Kinetics of extraction and stripping of y(III) by Cyanex 272 as an acidic extractant using a constant interfacial cell with laminar flow

The extraction and stripping kinetics of yttrium(III) with bis(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272, HA) dissolved in heptane as an acid extractant have been investigated by constant interfacial cell with laminar flow. The experimental hydrodynamic conditions have been chosen so that the contribution of diffusion to the measured rate of reaction is minimized. The plot of interfacial area on the rate has shown a linear relationship, which makes the interface the most probable local for the chemical reactions. At the same time, the extraction thermodynamic and kinetic methods are compared to determine the equilibrium extraction constant. A rate equation and the rate-determining step of the extraction and stripping of yttrium(III) have also been obtained, respectively.

Kinetics of ytterbium(III) extraction with Cyanex 272 using a constant interfacial cell with laminar flow

Studies have been made on the kinetics of ytterbium(III) with bis-(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272, HA) in n-heptane using a constant interfacial cell with laminar flow. The stiochiometry and the equilibrium constant of the extracted complex formation reaction between Yb3+ and Cyanex 272 are determined. The extraction rate is dependent of the stirring rate. This fact together with the Ea value suggests that the mass transfer process is a mixed chemical reaction-diffusion controlled at lower temperature, whereas it is entirely diffusion controlled at higher temperature. The rate equations for the ytterbium extraction with Cyanex 272 have been obtained. The rate-determining step is also made by predictions derived from interfacial reaction models, and through the approximate solutions of the flux equation, diffusion parameters and thickness of the diffusion film have been calculated.

Mass transfer kinetics of yttrium(III) using a constant interfacial cell with laminar flow. Part II. Extraction with Cyanex 272

The yttrium(III) extraction kinetics and mechanism with bis-(2,4,4-trimethyl-pentyl) phosphinic acid (Cyanex 272, HA) dissolved in heptane have been investigated by constant interfacial cell with laminar flow. The data has been analyzed in terms of pseudo-first order constants. Studies on the effects of stirring rate, temperature, acidity in aqueous phase, and extractant concentration on the extraction rate show that the extraction regime is dependent on the extraction conditions. The plot of interfacial area on the rate has shown a linear relationship. This fact together with the strong surface activity of Cyanex 272 at heptane-water interfaces has made the interface the most probable location for the chemical reactions. The forward, reverse rate equations and extraction rate constant for the yttrium extraction with Cyanex 272 have been obtained under the experimental conditions. The rate-determining step has been also predicted from interfacial reaction models. The predictions have been found to be in good agreement with the rate equations obtained from experimental data, confirming the basic assumption that the chemical reaction is located at the liquid-liquid interface.

Kinetics of Y(III) stripping for the system Y/HCl/Cyanex 272-P507/heptane with constant interfacial area cell with laminar flow

Kinetics and mechanism of stripping of yttrium(III) previously extracted by mixtures of bis(2,4,4-trimethylpentyl)phosphinic acid (Cyanex 272, HA), and 2-ethylhexyl phosphonic acid mono-2-ethylhexl ester (P507, HB) dissolved in heptane have been investigated by constant interfacial-area cell by laminar flow. The corresponding equilibrium stripping equation and equilibrium constant were obtained. The studies of effects of the stirring rate and temperature on the stripping rate show that the stripping regime is dependent on the stripping conditions. The plot of interfacial area on the rate has shown a linear relationship. This fact together with the strong surface activity of mixtures of Cyanex 272 and P507 at heptane-water interfaces makes the interface the most probable locale for the chemical reactions. The stripping rate constant is obtained, and the value is compared with that of the system with Cyanex 272 and P507 alone. It is concluded that the stripping ability with the mixtures is easier than that of P507 due to lower the activation energy of the mixtures. The stripping rate equation has also been obtained, and the rate-determining steps are the two-step interfacial chemical reactions as predicted from interfacial reaction models.

