Study on methane hydration process in a semi-continuous stirred tank reactor

The methane hydration process is investigated in a semi-continuous stirred tank reactor. Liquid temperatures and reaction rates without stirrer are compared with those occurring with stirrer, while at the same time better stirring conditions of the methane hydration process are given by the experiments. Some basic data of fluid mechanics, for example, stirring Reynolds number, Froucle number and stirrer power, are calculated during the methane hydration process, which can be applied to evaluate stirrer capacity and provide some basic data for a scaled up reactor. Based on experiment and calculations in this work, some conclusions are drawn. First, the stirrer has great influence on the methane hydration process. Batch stirring is helpful to improve the mass transfer and heat transfer performances of the methane hydration process. Second, induction time can be shortened effectively by use of the stirrer. Third, in this paper, the appropriate stirring velocity and stirring time were 320 rpm and 30 min, respectively, at 5.0 MPa, for which the storage capacity and reaction time were 159.1 V/V and 370 min, respectively. Under the condition of the on-flow state, the initial stirring Reynolds number of the fluid and the stirring power were 12,150 and 0.54 W, respectively. Fourth, some suggestions, for example, the use of another type of stirrer or some baffles, are proposed to accelerate the methane hydration process. Comparing with literature data, higher storage capacity and hydration rate are achieved in this work. Moreover, some fluid mechanics parameters are calculated, which can provide some references to engineering application.

Enhanced Thermal Shock Resistance of Ceramics through Biomimetically Inspired Nanofins

We propose here a new method to make ceramics insensitive to thermal shock up to their melting temperature. In this method the surface of ceramics was biomimetically roughened into nanofinned surface that creates a thin air layer enveloping the surface of the ceramics during quenching. This air layer increases the heat transfer resistance of the surface of the ceramics by about 10 000 times so that the strong thermal gradient and stresses produced by the steep temperature difference in thermal shock did not occur both on the actual surface and in the interior of the ceramics. This method effectively extends the applications of existing ceramics in the extreme thermal environments.

超临界压力下航空煤油水平管内对流换热特性数值研究

采用RNG(renormalization group)k-ε湍流模型和近壁区的Wolfstein一方程模型对超临界压力下大庆RP-3航空煤油在水平圆管内的流动和换热特性进行了数值研究.超临界压力下,由于航空煤油在拟临界点附近热物性的剧烈变化,浮升力将引起显著的二次流动.二次流动使得水平圆管的下表面湍流强度和对流换热增强,而上表面的湍流强度和对流换热减弱.最后分析了两种水平管内对流换热受浮升力影响判别标准在超临界流体中的适用性

超临界压力下航空煤油流动与传热特性试验

本文针对超燃冲压发动机再生冷却系统运行条件,实验研究了大庆RP-3煤油在超临界压力下的流动和传热特性,目的在于研究煤油在各种工况下的流动参数变化以及对流传热规律. 煤油通过二级煤油加热/输运系统加热,试验的煤油压力约2.6M~5.0MPa,油温约300~800 K. 相应的壁面热流密度为10~300 kW/m2. 通过油温与壁温的同步测量,结合非定常传热分析,获得了超临界压力下、亚/超临界温度范围内煤油的流动和传热物理参量的变化曲线

Thermal effects on Rayleigh-Marangoni-Benard instability in a system of superposed fluid and porous layers

Thermal effects of the heat transfer at free surface (represented by Biot number) on the Rayleigh-Marangoni-Benard instability in a system of liquid-porous layers with top free surface are investigated numerically. The results indicate that this thermal effect can evidently lead to the mode transition of convection, which is overlooked in previous works. (C) 2010 Elsevier Ltd. All rights reserved.

超临界压力下航空煤油圆管流动和传热的数值研究

对超临界压力下大庆RP-3航空煤油在小管道内的流动、传热过程进行了数值研究. 湍流模拟采用了 RNG k-ε两方程模型和Wolfstein一方程模型结合的两层模型;同时, 采用煤油的10组分替代模型以及NIST Supertrapp程序库对大庆3号航空煤油的热物理和输运特性进行了确定. 圆管传热的计算条件为:入口压力4 MPa, 入口温度300 K, 质量流量范围:0.06~0.12 kg/s, 壁面热流密度范围:300~700 kW/m~2. 计算结果显示, 煤油的流动和传热特性比水、二氧化碳等简单化合物复杂得多. 在超临界压力下, 煤油的吸热升温导致其热物理特性以及流动特性均发生剧烈变化, 其中, 雷诺数沿管道方向上升了至少一个量级, 而普朗特数下降了一个量级. 在加热开始段, 煤油的对流传热系数迅速上升;当壁面温度超过其拟临界温度后, 对流传热系数略有所回落;随着煤油温度的进一步上升, 传热系数又得到明显增强. 计算表明, 煤油对流换热特性的变化与煤油复杂的高温热物理特性以及湍流流动在近壁区的增强和抑止有关

