A highly reduced polyoxoanion with phosphorus-centered alternate layers of Mo/V oxides, [(PMo2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)](9-)

An unusual polyoxometalate [H2N(C2H4)(2)NH2](4)(H3O)[(PMO2Mo6V4O40)-Mo-V-V-VI-O-IV((VO)-O-IV)(2)].H2O is hydrothermally synthesized and characterized by IR, UV-VIS, elemental analyses, X-ray photoelectron spectrum, ESR, TG and Single crystal X-ray diffraction. The title compound crystallizes in the orthorhombic space group Pbca with a = 15-227(5), b = 19.491(4), c = 18.737(3) Angstrom, V = 5123(2) Angstrom(3), Z = 4, and R-1 (wR(2)) = 0.0726(0.1416). The compound contains an unusual highly reduced pseudo-Keggin type polyoxoanion and exhibits an interesting phosphorus-centered alternate arrangement of layers of molybdenum and vanadium oxides.

Electrochemical investigation of DNA adsorbed on conducting polymer modified electrode

Detection of DNA is a very important task for molecular biology and biomedical field. We have investigated electrochemical behavior of double-stranded DNA and single-stranded DNA adsorbed on conducting polymer modified electrode in presence of cobalt complex. The possibility of using such electrode as gene detector is discussed.

EPITAXIAL CRYSTALLIZATION OF HDPE ON IPP IN HDPE/IPP BLENDS

Unique crystalline morphologies of solution-cast films of HDPE/iPP blends were investigated by means of transmission electron microscopy (TEM), electron diffraction, metal shadowing and specimen-tilt techniques. The unique morphologies come from an epitaxial crystallization of HDPE on iPP. The contact planes of the two kinds of crystals are (100) of HDPE and (010) of iPP, while the intercrossing angle between their chain axes is about 50-degrees. The HDPE existed with different crystalline morphologies in the two kinds of crystalline regions of iPP spherulites, i.e. cross-hatched and single-crystal-type structures. Based on structural analysis, two models of epitaxial growth of HDPE on iPP are proposed.

Bromophenol derivatives from the red alga Rhodomela confervoides

Eight new bromophenol derivatives, 2,3-dibromo-4,5-dihydroxybenzyl methyl sulfoxide (1), 4-(2,3-dibromo-4,5-dihydroxyphenyl)-3-butene-2-one (2), 2-(3-bromo-5-hydroxy-4-methoxyphenyl)-3-(2,3-dibromo-4,5-dihydroxyphenyl)propionic acid (3), 2-(3-bromo-5-hydroxy-4-methoxyphenyl)-3-(2,3-dibromo-4,5-dihydroxyphenyl)propionic acid methyl ester (4), 2-phenyl-3-(2,3-dibromo-4,5-dihydroxyphenyl)propionic acid (5), 4'-methoxy-2",3',3"-tribromo-4",5',5"-trihydroxydiphenylacetic acid (6), and 3-bromo-5-hydroxy-4-methoxyphenylacetic acid (7) and its methyl ester (8), together with a known bromophenol, 3-bromo-5-hydroxy4-methoxybenzoic acid (9), were isolated from the red alga Rhodomela confervoides. Their structures were elucidated by spectroscopic methods including IR, EIMS, FABMS, ESIMS, HRFABMS, HRESIMS, 1D and 2D NMR, and single-crystal X-ray structure analysis. Compounds 1-4, 8, and 9 were found inactive against several human cancer cell lines and microorganisms.

Unprecedented 5,5-connected (4(7)center dot 6(3)) (4(8)center dot 6(2)) structural topology: A lead biphosphonate with double layered structure

A new lead(II) phosphonate, Pb[(PO3)(2)C(OH)CH3]center dot H2O (1) was hydrothermally synthesized and characterized by IR, elemental analysis, UV, TGA, SEM, and single crystal X-ray diffraction analysis. X-ray crystallographic study showed that complex 1 has a two-dimensional double layered hybrid structure containing interconnected 4- and 12-membered rings and shows an unusual (5,5)-connected (4(7) . 6(3)) (4(8) .6(2)) topology. (C) 2008 Elsevier B.V. All rights reserved.