Synergistic extraction of zinc(II) with mixtures of CA-100 and cyanex 272

The extraction of zinc(II) from an aqueous chloride medium has been studied using mixtures of sec-nonylphenoxy acetic acid (CA-100) and bis(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272). The results demonstrate that zinc ion is extracted into heptane as ZnA(2).2HA with CA-100, ZnL2.2HL with Cyanex 272, and ZnA(2)L(2)H(2) with synergistic mixture. The equilibrium constants of the these species have been calculated and extraction mechanisms have been proposed. Thermodynamic parameters of the extraction process were determined by the temperature coefficient of extractability. The synergistic system enhances the extraction efficiency of zinc(II) and also improves the selectivity between zinc(II) and cadmium(II).

Extraction and separation of heavy rare earth (III) with Extraction Resin containing di(2,4,4-trimethyl pentyl) phosphinic acid (Cyanex 272)

Extraction resins, of the type of;levextrel, (which is a collective term for styrene/divinylbenzene based copolymers of predominantly macroporous structure that contain a selective extractant) are important for the recovery and separation of metal ions, as they combine features of solvent extraction and ion exchange resins. This paper presents the results of the adsorption of heavy rare earth ions (Ho(III), Er(III), Tm(III), Yb(III), Lu(III) and Y(III)) from hydrochloric acid solutions at 0.2 mol/L ionic strength and 50 degrees C by the extraction resin containing di (2,4,4-trimethyl pentyl) phosphinic acid (Cyanex 272) and the chromatographic separation of (Er(III), Tm(III) and Yb(III)). Technological separation products, with purity and yield of Tm2O3 >99.97%, >80%, Er2O3 >99.9%, >94% and Yb2O3 >99.8%, >80% respectively, have been obtained from a feed having the composition Tm2O3 60%, Er2O3 10%, and Yb2O3 3%, the others 27%. The distribution coefficients, extraction equilibrium constants and separation factors have been determined as a function of acidity, loading of the resin and rare earths, flow rates and column ratios. The resolutions and efficiencies of separation of Er/Tm/Yb each other have been calculated. The stoichiometry of the extraction of rare earth ions has been suggested as well.

Electromechanical influence of crack velocity at bifurcation for poled ferroelectric materials

The piezoelastodynamic field equations are solved to determine the crack velocity at bifurcation for poled ferroelectric materials where the applied electrical field and mechanical stress can be varied. The underlying physical mechanism, however, may not correspond to that assumed in the analytical model. Bifurcation has been related to the occurrence of a pair of maximum circumferential stress oriented symmetrically about the moving crack path. The velocity at which this behavior prevails has been referred to as the limiting crack speed. Unlike the classical approach, bifurcation will be identified with finite distances ahead of a moving crack. Nucleation of microcracks can thus be modelled in a single formulation. This can be accomplished by using the energy density function where fracture initiation is identified with dominance of dilatation in relation to distortion. Poled ferroelectric materials are selected for this study because the microstructure effects for this class of materials can be readily reflected by the elastic, piezoelectic and dielectric permittivity constants at the macroscopic scale. Existing test data could also shed light on the trend of the analytical predictions. Numerical results are thus computed for PZT-4 and compared with those for PZT-6B in an effort to show whether the branching behavior would be affected by the difference in the material microstructures. A range of crack bifurcation speed upsilon(b) is found for different r/a and E/sigma ratios. Here, r and a stand for the radial distance and half crack length, respectively, while E and a for the electric field and mechanical stress. For PZT-6B with upsilon(b) in the range 100-1700 m/s, the bifurcation angles varied from +/-6degrees to +/-39degrees. This corresponds to E/sigma of -0.072 to 0.024 V m/N. At the same distance r/a = 0.1, PZT-4 gives upsilon(b) values of 1100-2100 m/s; bifurcation angles of +/-15degrees to +/-49degrees; and E/sigma of -0.056 to 0.059 V m/N. In general, the bifurcation angles +/-theta(0) are found to decrease with decreasing crack velocity as the distance r/a is increased. Relatively speaking, the speed upsilon(b) and angles +/-theta(0) for PZT-4 are much greater than those for PZT-6B. This may be attributed to the high electromechanical coupling effect of PZT-4. Using upsilon(b)(0) as a base reference, an equality relation upsilon(b)(-) < upsilon(b)(0) < upsilon(b)(+) can be established. The superscripts -, 0 and + refer, respectively, to negative, zero and positive electric field. This is reminiscent of the enhancement and retardation of crack growth behavior due to change in poling direction. Bifurcation characteristics are found to be somewhat erratic when r/a approaches the range 10(-2)-10(-1) where the kinetic energy densities would fluctuate and then rise as the distance from the moving crack is increased. This is an artifact introduced by the far away condition of non-vanishing particle velocity. A finite kinetic energy density prevails at infinity unless it is made to vanish in the boundary value problem. Future works are recommended to further clarify the physical mechanism(s) associated with bifurcation by means of analysis and experiment. Damage at the microscopic level needs to be addressed since it has been known to affect the macrocrack speeds and bifurcation characteristics. (C) 2002 Published by Elsevier Science Ltd.

