Ice induced low temperature fatigue crack propagation in offshore structural steel A131

To investigate the low temperature fatigue crack propagation behavior of offshore structural steel A131 under random ice loading, three ice failure modes that are commonly present in the Bohai Gulf are simulated according to the vibration stress responses induced by real ice loading. The test data are processed by a universal software FCPUSL developed on the basis of the theory of fatigue crack propagation and statistics. The fundamental parameter controlling the fatigue crack propagation induced by random ice loading is determined to be the amplitude root mean square stress intensity factor K-arm. The test results are presented on the crack propagation diagram where the crack growth rate da/dN is described as the function of K-arm. It is evident that the ice failure modes have great influence on the fatigue crack propagation behavior of the steel in ice-induced vibration. However, some of the experimental phenomena and test results are hard to be physically explained at present. The work in this paper is an initial attempt to investigate the cause of collapse of offshore structures due to ice loading.

变波长读出条件下光折变局域体全息光栅的衍射性质

利用二维耦合波理论，研究了用短波长记录全息光栅而用通讯波段内的长波长读出时，用于90°结构垂直读出平板型的光折变局域体全息光栅的衍射性质．讨论了局域体全息光栅的几何尺寸对其衍射效率及光栅布喇格选择性的影响．结果表明，随着光栅的纵向和横向尺寸的增加，光栅的衍射效率也逐渐增加．当光栅的纵向和横向尺寸发生改变但光栅的总面积不变时，光栅衍射效率保持不变．此外，随着光栅尺寸的增加光栅的布喇格选择性越好．在利用短波长记录全息光栅而用长波长读出的光学器件设计过程中，为了获得最佳的衍射效率及其布喇格选择特性，应当根据要求

KARYOTYPE EVOLUTION OF SHREW MOLES (SORICOMORPHA: TALPIDAE)

The Chinese long-tailed mole (Scaptonyx fusicaudus) closely resembles American (Neurotrichus gibbsii) and Japanese (Dymecodon pilirostris and Urotrichus talpoides) shrew moles in size, appearance, and ecological habits, yet it has traditionally been classified either together with (viz subfamily Urotrichinae) or separately (tribe Scaptonychini) from the latter genera (tribe Urotrichini sensu lato). We explored the merit of these competing hypotheses by comparing the differentially stained karyotypes of S.fusicaudus and N. gibbsii with those previously reported for both Japanese taxa. With few exceptions, diploid chromosome number (2n = 34), fundamental autosomal number (FNa = 64), relative size, and G-banding pattern of S. fusicaudus were indistinguishable from those of D. pilirostris and U. talpoides. In fact, only chromosome 15 differed significantly between these species, being acrocentric in D. pilirostris, subtelocentric in U. talpoides, and metacentric in S. fusicaudus. This striking similarity is difficult to envisage except in light of a shared common ancestry, and is indicative of an exceptionally low rate of chromosomal evolution among these genera. Conversely, the karyotype of N. gibbsii deviates markedly in diploid chromosome and fundamental autosomal number (2n = 38 and FNa = 72, respectively), morphology, and G-banding pattern from those of Scaptonyx and the Japanese shrew moles. These differences cannot be explained by simple chromosomal rearrangements, and Suggest that rapid chromosomal reorganization Occurred ill the karyotype evolution of this species, possibly due to founder or bottleneck events.

纳米材料对环境和健康的潜在危害

随着越来越多的纳米商品材料在生产和生活中的应用,纳米材料的环境安全问题逐渐引起关注,纳米科技和纳米材料的潜在风险及其负面影响己成为专家共识。文章综述了纳米材料对环境和生命健康带来的可能危害及其毒性特性,并认为深入研究纳米材料的环境安全问题将有助于建立正确生产、使用和处理纳米材料的科学规范。

O~(5+)离子入射在金属表面形成L壳层X射线产生截面的研究

<正>迄今为止,K壳层电离的研究已取得了长足的进展。人们已对各不同入射离子轰击各种靶元素,在很大的能区范围内测量了K壳层X射线产生截面,而L壳层的实验数据则不够完善。本实验测量了

湖北清江和尚洞石笋脂肪酸的古气候意义

IEECAS SKLLQG

Capillary array electrophoresis with confocal fluorescence rotary scanner

A capillary array electrophoresis system with rotary corifocal fluorescence scanner was reported. High speed direct current rotary motor combined with a rotary encoder and the reflection mirror has been designed to direct exactly the excitation laser beam. to the array of capillaries, which are symmetrically distributed around the motor. The rotary encoder is introduced to accurately orient the position of each capillary and its output signal triggers the data acquiring system to record. the fluorescence signal corresponding to each capillary. Separations of several amino acids are demonstrated by eight-channel capillary array electrophoresis built by ourselves.

