Decomposition of transformer oil under ultrasonic irradiation during degassing process

In the degassing process of transformer oil with ultrasonic waves, decomposition of the oil was observed. Light hydrocarbons, including methane, ethane, ethylene, acetylene, propane etc, were found to be released continuously from the oil into headspace within a closed vial placed in an ultrasonic field. The gases came from decomposition of hydrocarbon Molecules under cavitation effect.

Climate change, sea level rise and integrated coastal zone management: An IPCC approach

Expansion of economic activities, urbanisation, increased resource use and population growth are continuously increasing the vulnerability of the coastal zone. This vulnerability is now further raised by the threat of climate change and accelerated sea level rise. The potentially severe impacts force policy-makers to also consider long-term planning for climate change and sea level rise. For reasons of efficiency and effectiveness this long-term planning should be integrated with existing short-term plans, thus creating an Integrated Coastal Zone Management programme. As a starting point for coastal zone management, the assessment of a country's or region's vulnerability to accelerated sea level rise is of utmost importance. The Intergovernmental Panel on Climate Change has developed a common methodology for this purpose. Studies carried out according to this Common Methodology have been compared and combined, from which general conclusions on local, regional and global vulnerability have been drawn, the latter in the form of a Global Vulnerability Assessment. In order to address the challenge of coping with climate change and accelerated sea level rise, it is essential to foresee the possible impacts, and to take precautionary action. Because of the long lead times needed for creating the required technical and institutional infrastructures, such action should be taken in the short term. Furthermore, it should be part of a broader coastal zone management and planning context. This will require a holistic view, shared by the different institutional levels that exist, along which different needs and interests should be balanced.

On the induction period of methane aromatization over Mo-based catalysts

The behavior of different species during the temperature-programmed surface reaction (TPSR) of methane over various catalysts is traced by an online mass spectrometer, It is demonstrated that the transformation of MoO3 to molybdenum carbide hinders the activation of methane as well as the succeeding aromatization in the TPSR, If this transformation process is done before the reaction, the temperature needed for methane activation and benzene formation will be greatly lowered (760 and 847 K, respectively). On the basis of comparison of the catalytic behavior of molybdenum supported on different zeolites, it is suggested that the initial activation of methane is the rate-determining step of this reaction. For the cobalt catalysts supported on HMCM-22 or Mo catalysts supported on TiO2, no benzene formation could be observed during the TPSR, However, the prohibition of benzene formation is different in nature over these two catalysts: the former lacks the special properties exhibited by molybdenum carbide, which can continuously activate methane even when multiple layers of carbonaceous species are formed on its surface, while the latter cannot accomplish the aromatization reaction since there are no Bronsted acid sites to which the activated intermediates can migrate, although the activation of methane can be achieved on it. Only for the catalysts that possess both of these properties, together with the special channel structure of zeolite, can efficient methane aromatization be accomplished. (C) 2000 Academic Press.

Degradation products formed during UV-irradiation of humic waters

Natural humic lake water and aqueous solutions of humic substances were treated with ultraviolet (UV) radiation (λ = 254 nm). The effects on the dissolved organic carbon content (DOC) and the absorbance at 254 nm (Abs254) and 460 nm (Abs460) were monitored and the identity and concentrations of gas chromatographable organic degradation products were determined. The DOC content and the (Abs254) of the humic solutions decreased continuously with increasing UV-dose. Several aromatic and aliphatic degradation products were identified and roughly quantified The concentrations of aromatic hydroxy carboxylic acids and hydroxy aldehydes increased when relatively low UV-doses were used, but declined following further irradiation. The concentrations of aliphatic dibasic acids increased over the full range of UV-doses

On-line voltammetric monitoring of dissolved Cu and Ni in the Gulf of Cadiz, south-west Spain

Geochemical processes in estuarine and coastal waters often occur on temporally and spatially small scales, resulting in variability of metal speciation and dissolved concentrations. Thus, surveys, which are aimed to improve our understanding of metal behaviour in such systems, benefit from high-resolution, interactive sampling campaigns. The present paper discusses a high-resolution approach to coastal monitoring, with the application of an automated voltammetric metal analyser for on-line measurements of dissolved trace metals in the Gulf of Cadiz, south-west Spain. This coastal sea receives metal-rich inputs from a metalliferous mining area, mainly via the Huelva estuary. On-line measurements of dissolved Cu, Zn, Ni and Co were carried out on-board ship during an eight-day sampling campaign in the study area in June 1997. A pumping system operated continuously underway and provided sampled water from a depth of ca. 4 m. Total dissolved metal concentrations measured on-line in the Gulf of Cadiz ranged between <5 nM Cu (<3 nM Ni) ca. 50 km off-shore and 60–90 nM Cu (5–13 nM Ni) in the vicinity of the Huelva estuary. The survey revealed steep gradients and strong tidal variability in the dissolved metal plume extending from the Huelva estuary into the Gulf of Cadiz. Further on-line measurements were carried out with the automatic metal monitor from the bank of the Odiel estuary over a full tidal cycle, at dissolved metal concentrations in the μM range. The application confirmed the suitability of the automated metal monitor for coastal sampling, and demonstrated its adaptability to a wide range of environmental conditions in the dynamic waters of estuaries and coastal seas. The near-real time acquisition of dissolved metal concentrations at high resolution enabled an interactive sampling campaign and therefore the close investigation of tidal variability in the development of the Huelva estuary metal plume.

