超重核~(294)118和~(291)116及其α衰变链上各核素半衰期的研究

运用推广的液滴模型(GLDM)确定了超重核294118和291116及其α衰变链上各核素的衰变势垒,采用量子力学中的WKB方法计算α衰变中的势垒穿透几率,对该链上各原子核的α衰变半衰期进行了研究。此外,还利用Royer公式对该链上各原子核的α衰变半衰期进行了计算。结果表明,GLDM考虑亲和能与Royer公式给出的α衰变半衰期与超重核区的实验值符合很好,验证了GLDM和Royer公式在超重核区的适用性,可以用来预测超重核的半衰期。最后,预言了Z=118和116同位素链上各核素的半衰期,结果表明,在Z=118和116中存在α衰变长寿命同位素,这需要实验上的检验。

Gound State Properties of Nuclei in (295)118 alpha-Decay Chain

The properties of nuclei belonging to the alpha-decay chain of superheavy element (295)118 have been studied in the framework of axially deformed relativistic mean field (RMF) theory with the parameter set of NL-Z2 in the blocked BCS approximation. Some ground state properties such as binding energies, deformations, and alpha-decay energies Q(alpha) have been obtained and agree well with those from finite-range droplet model (FRDM). The single-particle spectra of nuclei in (295)118 alpha-decay chain show that the shell gaps present obviously nucleon number dependence. The root-mean-square (rms) radii of proton, neutron and matter distributions change slowly from (283)112 to (295)118 but dramatically from (279)110 to (283)112, which may be due to the subshell closure at Z = 110 in (279)110. The alpha-decay half-lives in (295)118 decay chain are evaluated by employing the cluster model and the generalized liquid drop model (GLDM), and the overall agreement is found when they are compared with the known experimental data. The alpha-decay lifetimes obtained from the cluster model are slightly larger than those of GLDM ones. Finally, we predict the alpha-decay half-lives of Z = 118, 116, 114, 112 isotopes using the cluster model and GLDM, which also indicate these two models can corroborate each other in studies on superheavy nuclei. The results from GLDM are always lower than those obtained from the cluster model.

C-118 from fullerenols: Formation, structure and intermolecular nC(2) transfer reactions in mass spectrometry

In fast atom bombardment, two fullerenols C-60(OH)(x) (x=13-15) and C-60(OH)(x) (x-24-26) gave rise to a group of ions centered at C-118 with intervals of 24 mass units in the high mass region. In contrast, no such ions appeared in the mass spectra of pure C-60, C-70 and other fullerene derivatives such as C-60(C6H5)(10), under the same conditions. It is proposed that the pinacol rearrangement of C-60(OH)(2), resulting from partial rupture of the polyhydroxy molecules, produces C-59 with two carbon atoms bearing an unpaired electron, and that dimerization of this reactive intermediate is responsible for the formation of the predominant product C-118. An intermolecular nC(2) transfer process is used to explain the symmetrical abundance distribution of these product ions in the spectra of fullerenols.