A Holocene paleotemperature record based on radiolaria from the northern Okinawa Trough (East China Sea)

Using a radiolarian-based transfer function, mean annual sea surface temperature (SST) and seasonal temperature range are reconstructed through the last 10,500yrs in the northern Okinawa Trough. Down-core SST estimates reveal that throughout the Holocene the changes of mean annual SST display a three-step trend: (i) an early Holocene continuous warming between 10,500 and 8500yr BP which ends up with a abrupt cooling at about 8200yr BP; (ii) a relatively stable middle Holocene with high SST that lasted until 3200yr BP; and (iii) a late-Holocene distinct SST decline between 3200 and 500yr BP. This pattern is in agreement with the ice core and terrestrial paleoclimatic records in the Chinese continent and other regions of the world. Five cooling events with abrupt mean annual SST drops, which occur at similar to 300-600, 1400, 3100, 4600-5100 and 8200yr BP, are recognized during the last 10,500yrs. Comparison of our results with records of GISP2 ice core and marine sediment in North Atlantic region suggests these cooling events are strongly coupled, which implies a possible significant climatic correlation between high- and low-latitude areas. (C) 2007 Elsevier Ltd and INQUA. All rights reserved.

Authigenic sulfide minerals and their sulfur isotopes in sediments of the northern continental slope of the South China Sea and their implications for methane flux and gas hydrate formation

This is a report of the study of the authigenic sulfide minerals and their sulfur isotopes in a sediment core (NH-1) collected on the northern continental slope of the South China Sea, where other geophysical and geochemical evidence seems to suggest gas hydrate formation in the sediments. The study has led to the findings: (1) the pyrite content in sediments was relatively high and its grain size relatively large compared with that in normal pelagic or hemipelagic sediments; (2) the shallowest depth of the acid volatile sulfide (AVS) content maximum was at 437.5 cm (> 2 mu mol/g), which was deeper than that of the authigenic pyrite content maximum (at 141.5-380.5 cm); (3) delta S-34 of authigenic pyrite was positive (maximum: +15 parts per thousand) at depth interval of 250-380 cm; (4) the positive delta S-34 coincided with pyrite enrichment. Compared with the results obtained from the Black Sea sediments by Jorgensen and coworkers, these observations indicated that at the NH-1 site, the depth of the sulfate-methane interface (SMI) would be or once was at about 437.5-547.5 cm and the relatively shallow SMI depth suggested high upward methane fluxes. This was in good agreement with the results obtained from pore water sulfate gradients and core head-space methane concentrations in sediment cores collected in the area. All available evidence suggested that methane gas hydrate formation may exist or may have existed in the underlying sediments.

Development of the East Asian monsoon: Mineralogical and sedimentologic records in the northern South China Sea since 20 Ma

We here reconstruct the past change of the East Asian monsoon since 20 Ma using samples from Ocean Drilling Program (ODP) Site 1146 in the northern South China Sea based On a multi-proxy approach including a monomineralic quartz isolation procedure, identification of clay minerals by X-ray Diffraction (XRD) and grain-size analysis of isolated terrigenous materials. Terrigenous supply to ODP Site 1146 was dominated by changes in the strength of multiple sources and transport processes. Grain-size data modeled by an end-member modeling algorithm indicate that eolian dust from the and Asian inland and fluvial input have contributed on average 20% and 80% of total terrigenous material to ODP Site 1146, respectively. Specifically, about 40-53% of the total (quartz+feldspar) and only 6-11% of the total clay is related to eolian supply at the study site. Detailed analysis of the sedimentary environment, and clay minerals combined with previous studies shows that smectite originates mainly from Luzon, kaolinite from the Pearl River and illite and chlorite from the Pearl River, Taiwan and/or the Yangtze River. The proportion and mass accumulation rate (MAR) of the coarsest end-member EM1 (interpreted as eolian dust), ratios of (illite+chlorite)/smectite, (quartz+feldspar)% and mean grain-size of terrigenous materials at ODP Site 1146 were adopted as proxies for East Asian monsoon evolution. The consistent variation of these independent proxies since 20 Ma shows three profound shifts in the intensity of East Asian winter monsoon relative to summer monsoon, as well as aridity of the Asian continent, occurred at similar to 15 Ma, similar to 8 Ma and the youngest at about 3 Ma. In comparison, the summer monsoon intensified contemporaneously with the winter monsoon at 3 Ma. The phased uplift of the Himalaya-Tibetan plateau may have played a significant role in strengthening the Asian monsoon at similar to 15 Ma, 8 Ma and 3 Ma. (C) 2007 Elsevier B.V. All rights reserved.