用计算机技术标定测力传感器

本文提出用计算机技术标定压电测力传感器的方法。提高了标定精度,方便可靠地得到传感器的动态和静态性能,迅速处理大量标定数据;适于实验室中标定压电测力传感器。

第3届全国复合材料学术会议

<正> 会议于1984年11月2—7日在杭州举行,由中国宇航学会、中国航空学会和中国力学学会共同主办,全国科研、设计、生产部门和大专院校13个学院87个单位的221名代表参加了会议,大会收到学术报告312篇,接受了182篇,会前即预印了论文集,120篇论文分别在材料工艺、性能测试与应用、静动态力学性能、结构设计分析以及金属基复合材料五个组

后柱横向振动串列双圆柱尾迹特性

本文采用电化学显示方法和热线技术就雷诺数为10~2—10~3,后柱横向振动串列双圓柱尾迹和涡街进行了研究。双柱间距为1.5≤s/d≤10,后柱振动振幅为0.1d和0.3d。首先,本文得到了低雷诺数情况下,串列双圆柱绕流旋涡脱落频率随柱间距和雷诺数的变化规律。并且,通过流谱分析,对于出现频率间断现象给予了说明。其次,本文着重研究了振动情况下尾迹特性。当后柱以静止双柱涡脱落频率强迫振动,涡脱落和柱振动之间将发生联锁反应。本文实验揭示了联锁区奇特的涡街流谱——二次涡、涡的聚集和涡街伸长。

平面应力裂纹稳态扩展的弹塑性大变形有限元分析

本文根据平面应力弹塑性断裂的带状颈缩区模型,以裂纹顶端颈缩区的相对伸长达到材料延伸率作为裂纹扩展的准则,采用塑性大变形的基本方程和有限元方法,计算了含中心裂纹的铝合金薄板在均匀拉伸作用下的裂纹稳态扩展过程,计算结果与实验结果符合很好。

A coupled model for multiphase fluid flow and sedimentation deformation in oil reservoir and its numerical simulation

A mathematical model for coupled multiphase fluid flow and sedimentation deformation is developed based on fluid-solid interaction mechanism. A finite difference-finite element numerical approach is presented. The results of an example show that the fluid-solid coupled effect has great influence on multiphase fluid flow and reservoir recovery performances, and the coupled model has practical significance for oilfield development.

求解载流薄壳二维磁弹性的差分法

本文针对在电磁场和机械场耦合作用下的载流薄壳的非线性变形问题进行了研究。给出了载流薄壳在耦合场作用下的二维电动力学方程、磁弹性非线性运动方程和Lorentz力表达式,通过变量代换将描述载流薄壳的磁弹性状态方程整理成含有10个基本未知函数的标准Cauchy型。并通过差分法及准线性化方法,将标准Cauchy型非线性偏微分方程组,变换成为能够用正交离散法编程求解的准线性微分方程组,实现了载流薄壳的磁弹性应力与变形的数值解。

水下超声速气体射流回击现象的实验研究

对水下超声速气体射流的动力学行为进行了实验研究．通过流动可视化揭示了回击现象的演化过程，利用探针排获得了射流近场区的脉动压力分布，实验结果表明：在超声速喷管出口两倍直径处，射流形貌的变化导致气体中出现了大幅值压力脉冲．通过流场可视化与压力测量的同步校验，证实了喷口端面处回击事件与流场气相区中压力脉动之间相关性．