轮式移动机器人轨迹跟踪的最优控制

深入分析了轮式移动机器人的运动状态,建立了WMR路径偏差系统的非线性数学模型。应用小偏差线性化理论,将该多输入多输出非线性系统简化成一个单输入单输出线性系统。然后基于线性二次型调节器理论进行了系统最优控制器的设计,并针对该理论中加权矩阵Q与R难以确定的问题,从控制效果出发,采用自适应遗传算法对其进行了优化。实现了移动机器人对预定轨迹的满意鲁棒跟踪,同时满足了实时性要求。实验结果证明了该方法的正确性与实用性。

转子系统油膜振荡的小波包分解与频带能量比例特征分析

在介绍小波包分解原理的基础上 ,对试验测得的单盘单跨转子系统的油膜振荡非平稳信号用小波包分解方法进行了研究。采用db44小波基函数进行 4层小波包分解。给出了各频带内分解信号的特点及频带能量比例 ,其中第 3频带是该转子系统在 960 0r/min时产生油膜振荡的特征频带。得到的试验数据及其分析结果对转子系统油膜振荡研究和旋转机械状态监测等具有重要意义。

基于MCX314as的运动控制器设计

文章介绍了用C8051F120单片机和MCX314as组成运动控制器的方案。该方案应用存储器扩展的方法为运动控制芯片MCX314as和液晶显示模块MT22G06B的内部寄存器分配地址空间,从而实现C8051F120单片机对运动控制芯片和液晶模块的控制作用。文章还给出了MCX314和MT22G06B的驱动程序架构。

成批生产计划调度的集成建模与优化

针对多品种批量生产类型,建立了调度约束的生产计划与调度集成优化模型。模型的目标函数是使总调整费用、库存费用及生产费用之和最小,约束函数包括库存平衡约束和生产能力约束,同时考虑了调度约束,即工序顺序约束和工件在单机上的加工能力约束,保证了计划可行性。该模型为两层混合整数规划模型,对其求解综合运用了遗传算法和启发式规则,提出了混合启发式求解算法。最后,针对某机床厂多品种批量生产类型车间进行了实例应用,对车间零件月份作业计划进行分解,得到各工段单元零件周作业计划,确定了零件各周生产批量与投产顺序。

软土亚塑性模型与一维非线性固结理论研究

With the great development of Tianjing New Coastal District economy, people need more land to build and live. Land subsidence, which is caused by its special engineering geological conditions, has restricted the further development in the district. Soft soil consolidation is main factor of land subsidence ;thus , on the basis of consolidation theory, the paper make further study on soft soils one-dimension nonlinear consolidation which contains two parts:(1) the nonlinear consolidation of permeability coefficient and compressibility coefficient changing with time and depth, which means real one-dimension nonlinear consolidation;(2) the non-homogeneous consolidation of permeability coefficient and compressibility coefficient only changing with depth. Firstly, nonlinear characteristics of soft soils are elaborated. Hypoplastic theory is introduced to establish a modified soft soils nonlinear constitutive model; the nonlinear governing equation of compressibility coefficient is built, and the nonlinear characteristics of compressibility coefficient are analyzed. Secondly, Considering Load Fluctuation and soil thickness changing ,the consolidation characteristics of single layer is discussed in the paper; meanwhile, on the basis of the Davis and Raymond’s hypothesis and single layer nonlinear consolidation equation, the doubled-layer one-dimension nonlinear consolidation equation is also derived. The solution of the equation is obtained by analytical method, and the consolidation characteristics of doubled-layer soft soil nonlinear theory is also analyzed. Finally, based on assumption that permeability coefficient and compressibility coefficient is varying along depth, single layer soil one-dimension non-homogeneous consolidation differential equation is derived; and the approximate solution is obtained. Furthermore, the single layer non-homogeneous consolidation is extended to double layer non-homogeneous consolidation theory. By using parabolic differential scheme, the matrix equation is established; and the solution of the matrix equation is obtained by chase method. Consolidation characteristics of soil soft single (double) layer non-homogeneous consolidation theory and Terzaghi’s theory are also discussed.