Grain-size records at ODP site 1146 from the northern South China sea: Implications on the east Asian monsoon evolution since 20 Ma

273 samples from Ocean Drilling Program (ODP) Site 1146 in the northern South China Sea (SCS) were analyzed for grain-size distributions using grain-size class vs. standard deviation method and end-member modeling algorithm (EMMA) in order to investigate the evolution of the East Asian mon-soon since about 20 Ma. 10-19 mu m/1.3-2.4 mu m, the ratio of two grain-size populations with the highest variability through time was used to indicate East Asian winter monsoon intensity relative to summer monsoon. The mass accumulation rate of the coarsest end member EM1 (eolian), resulting from EMMA, can be used as a proxy of winter monsoon strength and Asian inland aridity, and the ratio of EM1/(EM2+EM3) as a proxy of winter monsoon intensity relative to summer monsoon. The combined proxies show that a profound enhancement of East Asian winter monsoon strength and winter monsoon intensity relative to summer monsoon occurred at about 8 Ma, and it is possible that the summer monsoon simultaneously intensified with winter monsoon at 3 Ma. Our results are well consistent with the previous studies in loess, eolian deposion in the Pacifc, radiolarians and planktonic foraminifera in the SCS. The phased uplift of the Himalaya-Tibetan Plateau may have played a significant role in strengthening the Asian monsoon at 8 Ma and 3 Ma.

Low-amplitude BSRs and gas hydrate concentration on the northern margin of the South China Sea

The passive northern continental margin of the South China Sea is rich in gas hydrates, as inferred from the occurrence of bottom-simulating reflectors (BSR) and from well logging data at Ocean Drilling Program (ODP) drill sites. Nonetheless, BSRs on new 2D multichannel seismic reflection data from the area around the Dongsha Islands (the Dongsha Rise) are not ubiquitous. They are confined to complex diapiric structures and active fault zones located between the Dongsha Rise and the surrounding depressions, implying that gas hydrate occurrence is likewise limited to these areas. Most of the BSRs have low amplitude and are therefore not clearly recognizable. Acoustic impedance provides information on rock properties and has been used to estimate gas hydrate concentration. Gas hydrate-bearing sediments have acoustic impedance that is higher than that of the surrounding sediments devoid of hydrates. Based on well logging data, the relationship between acoustic impedance and porosity can be obtained by a linear regression, and the degree of gas hydrate saturation can be determined using Archie's equation. By applying these methods to multichannel seismic data and well logging data from the northern South China Sea, the gas hydrate concentration is found to be 3-25% of the pore space at ODP Site 1148 depending on sub-surface depth, and is estimated to be less than values of 5% estimated along seismic profile 0101. Our results suggest that saturation of gas hydrate in the northern South China Sea is higher than that estimated from well resistivity log data in the gas hydrate stability zone, but that free gas is scarce beneath this zone. It is probably the scarcity of free gas that is responsible for the low amplitudes of the BSRs.

