TW-80对污染土壤中菲和芘的生物降解影响

以 Ｔ Ｗ８０ 为供试物，进行了表面活性剂对污染土壤中菲和芘生物降解影响研究． 实验周期１５０ ｄ ．并分别在３０ ｄ 、６０ ｄ 和１５０ ｄ 间隔采样监测菲、芘降解率．结果表明，３０ ｄ 后，加入 Ｔ Ｗ８０ 的不同处理土壤中，菲的降解率分别达８１ ％ ～９８ ．９ ％ ，比 Ｃ Ｋ 高２２ ．０２ ％ 以上、芘的降解率分别达７１ ．９０ ％ ～８０ ．６６ ％ ，比 Ｃ Ｋ 高９ ．４６ ％ 以上．６０ ｄ 后，加入 Ｔ Ｗ８０ 的处理中，菲的降解率达８８ ．９４ ％ ～９６ ．５１ ％ 、比 Ｃ Ｋ 高１１ ．１４ ％ 以上； 芘降解率达９２ ．３９ ％～９４ ．０２ ％ ，比 Ｃ Ｋ 高２ ．２７ ％ 以上．１５０ ｄ 后，所有处理中，菲和芘的降解率均分别达到９８ ％ 和９６ ％ 以上， 与 Ｃ Ｋ 无明显差别．研究还发现， Ｔ Ｗ８０ 土壤中含有优势真菌常见青霉、蠕形青霉、淡紫青霉和顶孢头孢霉．它们可能是促进土壤中菲、芘降解的原因

Heat capacity and thermodynamic properties of pyrimethanil myristic salt (C26H41N3O2)

Pyrimethanil myristic salt was synthesized and its heat capacities were measured with an automated adiabatic calorimeter over the temperature range from T = (79 to 360) K. The melting point, molar enthalpy, Delta(fus)H(m) and entropy, Delta(fus)S(m), of fusion of this compound were determined to be (321.84 +/- 0.05) K, (56.53 +/- 0.03) kJ . mol(-1) and (175.64 +/- 0.05) J . mol(-1) . K-1, respectively. The purity of the compound was calculated to be 98.99 mol% by using the fractional melting technique. The thermodynamic functions relative to the reference temperature, T = 298.15 K, were calculated based on the heat capacity measurements in the temperature ranges from T = (80 to 360) K. The TG-DTG results demonstrate that the mass loss of the sample takes place in one step with the maximum rate at T = 500 K, which was caused by evaporation of the sample. (C) 2004 Elsevier Ltd. All rights reserved.

Heat capacity and thermodynamic properties of crystalline ornidazole (C7H10ClN3O3)

The molar heat capacities of 1-(2-hydroxy-3-chloropropyl)-2-methyl-5-nitroimidazole (Ornidazole) (C7H10CIN3O3) with purity of 99.72mol% were measured with an adiabatic calorimeter in the temperature range between 79 and 380K. The melting-point temperature, molar enthalpy Delta(fus)H(m), and entropy, Delta(fus)S(m), of fusion of this compound were determined to be 358.59 +/- 0.04K, 21.38 +/- 0.02 kJ mol(-1) and 59.61 +/- 0.05 J K-1 mol(-1), respectively, from fractional melting experiments. The thermodynamic function data relative to the reference temperature (298.15 K) were calculated based on the heat capacities measurements in the temperature range from 80 to 380 K. The thermal stability of the compound was further investigated by DSC and TG. From the DSC curve an intensive exothermic peak assigned to the thermal decomposition of the compound was observed in the range of 445-590 K with the peak temperature of 505 K. Subsequently, a slow exothermic effect appears when the temperature is higher than 590 K, which is probably due to the further decomposition of the compound. The TG curve indicates the mass loss of the sample starts at about 440K, which corresponds to the decomposition of the sample. (C) 2003 Elsevier B.V. All rights reserved.