土壤持水特征测定中质量含水量、吸力和容重三者间定量关系I.填装土壤

在试验过程中,通常采用一个土样进行连续试验来测定土壤的持水特征。此时,土样的有机质、黏粒矿物类型和阳离子交换量等性质基本保持不变,而土壤的容重在水力学和机械压力共同作用下会发生很大的变化。因此,我们认为实测的土壤持水特征不再是土壤吸力和含水量相对应的一条曲线,而是由土壤质量含水量、吸力和容重三变量共同确定的一个曲面。本文在Brooks-Corey土壤水分特征曲线模型的基础上,提出了两种描述土壤质量含水量、吸力和容重三变量关系的曲面模型,分析了模型的优缺点和适用条件,并采用离心机石蜡控容重法实测了四种质地填装土壤的三变量特征曲面。研究结果表明:土壤持水特征是由土壤质量含水量、吸力和容重三变量共同确定的一个曲面这一假设是合理的;类似于Brooks-Corey模型的两种幂函数经验曲面模型能够合理地描述填装土壤的实测数据,决定系数均大于0.94;模型Ⅰ的拟合效果略好于模型Ⅱ,但模型Ⅱ包含两个物理意义明确的参数,具有一定的优势。这一研究将为校正容重变化对土壤水力学参数的影响提供新的途径。

黄土丘陵区几种林木茎干径向生长的日变化及其对环境因素的响应

利用树木径向生长仪研究了黄土丘陵区6年生油松(Pinus tabulaef ormis)、山杨(Populus davidiana)和辽东栎(Quercus liaotungensis)及林下灌木胡颓子(Elaegnus umbellata)4种林木整个生长季茎干的径向变化,发现4种林木的径向变化表现为膨胀收缩旋回增长的模式。在整个生长季中,山杨从5月到10月径向持续增长,增长时间最长;而油松和胡颓子的径向生长主要发生在7月份,从8月份开始其增长速率变缓;辽东栎在整个生长季节的径向生长最小。在整个生长季内,山杨径向增长了2.63 mm,胡颓子为0.64 mm,油松和辽东栎则分别为0.40 mm和0.26 mm。辽东栎日收缩量与膨胀量明显大于其他树种。通过对影响林木径向生长的15种环境因子进行主成分分析后,将主要环境因子归结为温度影响因子、湿度影响因子和降水影响因子3个主成分,并提取了影响该区几种林木生长的主要环境因子:日大于0℃的积温、最低6 h相对湿度和日降雨量。采用线性逐步回归方法,建立了日膨胀量与日收缩量与3个主要环境因子之间的关系。发现日收缩量与日大于0℃的积温成正相关,而与最低6 h相对湿度和日降雨...

半干旱区柠条林利用土壤水分深度和耗水量

植物根系利用土壤水分深度和耗水量是研究植物与土壤水关系的基础。以柠条为对象,采用中子仪,对撂荒地和柠条林地土壤水分进行长期定位观测和分析。结果表明,2002年内,随着时间推移,柠条利用土壤水分深度从播种时的2cm左右,迅速增加到9月1日的90cm,10月15日的110cm,11月1日的170cm,到11月15日柠条利用土壤水分深度为220cm;除丰水年(2年生)柠条土壤储水量增加了122.8mm外,随着林龄的增加和降雨量等的变化,植物利用土壤水分的深度和耗水量增加,土壤储水量下降。到2004年生长季末,3年生柠条林地100cm土层出现土壤干层,5年生柠条林地剖面60—300cm土层出现土壤干层。此时需要采取措施,控制柠条生长、密度和耗水量,实现土壤水资源的可持续利用。