Geochemical and isotopic characteristics of volcanic rocks from the northern East China Sea shelf margin and the Okinawa Trough

Volcanic rocks both from the northern East China Sea (NECS) shelf margin and the northern Okinawa Trough are subalkaline less aluminous, and lower in High Field Strength Elements (HFSE). These rocks are higher in Large Ion Lithophile Elements (LILE), thorium and uranium contents, positive lead anomalies, negative Nb-Ta anomalies, and enrichment in Light Rare Earth Elements (LREE). Basalts from the NECS shelf margin are akin to Indian Ocean Mid-Ocean Ridge Basalt (MORB), and rhyolites from the northern Okinawa Trough have the highest Pb-207/Pb-208 and Pb-208/Pb-204 ratios. The NECS shelf margin basalts have lower Sr-87/Sr-86 ratios, epsilon(Nd) and sigma O-18 than the northern Okinawa Trough silicic rocks. According to K-40-Ar-40 isotopic ages of basalts from the NECS shelf margin, rifting of the Okinawa Trough may have been active since at least 3.65-3.86 Ma. The origin of the NECS shelf margin basalt can be explained by the interaction of melt derived from Indian Ocean MORB-like mantle with enriched subcontinental lithosphere. The basalts from both sides of the Okinawa Trough may have a similar origin during the initial rifting of the Okinawa Trough, and the formation of basaltic magmas closely relates to the thinning of continental crust. The source of the formation of the northern Okinawa Trough silicic rocks was different from that of the middle Okinawa Trough, which could have been generated by the interaction of basaltic melt with an enriched crustal component. From the Ryukyu island arc to East China, the Cenozoic basalts have apparently increasing trends of MgO contents and ratios of LREE to Heavy Rare Earth Elements (HREE), suggesting that the trace element variabilities of basalts may have been influenced by the subduction of the Philippine Sea plate, and that the effects of subduction of the Philippine Sea plate on the chemical composition of basaltic melts have had a decreasing effect from the Ryukyu island arc to East China.

Estimation of gas hydrate saturation using constrained sparse spike inversion: Case study from the northern South China Sea

Bottom-simulating reflectors (BSRs) were observed beneath the seafloor in the northern continental margin of the South China Sea (SCS). Acoustic impedance profile was derived by Constrained Sparse Spike Inversion (CSSI) method to provide information on rock properties and to estimate gas hydrate or free gas saturations in the sediments where BSRs are present. In general, gas hydrate-bearing sediments have positive impedance anomalies and free gas-bearing sediments have negative impedance anomalies. Based on well log data and Archie's equation, gas hydrate saturation can be estimated. But in regions where well log data is not available, a quantitative estimate of gas hydrate or free gas saturation is inferred by fitting the theoretical acoustic impedance to sediment impedance obtained by CSSI. Our study suggests that gas hydrate saturation in the Taixinan Basin is about 10 - 20% of the pore space, with the highest value of 50%, and free gas saturation below BSR is about 2 - 3% of the pore space, that can rise to 8 - 10% at a topographic high. The free gas is non-continuous and has low content in the southeastern slope of the Dongsha Islands. Moreover, BSR in the northern continental margin of the SCS is related to the presence of free gas. BSR is strong where free gas occurs.

Characteristics of clay minerals in the northern South China Sea and its implications for evolution of East Asian monsoon since Miocene

Clay mineral assemblages, crystallinity, chemistry, and micromorphology of clay particles in sediments from ODP Site 1146 in the northern South China Sea (SCS) were analyzed, and used to trace sediment sources and obtain proxy records of the past changes in the East Asian monsoon climate since the Miocene, based on a multi-approach, including X-ray diffraction (XRD) and scanning electron microscopy combined with energy dispersive X-ray spectrometry (SEM-EDS). Clay minerals consist mainly of illite and smectite, with associated chlorite and kaolinite. The illite at ODP Site 1146 has very well-to-well crystallinity, and smectite has moderate-to-poor crystallinity. In SEM the smectite particles at ODP Site 1146 often appear cauliflower-like, a typical micromorphology of volcanic smecites. The smectite at ODP Site 1146 is relatively rich in Si element, but poor in Fe, very similar to the smectite from the West Philippine Sea. In contrast, the chemical composition of illite at ODP Site 1146 has no obvious differences from those of the Loess plateau, Yellow River, Yangtze River, and Pearl River. A further study on sediment source indicates that smectite originates mainly from Luzon, kaolinite from the Pearl River, and illite and chlorite from the Pearl River, Taiwan and/or the Yangtze River. The clay mineral assemblages at ODP Site 1146 were not only controlled by continental eathering regimes surrounding the SCS, but also by the changing strength of the transport processes. The ratios of (illite+chlorite)/smectite at ODP Site 1146 were adopted as proxies for the East Asian monsoon evolution. Relatively higher ratios reflect strongly intensified winter monsoon relative to summer monsoon, in contrast, lower ratios indicate a strengthened summer monsoon relative to winter monsoon. The consistent variation of this clay proxy from those of Loess plateau, eolian deposition in the North Pacific, planktonic, benthic foraminifera, and black carbon in the SCS since 20 Ma shows that three profound shifts of the East Asian winter monsoon intensity, and aridity in the Asian inland and the intensity of winter monsoon relative to summer monsoon, occurred at about 15 Ma, 8 Ma, and the younger at about 3 Ma. The phased uplift of the Himalaya-Tibetan plateau may have played a significant role in strengthening the Asian monsoon at 15 Ma, 8 Ma, and 3 Ma.