内蒙古东部喀喇沁地区早中生代底侵作用

Mafic granulite xenoliths have been extensively concerned over the recent years because they are critical not only to studies of composition and evolution of the deep parts of continental crust but to understanding of the crust-mantle interaction. Detailed petrology, geochemistry and isotope geochronology of the Early Mesozoic mafic-ultramafic cumulate xenoliths and mafic granulite xenoliths and their host diorites from Harqin area, eastern Inner-Mongolia have been studied here. Systematic Rb-Sr isochron, ~(40)Ar-~(39)Ar and K-Ar datings for mafic-ultramafic cumulate xenoliths give ages ranging from 237Ma to 221Ma. Geochemical research and forming temperature and pressure estimates suggest that cumulates are products of the Early Mesozoic mantle-derived magmatic underplating and they formed in the magmatic ponds at the lowermost of the continental crust and are later enclaved by the dioritic magma. Detailed study on the first-discovered mafic granulite xenoliths reveals that their modal composition, mineral chemistry and metamorphic P-T conditions are all different from those of the Precambrian granulite exposed on the earth surface of the North China craton. High-resolution zircon U-Pb dating suggests that the granulite facies metamorphism may take place in 253 ～ 236Ma. Hypersthene single mineral K-Ar dating gives an age of 229Ma, which is believed to represent a cooling age of the granulite. As the host rock of the cumulate and granulite xenoliths, diorites intruded into Archean metamorphic rocks and Permian granite. They are mainly composed of grandodiorite, tonalite and monzogranite and show metaluminous and calc-alkaline features. Whole rock and single mineral K-Ar dating yields age of 221 ～ 223Ma, suggesting a rapid uplift in the forming process of the diorites. Detailed field investigation and geochemical characteristics indicate that these diorites with different rock types are comagmatic rocks, and they have no genetic correlation with cumulate and granulite xenoliths. Geochemical model simulating demonstrates that these diorites in different lithologies are products of highly partial melting of Archean amphibolite. It is considered that the Early Mesozoic underplating induced the intrusion of diorites, and it reflects an extensional geotectonic setting. Compression wave velocity V_P have been measured on 10 representative rock samples from the Early Mesozoic granulite and mafic-ultramafic cumulate xenoliths population as an aid to interpret in-situ seismic velocity data and investigating velocity variation with depth in a mafic lower crust. The experiments have been carried out at constant confining pressures up to 1000MPa and temperatures ranging from 20 ℃ to around 1300 ℃, using the ultrasonic transmission technique. After corrections for estimated in situ crustal pressures and temperatures, elastic wave velocities range from 6.5 ～ 7.4 km s~(-1). On the basis of these experimental data, the Early-Mesozoic continental compression velocity profile has also been reestablished and compared with those of the present and of the different tectonic environments in the world. The result shows that it is similar to the velocity structure of the extensional tectonic area, providing new constraints on the Early Mesozoic continental structure and tectonic evolution of the North-China craton. Combining with some newly advancements about the regional geology, the thesis further proposes some constraints on the Mesozoic geotectonic evolution history, especially the features of deep geology of the North China craton.

火成岩储层裂缝识别、预测理论与方法研究－以济阳坳陷火成岩油藏为例

Since 1970s, igneous reservoirs such as Shang741, Bin674 and Luol51 have been found in Jiyang depression, which are enrichment and heavy-producing. Showing good prospect of exploration and development, igneous reservoirs have been the main part of increasing reserves and production in Shengli oilfield. As fracture igneous reservoir being an extraordinary complex concealed reservoir and showing heavy heterogeneity in spatial distribution, the study of recognition, prediction, formation mechanism and the law of distribution of fracture is essential to develop the reservoir. Guided by multiple discipline theory such as sedimentology, geophysics, mineralogy, petroleum geology, structural geology and reservoir engineering, a set of theories and methods of recognition and prediction of fractured igneous rock reservoir are formed in this paper. Rock data, three-dimensional seismic data, log data, borehole log data, testing data and production data are combined in these methods by the means of computer. Based on the research of igneous rock petrography and reservoir formation mechanism, emphasized on the assessment and forecast of igneous rock reservoir, aimed at establishing a nonhomogeneity quantification model of fractured igneous rock reservoir, the creativity on the fracture recognition, prediction and formation mechanism are achieved. The research result is applied to Jiyang depression, suggestion of exploration and development for fractured igneous rock reservoir is supplied and some great achievement and favourable economic effect are achieved. The main achievements are gained as follows: 1. The main facies models of igneous rock reservoir in JiYang depression are summarized. Based on data and techniques of seism, well log and logging,started from the research of single well rock facies, proceeded by seismic and log facies research, from point to line and line to face, the regional igneous facies models are established. And hypabyssal intrusion allgovite facies model, explosion volcaniclastic rock facies model and overfall basaltic rocks facies model are the main facies models of igneous rock reservoir in JiYang depression. 2. Four nonhomogenous reservoir models of igneous reservoirs are established, which is the base of fracture prediction and recognition. According to characteristics of igneous petrology and spatial types of reservoir, igneous reservoirs of Jiyang depression are divided into four categories: fractured irruptive rock reservoir, fracture-pore thermocontact metamorphic rock and irruptive rock compound reservoir, pore volcanic debris cone reservoir and fracture-pore overfall basaltic rock reservoir. The spatial distribution of each model's reservoir has its features. And reservoirs can be divided into primary ones and secondary ones, whose mechanism of formation and laws of distribution are studied in this paper. 3. Eight geologic factors which dominate igneous reservoirs are presented. The eight geologic factors which dominates igneous reservoirs are igneous facies, epigenetic tectonics deformation, fracture motion, intensity of intrusive effect and adjoining-rock characters, thermo-contact metamorphic rock facies, specific volcano-tectonic position, magmatic cyclicity and epigenetic diagenetic evolution. The interaction of the eight factors forms the four types nonhomogenous reservoir models of igneous reservoirs in Jiyang depression. And igneous facies and fracture motion are the most important and primary factors. 4. Identification patterns of seismic, well log and logging facies of igneous rocks are established. Igneous rocks of Jiyang depression show typical reflecting features on seismic profile. Tabular reflection seismic facies, arc reflection seismic facies and hummocky or mushroom reflection seismic facies are the three main facies. Logging response features of basic basalt and diabase are shown as typical "three low and two high", which means low natural gamma value, low interval transit-time, low neutron porosity, high resistivity and high density. Volcaniclastic rocks show "two high and three low"-high neutron porosity, high interval transit-time, low density, low-resistance and low natural gamma value. Thermo-contact metamorphic rocks surrounding to diabase show "four high and two low" on log data, which is high natural gamma value, high self-potential anomaly, high neutron porosity, high interval transit-time and low density and low-resistance. Based on seismic, well log and logging data, spatial shape of Shang 741 igneous rock is described. 5. The methods of fracture prediction and recognition for fractured igneous reservoir are summarized. Adopting FMI image log and nuclear magnetic resonance log to quantitative analysis of fractured igneous reservoir and according to formation mechanism and shape of fracture, various fractures are recognized, such as high-angle fracture, low-angle fracture, vertical fracture, reticulated fracture, induced fracture, infilling fracture and corrosion vug. Shang 741 intrusive rock reservoir can be divided into pore-vug compound type, pore fracture type, micro-pore and micro-fracture type. Physical properties parameters of the reservoir are computed and single-well fracture model and reservoir parameters model are established. 6. Various comprehensive methods of fracture prediction and recognition for fractured igneous reservoir are put forward. Adopting three-element (igneous facies, fracture motion and rock bending) geologic comprehensive reservoir evaluation technique and deep-shallow unconventional laterolog constrained inversion technique, lateral prediction of fractured reservoir such as Shang 741 is taken and nonhomogeneity quantification models of reservoirs are established.