表面活性剂TW-80对土壤中多环芳烃生物降解的影响

以表面活性剂ＴＷ８０为供试物，进行了为期１５０ｄ的实验研究，并分别在３０、６０和１５０ｄ间隔采样监测ＰＡＨｓ降解率．结果表明，３０ｄ后，土壤中ＰＡＨｓ的降解率达９０％，比对照提高约３０％．６０ｄ后，浓度为１００００ｍｇ·ｋｇ－１表面活性剂的土壤和对照中，ＰＡＨｓ降解率从６５．１％和６０％迅速提高到９３．８％和７９．２％．其它处理中，ＰＡＨｓ的平均降解率仅比３０ｄ的结果提高４％．１５０ｄ后，所有处理中ＰＡＨｓ的降解率均达到９０％以上．可以认为，表面活性剂能提高ＰＡＨｓ的生物可利用性，加快ＰＡＨｓ的降解速率，从而减少污染暴露时间．但表面活性剂浓度过高可抑制微生物活性．研究还发现，ＴＷ８０土壤中含有优势真菌．经鉴定为常见青霉、蠕形青霉、淡紫青霉和顶孢头孢霉．它们是土壤ＰＡＨｓ迅速降解的动因

表面活性剂吐温-80对菲和芘生物降解的影响

表面活性剂吐温－８０对菲和芘生物降解的影响宋玉芳赵燕杨桂芬（中国科学院沈阳应用生态研究所，沈阳１１００１５）我们通过室内模拟实验方法选择了表面活性剂吐温－８０，研究其生物毒性及对菲，芘微生物活性和微生物降解的影响，土壤呼吸强度实验结果表明，当吐温－８...

Low-temperature heat capacity and thermodynamic properties of crystalline carboxin (C12H13NO2S)

Carboxin was synthesized and its heat capacities were measured with an automated adiabatic calorimeter over the temperature range from 79 to 380K. The melting point, molar enthalpy (Delta(fus)H(m)) and entropy (Delta(fus)S(m)) of fusion of this compound were determined to be 365.29 +/- 0.06K, 28.193 +/- 0.09 kJ mol(-1) and 77.180 +/- 0.02 J mol(-1) K-1, respectively. The purity of the compound was determined to be 99.55 mol% by using the fractional melting technique. The thermodynamic functions relative to the reference temperature (298.15 K) were calculated based on the heat capacity measurements in the temperature range between 80 and 360 K. The thermal stability of the compound was further investigated by differential scanning calorimetry (DSC) and thermogravimetric (TG) analysis. The DSC curve indicates that the sample starts to decompose at ca. 290degreesC with the peak temperature at 292.7degreesC. The TG-DTG results demonstrate the maximum mass loss rate occurs at 293degreesC corresponding to the maximum decomposition rate. (C) 2003 Elsevier B.V All rights reserved.

长白山各植被带主要树种凋落物分解速率及模型模拟的试验研究

2001～2003年在长白山自然保护区内3个垂直植被带的典型群落红松阔叶林、云冷杉林和岳桦林内,利用网袋埋藏法对群落内的6个主要优势乔木树种凋落物进行埋藏分解试验,研究凋落物分解速率及其变化动态;同时利用分解模型,模拟预测凋落物的分解进展,为深入研究这6个树种的营养策略、群落养分循环等奠定基础,也为森林生态系统管理提供理论依据。研究结果表明,所研究的6个树种凋落物都表现出随时间进程失重率增大的现象,但失重率并不与时间呈线性相关。在分解的638d(1.75a)后,6种叶凋落物的分解速率明显升高。到分解实验结止时(699d),叶凋落物干重剩余率从小至大依次为白桦(24.56%)、紫椴(24.81%)、红松(38.48%)、鱼鳞云杉(41.15%)、岳桦(41.53%)和臭冷杉(42.62%)。枝凋落物分解速率明显低于叶,枝干重剩余率从小至大依次为紫椴(44.98%)、臭冷杉(64.62%)、红松(72.07%)、鱼鳞云杉(73.51%)、白桦(77.37%)和岳桦(80.35%)。在同一海拔高度,阔叶树种叶凋落物分解速率大于针叶树种。并且随着海拔的升高,叶凋落物分解速率逐渐减慢。模型分析预测结果表明,长白山北坡各垂直植被带的优势树种叶凋落物分解95%需4.5～8.0a;年分解系数为紫椴(0.686)>白桦(0.624)>红松(0.441)>鱼鳞云杉(0.406)>臭冷杉(0.397)>岳桦(0.385);枝凋落物分解95%需7.8～29.3a,不同树种间的差异明显。枝年分解系数为紫椴(0.391)>臭冷杉(0.204)>红松(0.176)>鱼鳞云杉(0.157)>白桦(0.148)>岳桦(0.102)。