Warming trend in northern East China Sea in recent four decades

Global warming has become a notable trend especially since an abrupt climate change in 1976. Response of the East China Sea (ECS) to the global warming trend, however, is not well understood because of sparse long-term observation. In this paper, hydrographic observation data of 1957-1996 are collected and reviewed to study climatological variability in northern ECS. Significant warming trends are found in both summer and winter. In summer, the average SST is about 0.46A degrees C higher during the period of 1977-1996 than that of 1957-1976, and the Taiwan Warm Current Water (TWCW) was strengthened. In winter, despite of the cooling effect in the coastal areas adjacent to the Changjiang (Yangtze) River Estuary (CRE), the average SST increase was about 0.53A degrees C during the same period. The causes of this SST warming up in summer are different from in winter. The warming trend and intensification of the TWCW in summer were primarily influenced by the strengthening of the Kuroshio transport, while the warming in winter was mainly induced by the variability of the climate system.

STUDY ON THE FORMATIONAL MECHANISM OF THE NORTHERN YELLOW (HUANGHAI) SEA COLD WATER MASS(I)

A hydrodynamic-thermodynamic equation set was set up to reflect the formational mechanism and evolution of the Northern Yellow (Huanghai) Sea cold water mass (NYSCWM) and its density circulation. Appropriate mathematical physical models were established by using some physical postulations. An approximate analytic solution to expound the distributions of temperature and three-dimensional current velocity, which can be used to expound the formational mechanism of the NYSCWM and its density circulation is obtained by using the theory of boundary layer and perturbational analyses.

STUDY ON THE FORMATIONAL MECHANISM OF THE NORTHERN YELLOW (HUANGHAI) SEA COLD WATER MASS .2. DISCUSSION ON THE SOLUTION OF THE MODEL

The theoretical solution of the model of the Northern Yellow (Huanghai) Sea Cold Water Mass (NYSCWM) reveals that the NYSCWM is mainly formed through the continuous temperature increase of the overwintered water body above the Northern Yellow Sea Depression (NYSD) after spring when heat is continuously conducted from the sea surface to the deeper layer. In the NYSCWM's growing period, (June-July), nonlinear vertical convection and advection effects continuously increase, and are gradually balanced by the heat diffusion effect as the temperature increases from the surface to the bottom, which leads to the formation of an intensive thermocline and lateral front. Meanwhile, the three-dimensional circulation correspondingly occurs. In the NYSCWM's entire growing period, the horizontal circulation is always in the cyclonic motion, while the vertical circulation passes through a transition from a period with the cold centre as downwelling to a period with the cold centre as upwelling.

