acid mono-2-ethylhexl ester (P507, HB) dissolved in heptane have been investigated by constant interfacial-area cell by laminar flow. The corresponding equilibrium stripping equation and equilibrium constant were obtained. The studies of effects of the stirring rate and temperature on the stripping rate show that the stripping regime is dependent on the stripping conditions. The plot of interfacial area on the rate has shown a linear relationship. This fact together with the strong surface activity of mixtures of Cyanex 272 and P507 at heptane-water interfaces makes the interface the most probable locale for the chemical reactions. The stripping rate constant is obtained, and the value is compared with that of the system with Cyanex 272 and P507 alone. It is concluded that the stripping ability with the mixtures is easier than that of P507 due to lower the activation energy of the mixtures. The stripping rate equation has also been obtained, and the rate-determining steps are the two-step interfacial chemical reactions as predicted from interfacial reaction models.

Synergistic extraction of zinc(II) with mixtures of CA-100 and cyanex 272

The extraction of zinc(II) from an aqueous chloride medium has been studied using mixtures of sec-nonylphenoxy acetic acid (CA-100) and bis(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272). The results demonstrate that zinc ion is extracted into heptane as ZnA(2).2HA with CA-100, ZnL2.2HL with Cyanex 272, and ZnA(2)L(2)H(2) with synergistic mixture. The equilibrium constants of the these species have been calculated and extraction mechanisms have been proposed. Thermodynamic parameters of the extraction process were determined by the temperature coefficient of extractability. The synergistic system enhances the extraction efficiency of zinc(II) and also improves the selectivity between zinc(II) and cadmium(II).

Extraction and separation of heavy rare earth (III) with Extraction Resin containing di(2,4,4-trimethyl pentyl) phosphinic acid (Cyanex 272)

Extraction resins, of the type of;levextrel, (which is a collective term for styrene/divinylbenzene based copolymers of predominantly macroporous structure that contain a selective extractant) are important for the recovery and separation of metal ions, as they combine features of solvent extraction and ion exchange resins. This paper presents the results of the adsorption of heavy rare earth ions (Ho(III), Er(III), Tm(III), Yb(III), Lu(III) and Y(III)) from hydrochloric acid solutions at 0.2 mol/L ionic strength and 50 degrees C by the extraction resin containing di (2,4,4-trimethyl pentyl) phosphinic acid (Cyanex 272) and the chromatographic separation of (Er(III), Tm(III) and Yb(III)). Technological separation products, with purity and yield of Tm2O3 >99.97%, >80%, Er2O3 >99.9%, >94% and Yb2O3 >99.8%, >80% respectively, have been obtained from a feed having the composition Tm2O3 60%, Er2O3 10%, and Yb2O3 3%, the others 27%. The distribution coefficients, extraction equilibrium constants and separation factors have been determined as a function of acidity, loading of the resin and rare earths, flow rates and column ratios. The resolutions and efficiencies of separation of Er/Tm/Yb each other have been calculated. The stoichiometry of the extraction of rare earth ions has been suggested as well.

铝粉快速反应光谱中AlOB~2Σ~＋→X~2Σ~＋发射光谱的研究

在由光学多道分析仪收集的氢氧气体爆轰激励下铝粉快速反应光谱中，观察到ＡｌＯＢ２Σ＋→Ｘ２Σ＋跃迁Δｖ＝０带系的光谱特征与通常铝氧化反应的光谱特征不同。经分析是因为存在一个从４６７ｎｍ开始向长波方增强的连续辐射，它改变了该波长区ＡｌＯ分子的辐射特征。这一连续辐射可能是由铝与水蒸汽发生水合反应生成，而处于不同激发态的多原子分子ＨＡｌＯＨ产生

用计算机技术标定测力传感器

本文提出用计算机技术标定压电测力传感器的方法。提高了标定精度,方便可靠地得到传感器的动态和静态性能,迅速处理大量标定数据;适于实验室中标定压电测力传感器。

剪切带状分叉的力学条件

在已论证过的应变软化效应对形成剪切带状分叉的作用的基础上,本文研究了:(1)什么受力情况最易激发剪切带(2)采用什么力学模型和参数可以模拟材料中的曲线型带状分叉。

后柱横向振动串列双圆柱尾迹特性

本文采用电化学显示方法和热线技术就雷诺数为10~2—10~3,后柱横向振动串列双圓柱尾迹和涡街进行了研究。双柱间距为1.5≤s/d≤10,后柱振动振幅为0.1d和0.3d。首先,本文得到了低雷诺数情况下,串列双圆柱绕流旋涡脱落频率随柱间距和雷诺数的变化规律。并且,通过流谱分析,对于出现频率间断现象给予了说明。其次,本文着重研究了振动情况下尾迹特性。当后柱以静止双柱涡脱落频率强迫振动,涡脱落和柱振动之间将发生联锁反应。本文实验揭示了联锁区奇特的涡街流谱——二次涡、涡的聚集和涡街伸长。