~(17)B的晕结构特征

实验利用束流衰减法测量了43.7AMeV丰中子核17B与C靶反应的总截面σR=(1724±93)mb.用零程Glauber计算,假定17B具有核芯15B和两个价中子结构,输入GG和GO密度分布,计算的激发函数曲线与该实验数据很好符合,输入描述稳定核双参数Fermi密度分布,不能得到与实验数据符合的结果,表明17B是核芯15B+2n的假定是合理的.并且中子密度分布表现较大空间扩展-晕结构特征.

丰中子奇异核~(17)B的实验研究

在兰州重离子加速器国家实验室(HIRFL)放射性次级束流线(RIBLL)上,用束流透射法测量了丰中子奇异核17B与C靶反应的总截面.假定17B具有15B(核芯)+2n结构,采用Gauss+HO形式的密度分布和零力程Glauber模型进行计算的结果可以很好地拟合实验数据,并得出17B的密度分布有一个很大的弥散,表明17B是双中子晕核.

RIBLL1上的奇异核研究

概要介绍了兰州重离子加速器放射性次级束流线(RIBLL1)及其部分实验成果.25P的鉴别,发现9C,12N,14B,23Al反应总截面和密度分布增大,符合测量17B的核芯15B的γ能谱.

丰中子奇异核17B的实验研究

在兰州重离子加速器国家实验室(HIRFL)放射性次级束流线(RIBLL)上，用束流透射法测量了丰中子奇异核17B与C靶反应的总截面.假定17B具有15B(核芯)＋2n结构，采用Gauss＋HO形式的密度分布和零力程Glauber模型进行计算的结果可以很好地拟合实验数据，并得出17B的密度分布有一个很大的弥散，表明17B是双中子晕核.

17B的实验研究

核反应总截面是描述原子核反应基本特征的一个重要的物理量，从中可以得到有关核反应、核结构和核内核子分布的信息。利用透射法测量核的反应总截面对于模型没有依赖性，因而得到的结果更加可靠。在兰州放射性束流线（RIBLL）上利用透射法测量了17B与C、Pb靶的反应，得到了17B与C、Pb的反应总截面和去除双中子截面，同时首次尝试用CLOVER探测器测量与碎片符合的γ能谱。利用半经验的Shen公式可以很好地拟合稳定核的反应总截面的实验结果，但是并不能很好地描述17B的实验结果，说明17B具有奇异结构。采用描述不稳定核的多种密度分布形式代入零力程的Glauber模型计算17B与C的反应总截面，并与实验结果进行了比较。发现采用Skyrme－Hatree－Fock（SHF）、双Gauss、Gauss＋HO计算的密度分布形式都能够很好地拟合整个能区内的实验结果。通过各种密度分布形式提取了17B的核子密度分布，发现17B的中子密度分布有很大的弥散，并证实了17B是由核芯15B加两个价中子组成的晕结构。将Skyrme－Hatree－Fock（SHF）、双Gauss、Gauss＋HO密度分布形式，输入Glauber模型与实验结果比较，提取了17B的物质均方根半径，不同密度分布提取的均方根半径值在实验误差范围内一致，也进一步验证了17B的晕结构。采用Woods－Saxon势来描述17B核外的价中子在核芯中形成的势场，通过解薛定鄂方程来求解价中子处于特定轨道的波函数。假设17B核外的价中子处于纯的s分波和d分波都不能很好地和实验结果符合。所以认为核外的价中子应该是混合组态，通过拟合实验结果求解出s分波谱学因子的值，证明核外的价中子处在2s1/2轨道的几率更大

中国两种萤火虫荧光素酶基因的分子克隆表达及其序列分析

本文通过5’-RACE和3’-RACE方法克隆了西双版纳地区的卵黄萤Luciola ovalis和端黑萤Luciola terminalis两种荧光素酶基因。两个荧光素酶基因被连接到pET-15b载体上并在BL21(DE3)菌株中表达。L. ovalis荧光素酶基因的开放阅读框有1635个碱基，编码一个544个氨基酸的蛋白。L. terminalis荧光素酶基因有一个1647bp的开放阅读框，编码一个548个氨基酸的蛋白。它们的氨基酸序列和北美萤火虫(Photinus pyralis)的氨基酸序列分别有65.3%和65.9%的相似性，而彼此之间又有73.5%的相似性。两种在大肠杆菌中表达的荧光素酶均有很高的活性，它们的最大发光波长分别是566 nm和563 nm。同时表达的四种荧光素酶(L. ovalis、L. terminalis、Hotaria parvula和Pyrocoelia miyako)在不同pH下活性变化很大，四种荧光素酶在pH 6.5-7.5之间有比较高的活性，其中L. ovalis和P. miyako两种荧光素酶在pH 7.0时活性最高，而另两种在pH 7.5时活性最高。当pH大于8.0时，这四种荧光素酶的活性都散失很快，可见它们对pH变化非常敏感。序列分析和结构模拟发现，荧光素酶活性位点周围有六个非常保守的结构域，这六个保守区域包含了大多数在催化发光反应中与底物荧光素和ATP结合的氨基酸。L. terminalis萤火虫荧光素酶的三级结构与L. cruciata荧光素酶晶体结构非常相似，而L. ovalis荧光素酶的三级结构在AMP结合位点附近有两个偏离的环。

Synthesis and structural characterization of organolanthanide complexes with 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate ligands