Rifting process and formation mechanisms of syn-rift stage prolongation in the deepwater basin, northern South China Sea

Based on the latest seismic and geological data, tectonic subsidence of three seismic lines in the deepwater area of Pearl River Mouth Basin (PRMB), the northern South China Sea (SCS), is calculated. The result shows that the rifting process of study area is different from the typical passive continental margin basin. Although the seafloor spreading of SCS initiated at 32 Ma, the tectonic subsidence rate does not decrease but increases instead, and then decreases at about 23 Ma, which indicates that the rifting continued after the onset of seafloor spreading until about 23 Ma. The formation thickness exhibits the same phenomenon, that is the syn-rift stage prolonged and the post-rift thermal subsidence delayed. The formation mechanisms are supposed to be three: (1) the lithospheric rigidity of the northern SCS is weak and its ductility is relatively strong, which delayed the strain relaxation resulting from the seafloor spreading; (2) the differential layered independent extension of the lithosphere may be one reason for the delay of post-rift stage; and (3) the southward transition of SCS spreading ridge during 24 to 21 Ma and the corresponding acceleration of seafloor spreading rate then triggered the initiation of large-scale thermal subsidence in the study area at about 23 Ma.

Characteristics of nonlinear internal waves observed in the northern South China Sea

The South China Sea (SCS) is one of the most active areas of internal waves. We undertook a program of physical oceanography in the northern South China Sea from June to July of 2009, and conducted a 1-day observation from 15:40 of June 24 to 16:40 of June 25 using a chain of instruments, including temperature sensors, pressure sensors and temperature-pressure meters at a site (117.5A degrees E, 21A degrees N) northeast of the Dongsha Islands. We measured fluctuating tidal and subtidal properties with the thermistor-chain and a ship-mounted Acoustic Doppler Current Profiler, and observed a large-amplitude nonlinear internal wave passing the site followed by a number of small ones. To further investigate this phenomenon, we collected the tidal constituents from the TPXO7.1 dataset to evaluate the tidal characteristics at and around the recording site, from which we knew that the amplitude of the nonlinear internal wave was about 120 m and the period about 20 min. The horizontal and vertical velocities induced by the soliton were approximately 2 m/s and 0.5 m/s, respectively. This soliton occurred 2-3 days after a spring tide.

Submesoscale activity over the shelf of the northern South China Sea in summer: simulation with an embedded model

We applied a primitive equation ocean model to simulate submesoscale activities and processes over the shelf of the northern South China Sea (NSCS) with a one-way nesting technology for downscaling. The temperature and density fields showed that submesoscale activities were ubiquitous in the NSCS shelf. The vertical velocity was considerably enhanced in submesoscale processes and could reach an average of 58 m per day in the subsurface. At this point, the mixed layer depth also was deepened along the front, and the surface kinetic energy also increased with the intense vertical movement induced by submesoscale activity. Thus, submesoscale stirring/mixing is important for tracers, such as temperature, salinity, nutrients, dissolved organic, and inorganic carbon. This result may have implication for climate and biogeochemical investigations.

Evolution of freshwater plumes and salinity fronts in the northern Bay of Bengal

[1] The evolution of freshwater plumes and the associated salinity fronts in the northern Bay of Bengal ( henceforth the bay) is studied using rotated empirical orthogonal function (REOF) analysis and extended associate pattern analysis (EAPA). The results show that sea surface salinity distribution is featured by eastern-bay and western-bay plumes in the northern bay during different seasons. The western-bay plume begins in early July, peaks in late August, and then turns into a bay-shaped plume with the two plumes in either side of the bay, which peaks in late October. The southward extension of the western-bay plume can be explained by the southwestward geostrophic flow associated with the cyclonic gyre in the northern bay, which counters the northeastward Ekman drift driven by wind stress. The offshore expansion of the western-bay plume is induced by the offshore Ekman drift which also produces a salinity front near the east coast of India. The bay-shaped plume appears when the cyclonic gyre shifts westward and a weak anticyclonic gyre occupies the northeastern bay. As the season advances, the western part of the bay-shaped plume decays while the eastern part persists until the following June, which is believed to be associated with the anticyclonic gyre in the northern bay. The evolution of the plumes except the eastern part of the bay-shaped plume in fall can be partly explained by the seasonal variation of mass transport associated with the Sverdrup balance. The fact that the western-bay (eastern-bay) plume appears when surface freshwater flux in the northeastern bay increases ( decreases) dramatically suggests that the plumes are not produced directly by surface freshwater flux. River discharge seems to be the freshwater source for the plumes and has little to do with the evolution of the plumes.