长白山红松针阔叶混交林生态系统生产力的估算

利用LI-6400CO2分析系统测定了长白山红松针阔叶混交林生态系统土壤呼吸、乔木和灌木树干和枝条的呼吸、植物叶片光合与呼吸．同步监测森林小气候气象因子,建立土壤、树干、叶片与气象因子间的模型．根据红松针阔叶混交林植被群落特性,估算红松针阔叶混交林森林生态系统不同组分CO2通量．利用涡度相关技术监测红松针阔叶混交林净生态系统交换量．探讨温度、光合有效辐射对森林生态系统CO2通量的影响．通过分析发现,在当年的气候条件下,该森林净生态系统交换量主要受土壤呼吸和叶片光合的影响．红松针阔叶混交林净生态系统交换量全年变化范围在-4．67～13．80μmol·m-2·s-1．该森林生态系统CO2通量在冬季和夏季里平均分别为-2．0和3．9μmol·m-2·s-1(24 h平均值)．乔木、灌木和草本的初级生产力分别占阔叶红松林总初级生产力的89．7％,3．5％,6．8％．土壤呼吸是森林生态系统中最主要的CO2排放源,约占红松针阔叶混交林生态系统CO2排放的69．7％,植物叶片和枝干分别占15．2％和15．1％．在生长季和非生长季中红松针阔叶混交林净生态系统交换量分别占全年CO2通量的56．8％和43．2％．自养呼吸占总初级生产力的比值(Ra:GPP)为0．52(NPP:GPP=0．48)．森林生态系统地下当年碳积累量占总初级生产力的52％．土壤呼吸占总初级生产力的60％．红松针阔叶混交林NPP为769．3 gC·m-2·a-1．该森林净生态系统交换量(NEE)为229．51 gC·m-2·a-1．涡度相关技术获得的该森林生态系统NEE低于箱式法获得的19．8％．

A comparative study of non-oxidative pyrolysis and oxidative cracking of cyclohexane to light alkenes

Naphthene is generally considered difficult to convert in traditional pyrolysis, but the ring rupture becomes fairly easy with the presence of oxygen in the gas phase oxidative cracking of the model compound, cyclohexane. About 86.8% conversion of cyclohexane, 43.7% yield of light alkenes, 6.6% yield of benzene and 14.3% yield of CO could be obtained at 750 degreesC, at which temperature the pyrolysis of cyclohexane was negligible, while at 850 degreesC, the total yield of alkenes, benzene and CO was as high as 80% (50%, 12% and 18%, respectively) with 98% conversion of cyclohexane. The gas phase oxidative cracking process could be run in an autothermal way (cyclohexane/O-2 mole ratio of 0.69-0.8 in theory), which would minimize energy consumption and capital costs of the whole process. CO prevailed in the produced CO, and the yield Of CO2 was always below 1%, which means about 90% Of CO2 emission by fuel burning in pyrolysis would be saved. The gas phase oxidative cracking process appears to be an environmentally benign and efficient route for light alkene production with naphthene rich feedstocks. (C) 2004 Published by Elsevier B.V.

东北黑土地区主要土壤肥力质量指标的空间变异性

采用地理信息系统(G IS)和地统计学相结合的方法研究了本世纪初东北黑土区土壤表层(0~20 cm)pH、有机质、速效磷、速效钾、粘粒这5种土壤肥力指标的空间变异性。结果表明:土壤pH和粘粒的理论模型均为指数模型;有机质、速效磷和速效钾的理论模型均为球状模型。速效磷、速效钾的C0/(C0+C)较大,为46.63%和49.91%,说明这2种肥力指标具有中等的空间相关性;而pH、有机质、粘粒的C0/(C0+C)分别为10.80%、16.57%、12.88%,说明这3种肥力指标具有较强的空间相关性。根据每个采样点的指标数据计算出该地区土壤肥力质量综合评价指数,最终得到研究区土壤肥力质量的分布图。