Reactions of anhydrous LnCl(3) (Ln = Nd, Gd, Dy, Er, Yb) with 2 equiv of LiCp' in THF afford the lanthanocene complexes Of CP'(2)Ln(mu-Cl)(2)Li(THF)(2) (CP' = eta(5)-t-BuC5H4, Ln = Nd (1), Gd (2), Dy (3), Er (4), Yb (5); Cp'= 1,3-eta(5)-t-Bu2C5H3, Ln = Nd (6), Gd (7), Dy (8), Er (9), Yb (10)). The molecular structures of 7 and 8 were characterized by X-ray crystallographic analysis. In these complexes, two Cp' ring centroids and two it-bridging chloride atoms around the lanthanide atoms form a distorted tetrahedron. The insertion of elemental chalcogen E (E = S, Se) into Li-C bonds of dilithium o-carborane in THF solution afforded dimers of dilithium. dichalcogenolate carboranes, [(THF)(3)LiE2C2B10H10Li(THF)](2) (E = S (12a), Se (12b)), which were confirmed by a crystal structure analysis. Reactions Of Cp'(2)Ln(mu-Cl)(2)Li(THF)(2) (1-10) with 12a or 12b gave dinuclear complexes of the formula [Li(THF)(4)](2)[Cp'(2)LnE(2)C(2)B(10)H(10)](2) (Cp'= eta(5)-t-BuC5H4, E = S, Ln = Nd (13a), Gd (14a), Dy (15a), Er (16a), Yb (17a); E = Se, Ln = Nd (13b), Gd (14b), Dy (15b), Er (16b), Yb (17b); Cp'= 1,3-eta(5)-t-Bu2C5H3 E = S, Ln = Nd (18a), Gd (19a), Dy (20a), Er (21a), Yb (22a); E = Se, Ln = Nd (18b), Gd (19b), Dy (20b), Er (21b), Yb (22b)). According to the X-ray structure analyses, the dianions of 13a and 13b contain two o-carborane dichalcogenolate bridges, and each CP'2Ln fragment is attached to one terminal and two bridging chalcogen ligands. The central Ln(2)E(2) four-membered ring is not planar, and the direct metal-metal interaction is absent.

释光测年实验室的建立与沉积物释光测年技术研究

The main research projects reported in this paper are the establishment of a luminescence (OSL/TL) dating laboratory in The Institute of Geology and Geophysics, CAS, and studies on OSL dating technique and protocol of sediments from North China. These projects have been suggested in order to fit in with the needs of research developments in environmental changes, in particular the aridity and desertification in North China. A new luminescence dating laboratory in which there are a Rise TL/OSL-DA-15B/C reader with Sr-90 beta source, a set of Little More Tape 9022 alpha and beta irradiators, three set of Daybreak 583 intelligent alpha counters and sample preparation system has been set up in the Institute in June 2001. The courses of the establishment of a new laboratory involved a series of technical works, besides making a suitable choice of the equipment, as follows: installing and testing TL/OSL reader, calibrating the dose rate of the beta and alpha sources in the irradiators with the standard sources, testing and calibrating the count rates of the thick source alpha counting in the alpha counters with a standard sample, and then dating of the know age samples to check and examine the OSL/TL dating system. All data obtained from above calibrations and tests show that the established OSL/TL system, including the used equipment in it, can be used to determine age of the geological and archaeological samples with an error of equivalent dose (De) of less than 5%. The OSL dates of several sediment samples obtained from the system are good agreement with those from the OSL dating laboratory in Hong Kong University and ~(14)C dates within 1 - 2 standard deviations. The studies on OSL dating technique and protocol of sediment samples being in progress involve the De determinations with single aliquot regeneration (SAR) (Murray and Wintle, 2000) of the coarse grain quartz from sand dune samples and comparison of the De determinations obtained from SAR with those measured by using multiple aliquot regeneration of loess fine grains. The preliminary results from these research works are shown as follows. The very low natural equivalent dose (De) of about 0.012 - 0.03 Gy, corresponding age of less than 10 years, for BLSL (blue light stimulated luminescence) of the coarse grain quartz from modern sand dune samples in Horqin sand fields has been determined with both the SAR and multiple aliquot regeneration (MAR) techniques. This imply that the BLSL signal zeroing of the quartz could be reached before burying of the sand in Horqin sand fields. The De values and ages of the coarse grain quartz measured with SAR protocol are in good agreement with those obtained from multiple aliquot technique for the modern sand dune samples, but the errors of De from the MAR is greater than those from the SAR. This may imply that the higher precision of age determination for younger sand dune samples could be achieved with the SAR of coarse grain quartz. The MAR combining with "Australian Slide method" may be a perfect choice for De measurements of loess fine grain samples on the basis of analysis of De values obtained from the SAR and from the MAR. The former can be employed to obtain a reliable age estimate of loess sample as older as approximately SO ka BR There is a great difference between De determinations from the (post-IR) OSL of the SAR (Roberts and Wintle, 2001) and those from independent or expected estimates for the older samples. However, the age estimates obtained from the (post-IR) OSL of the SAR are mostly closed to the independent age determinations for the younger (age less than 10 ka) fine grain samples. It may be suggested that the (post-IR) OSL of the SAR protocol of the fine grain fraction would be a suitable choice to dating of the younger samples, but may be unsuitable for the older samples.