微重力气液两相流动与池沸腾传热

综述了近年来中国科学院微重力重点实验室(国家微重力实验室)完成的一系列微重力气液两相流动与池沸腾传热方面的地基实验、飞行实验和理论研究等方面获得的主要成果.在微重力气液两相流动方面, 提出了半理论Weber数模型用于预测微重力条件下气液两相弹一环状流转换, 并采用Monte Carlo方法, 针对气泡初始尺寸对泡一弹状流转换的影响进行数值研究.通过俄罗斯"和平号"空间站与IL-76失重飞机实验, 获得了微重力下的气液两相流型图, 与此同时在地面利用小尺度毛细管模型模拟了微重力气液两相流动特征.实验测量了微重力气液两相流压降, 并基于微重力流动特性建立了一个泡状流压降关联模型.在微重力池沸腾传热方面, 利用我国返回式卫星完成了两次空间实验, 其中, 第22颗返回式卫星搭载铂丝表面R113池沸腾实验采用控制温度的稳态加热方式, 而实践8号育种卫星搭载平面FC-72池沸腾实验则采用控制加热电压的准稳态加热方式.同时, 还进行了地面常重力和落塔短时微重力条件下的对比实验研究.观察到丝状加热表面微重力时轻微的传热强化现象, 而平板加热表面微重力核态池沸腾低热流时传热强化、高热流时传热恶化.微重力实验中观察到气泡脱落前存在横向运动现象, 据此分析了气泡行为与传热之间关系, 并提出了一个预测丝状加热表面气泡脱落直径的半理论模型.旨在对相关领域的进一步发展和空间两相流系统的应用提供数据及理论支持

Pool Boiling on Wire in Microgravity - What Have We Learned

In the past years, steady pool boiling of degassed R113 on thin platinum wires has been studied systematically in our lab, including experiments in long-term microgravity aboard RS-22, in short-term microgravity in the Drop Tower Beijing / NMLC, and in normal gravity on the ground. Slight enhancement of nucleate boiling heat transfer is observed in microgravity, while dramatic changes of bubble behaviors are much evident. The value of CHF in microgravity is lower than that in normal gravity, but it can be predicted well by the Lienhard-Dhir correlation, although the dimensionless radius in the present case is far beyond its initial application range. The scaling of CHF with gravity is thus much different from the traditional viewpoint. Considering the influence of the Marangoni effects, the different characteristics of bubble behaviors in microgravity have been explained. A new bubble departure model has also been proposed, which can predict the whole observation both in microgravity and in normal gravity.

等离子体电弧炉内流动与传热数值模拟

本文采用磁流体动力学(MHD)模型对直流等离子体自由燃烧电弧和电弧炉内部的流动与传热进行了数值模拟研究. 通过对基于磁矢量势描述的电磁场方程组和流体力学方程组的耦合迭代计算, 求解得到了流体的温度场和速度场等, 计算结果清晰地反映出等离子体电弧的高温阴极射流现象, 并与同行的实验和数值结果进行了对比. 本模拟方法和结果对于电弧炉的工业应用和优化设计有重要的指导意义.