延安试区土壤干层现状分析

近年来 ,以林草地地力衰退为特征的人工林草地土壤退化日趋严重 ,其中以土壤水分严重亏缺为特征的土壤干化现象愈益引起了人们的重视。土壤干化的直接后果是形成土壤干层 ,导致土壤退化 ,植物生长速率减缓 ,群落衰败以至大片死亡 ,严重地威胁到中国中北方地区特别是黄土高原地区生态环境的建设。因此 ,研究和解决土壤干层问题已成为黄土高原植被建设的迫切任务。根据现有土壤水分资料 ,初步分析了延安试区植被下的土壤干层现状 ,对不同林草植被下的干层状况做了比较 ,并提出了解决土壤干层问题的意义

黄土丘陵区小流域土壤特性时空动态变化研究

以安塞大南沟为例首次在流域范围内对几项土壤表面特性进行连续定位测定,初步研究了其时空动态变化规律。结果表明,大南沟流域内土壤随机糙度、抗剪力和团粒稳定性具有一定的空间变化规律,不同土地利用方式间有显著差异。不同地貌类型农耕地土壤随机糙度、抗剪力无明显差异,而团粒稳定性则差异显著。年内各测定周期间土壤随机糙度、抗剪力和团粒稳定性随时间变异不显著。

一个改进的随机动力学水平衡模型及其应用研究Ⅱ.应用

本文用黄土高原长武农业生态试验站的冬小麦长期定位试验资料对改进的随机动力学水平衡模型进行了准确性检验 .从模型对参数反映的敏感性分析和模型计算值与数值模型WAVES的比较 ,以及模型对黄土区旱作高生产力的水分环境效应的评价结果 ,均证明改进的随机动力学水平衡模型能比较准确地预测一定生产力水平、特定生态系统平衡体系水均衡要素的定量分配和土壤含水量的动态变化 .

中国化肥施用与粮食生产的进程、前景与布局

根据试验研究资料与调查结果，对中国粮食生产与化肥施用进行了时空宏观分析。结果表明，化肥施用量是２０ 世纪中国粮食生产重大成就之一，化肥对粮食产量的贡献率平均为４６．４３％ ，每吨化肥科学施用可增产粮食８．８４ｔ。２１ 世纪中国粮食产量与化肥施量将持续增长。粮食每增产１００×１０６ｔ，则化肥最少需增施１０．２２～１１．０８×１０６ｔ。为实现粮食持续发展与化肥高效施用，必须实施发展东部平原带，提高中部高原带，开发西部高寒荒漠带的战略布局。各带都应大力发展优质粮食与特用粮食生产，以提高国产粮食的市场占有率。

耕作制度发展矛盾及对策——以黄土高原为例

建国 5 0年来 ,我国的耕作制度发生了翻天覆地的变化 ,耕作制度的改革有新的起点与突破 ,仅以占全世界 7%的耕地养活了占全世界 2 2 %的人口 ,取得了举世瞩目的成就。本文根据中国近几年耕作制度合理利用自然资源和社会资源 ,运用各种高新技术 ,实现农业持续、稳定和高效的增产 ,使农业生产各关联部门得以协调发展的实际 ,阐明了耕作制度的发展趋势 ,探讨了耕作制度在新形势下面临的挑战 ,研究了耕作技术发展的对策 ,可供同类地区研究者参考。

土壤养分对小偃22叶片光合特性影响的初步研究

在大田不同供肥条件下 ,于小麦灌浆后期对小麦旗叶光合特性参数进行了连续测定。结果表明 ,小麦叶片气体交换参数均有明显的日变化趋势 ,肥力条件对其日变化进程具有明显的调控作用。不施肥处理小麦叶片 Pn有明显午休现象 ,而低肥处理第一高峰不明显 ,没有明显午休现象 ;高肥处理的 Pn呈单峰曲线 ,峰值来得也较晚。养分条件可改善小麦叶片水分利用效率

延安试区人工刺槐林地的土壤干层分析

8 0年代以来 ,以林草地地力衰退为特征的人工林草地土壤退化日趋严重 ,其中以土壤水分严重亏缺为特征的土壤干化现象愈益引起了人们的重视。土壤干化的直接后果是形成土壤干层 ,导致土壤退化 ,植物生长速率减缓 ,群落衰败以至大片死亡 ,严重地威胁到我国北方地区特别是黄土高原地区生态环境的建设。因此 ,研究和解决土壤干层问题已成为黄土高原植被建设的迫切任务。根据延安试区的土壤水分和植被生长状况调查资料 ,初步分析了不同条件下刺槐人工林地的水分状况。结果表明 :试区刺槐人工林地普遍形成了土壤干层 ,且已相当严重 ;坡向对土壤干层有明显影响 ,阳坡形成的干层较阴坡严重 ;坡度愈大 ,土壤干化愈剧烈 ;林龄对干层严重程度影响不明显。同时 ,研究指出了解决土壤干层问题的意义。