施用镁、硼及硝基腐植酸对烤烟产量和品质的影响

以辽宁省昌图县横沟子乡先锋村烟田的土壤农化性状指标为参数，设计镁、硼素及硝基腐植酸作为烟草专用肥的添加剂，研究其对提高和改善烤烟产量、品质的影响，１９９１～１９９３年三年的田间试验表明，亩施硫酸镁、硼砂各０．５ｋｇ及硝基腐植酸３．５ｋｇ做基肥，移栽４０天，镁、硼处理区再分别喷施硫酸镁５００克（１％浓度），硼砂１００克（０．２％浓度），这三个处理区不论是烟株苗期生长的叶色、抗病力及成熟期烟叶落黄、烘烤效果，还是上等烤烟比重、化学成分含量等指标均有改善和提高。

新型二维异核配位聚合物{[NdBi(cydta)(NO_3)_2(H_2O)_4]·2.5H_2O}_n的晶体结构与热分解

由Bi(Hcydta).5H2O和Nd(NO3).6H2O按1︰1的物质的量比,在水溶液中合成了含Bi(III)-Nd(III)的异核配位聚合物{[(NO3)Nd(H2O)4(μ3-cydta)Bi(μ-ONO2)].2.5H2O}n.用元素分析、红外光谱、热重-差热和X射线单晶衍射等手段对标题配合物的组成和结构进行了表征.该配合物属三斜晶系,空间群P1,晶胞参数:a=0.9235(3)nm,b=1.0902(4)nm,c=1.4253(5)nm,α=71.840(4)°,β=86.877(4)°,γ=76.991(4)°,Z=2,Mr=936.65,V=1.3284(8)nm3,Dc=2.342g.cm-3,μ=8.646mm-1,F(000)=900,最终偏离因子R1=0.0406,wR2=0.1124.在该配合物中,铋(III)与配体cydta4-的4O2N和1个硝酸根中1个O原子以及邻位分子的硝酸根形成8配位的畸变双帽三棱柱.钕(III)与4个水分子的O,1个硝酸根中2个O以及来自3个不同配体cydta4-的桥联羧基O结合,形成9配位的三帽三棱柱构型.羧酸根在Bi—Nd和硝酸根在Bi—Bi间的桥联作用...

Simultaneous determination of dopamine, ascorbic acid and uric acid with electrospun carbon nanofibers modified electrode

A novel carbon-nanofiber-modified carbon-paste electrode (CNF-CPE) was employed for the simultaneous determination of dopamine (DA), ascorbic acid (AA) and uric acid (UA) with good selectivity and high sensitivity. The CNFs were prepared by combination of electrospinning technique with thermal treatment method and were used without any pretreatment. In application to determination of DA, AA and UA in the ternary mixture, the pristine CNF-CPE exhibited well-separated differential pulse voltammetric peaks with high catalytic current. Low detection limits of 0.04 mu M, 2 mu M and 0.2 mu M for DA, AA and UA were obtained, with the linear calibration curves over the concentration range 0.04-5.6 mu M, 2-64 mu M and 0.8-16.8 mu M, respectively.

Rotating minidisk-disk electrodes

Rotating minidisk-disk electrode (RMDDE) was developed by replacing ring electrode of rotating ring-disk electrode (RRDE) with a minidisk electrode. Its applications were demonstrated by studying electrochemical reactions of ferricyanide and divalent copper. The replacement of ring electrode by minidisk electrode results in following advantages. First, the fabrication of RMDDE is easier than that of RRDE with the same electrode material. Second, there is more freedom in choosing electrode materials and sizes, since it is difficult to make thin ring electrodes of RRDE with fragile materials. Third, the replacement of ring electrode by minidisk electrode saves electrode materials, especially rare materials. Finally, the substitution of minidisk electrode for ring electrode allows using multiple minidisks for simultaneous monitoring of multiple components. Therefore, RMDDE is a promising generator-collector system, especially when special generator-collector systems are not commercially available, such as corrosion study and electrocatalysis study of new electrode materials.