Numerical Simulation of a Low-power Hydrazine Arcjet Thruster

A modeling study is conducted to investigate the plasma flow and heat transfer characteristics of low-power (kW class) arc-heated thrusters (arcjets) with 2:1 hydrogen/nitrogen to simulate decomposed hydrazine as the propellant. The all-speed SIMPLE algorithm is employed to solve the governing equations, which take into account the effects of compressibility, the Lorentz force and Joule heating, as well as the temperature- and pressure-dependence of the gas properties. Typical computed results about the temperature, velocity and Mach number distributions within arcjet thruster are presented for the case with arc current of 9 A and inlet stagnant pressure of 3.3×105 Pa to show the flow and heat transfer characteristics. It is found that the propellant is heated mainly in the near-cathode and constrictor region, with the highest plasma temperature appearing near the cathode tip, and the flow transition from the subsonic to supersonic regime occurs within the constrictor region. The effect of gas viscosity on the plasma flow within arcjet thruster is examined by an additional numerical test using artificially reduced values of gas viscosity. The test results show that the gas viscosity appreciably affects the plasma flow and the performance of the arcjet thruster for the cases with the hydrazine or hydrogen as the propellant. The integrated axial Lorentz force in the thruster nozzle is also calculated and compared with the thrust force of the arcjet thruster. It is found that the integrated axial Lorentz force is much smaller than the thrust force for the low-power arcjet thruster. Modeling results for the NASA 1-kW class arcjet thruster with simulated hydrazine as the propellant are found to be reasonably consistent with available experimental data.

Shallow gas in the muddy sediments of Eckernförde Bay, Germany

The seafloor of central Eckernförde Bay is characterised by soft muddy sediments that contain free methane gas. Bubbles of free gas cause acoustic turbidity which is observed with acoustic remote sensing systems. Repeated surveys with subbottom profiler and side scan sonar revealed an annual period both of depth of the acoustic turbidity and backscatter strength. The effects are delayed by 3–4 months relative to the atmospheric temperature cycle. In addition, prominent pockmarks, partly related to gas seepage, were detected with the acoustic systems. In a direct approach gas concentrations were measured from cores using the gas chromatography technique. From different tests it is concluded that subsampling of a core should start at its base and should be completed as soon as possible, at least within 35 min after core recovery. Comparison of methane concentrations of summer and winter cores revealed no significant seasonal variation. Thus, it is concluded that the temperature and pressure influences upon solubility control the depth variability of acoustic turbidity which is observed with acoustic remote sensing systems. The delay relative to the atmospheric temperature cycle is caused by slow heat transfer through the water column. The atmospheric temperature cycle as ‘exiting function’ for variable gas solubility offers an opportunity for modelling and predicting the depth of the acoustic turbidity. In practice, however, small-scale variations of, e.g., salinity, or gas concentration profile in the sediment impose limits to predictions. In addition, oceanographic influences as mixing in the water column, variable water inflow, etc. are further complications that reduce the reliability of predictions.

One century record of contamination by polycyclic aromatic hydrocarbons and polychlorinated biphenyls in core sediments from the southern Yellow Sea

Sixteen polycyclic aromatic hydrocarbons (PAHs) and 28 polychlorinated biphenyls (PCBs) were measured at a 2-cm interval in a core sample from the middle of the southern Yellow Sea for elucidating their historical variations in inflow and sources. The chronology was obtained using the Pb-210 method. PAHs concentrations decreased generally with depth and two climax values occurred in 14-16 cm and 20-22 cm layers, demonstrating that the production and usage of PAHs might reach peaks in the periods of 1956-1962 and 1938-1944. The booming economy and the navy battles of the Second World War might explain why the higher levels were detected in the two layers. The result of principal component analysis (PCA) revealed that PAHs were primarily owing to the combustion product. Down-cored variation of PCB concentrations was complex. Higher concentrations besides the two peaks being the same as PAHs were detected from 4 to 8 cm, depositing from 1980 to 1992, which probably resulted from the disposal of the out-dated PCB-containing equipment. The average Cl percentage of PCBs detected was similar to that of the mixture of Aroclor 1254 and 1242, suggesting they might origin from the dielectrical and heat-transfer fluid. The total organic carbon (TOC) content played a prevalent role in the adsorption of high molecular weight PAHs (>= 4-ring), while no obvious relationship among total PCBs, the concentration of congeners, and TOC was found.

Observation and modeling for terrestrial processes in alpine meadow

The water-heat transfer process between land and atmosphere in Haibei alpine meadow area has been systematically observed. A multi-layer coupling model for land-atmosphere interaction was presented with special attention paid to the moisture transfer in leaf stomata under unsaturated condition. A profound investigation on the physical process of turbulent transfer inside the vegetation has been performed with a revised formula of water absorption for root system. The present model facilitates the study of vertically distributed physical variables in detail. Numerical simulation was conducted according to the transfer process of Kinesia humility meadow in the area of Haibei Alpine Meadow Ecosystem Station, CAS. The calculated results agree well with observation.