板北断块油藏储层均质特征与剩余油分布研究

With the growing development and perfection of reservoir describing technology, its research achievements have played an increasingly important role in old oilfields in recent years. Reservoir description quantitatively describes, characterizes and predicts every kind of reservoir characters in 3D space. The paper takes Banbei block reservoir as an object, studies the reservoir characters and residual oil distributing characteristics of gravity flow genetic reservoir, and definitudes potential adjustment direction of reservoir development. Main achievements are gained as follows. Through fine correlation of strati graphic sequence, the classification of layers and single sands of main payzones in Banbei block is ascertained, the classifying methods of sedimentary unit in gravity flow reservoir characterized with picked cyclical marker bed are formed. On the basis of comprehensive logging evaluation, depositional characters of Banbei block are studied, and classifying methods of sedimentary microfacies in gravity flow reservoir are described. The sedimentary background of main oil layers in Banbei block is open lake with shallow water, and belongs to lacustrine underwater gravity flow- lacustrine phase depositional system. Main microfacies types are underwater water course^ water course side-wing, underwater floodplain, between two water courses, and lacustrine mud, etc. Reservoir sands mainly are underwater water course sands. Influenced by distributing characters of gravity flow underwater water course, sand shapes in plane mainly are stripe, finger-shape, tongue-shape. Sand distribution shows obvious split property. Sands overlap each other. According to comprehensive analysis of lithologic data, logging parameters, and dynamic production data, the researching threads and methods of reservoir heterogeneous characters are perfected. The depositional characters of gravity flow underwater water course in Banbei block determine its high reservoir heterogeneity. Macroscopic heterogeneity is studied in many aspects such as the scale of layers, the scale of single sands, in-situ scale, the distribution of interlayer types, the interlayer scale, and heterogeneity in plane. Thus, heterogeneous characters of reservoir are thoroughly analyzed. Through microscopic research of reservoir, the types of porous structure and related parameters are determined. According to the analysis of dynamic production data, the reaction and inner influential factors of reservoir heterogeneity in waterflood development are further revealed. Started with the concept and classifying methods of flow unit, clustering classification which can better meet the requirements of production is formed. The flow unit of Banbei block can be classified into four types. According to comprehensive evaluation, the first and second type of flow unit have better percolating capability and reserving capability. Research thread of 3D model-building and reservoir numerical simulation combined as an integral is adopted. The types and characters of residual oil distribution are determined. Residual oil of Banbei block mainly distributes in the boundary of sands, near the faults, areas with non-perfect injection-production well pattern , undeveloped sands, vertically poor developed layers. On the basis of comprehensive reservoir study, the threads and methods of improving development effect towards reservoir with high water cut, high recovery percent, serious heterogeneity are ascertained. The whole waterflood development effect of Banbei block reservoir is good. Although its water cut and recovery percent is relatively high, there is still some potential to develop. According to depositional characters of gravity flow and actual production situation? effective means of further improving development level are as follows. We should drill new wells in every kind of areas abounding with residual oil, implement comprehensive measures such as increasing liquid discharge, cyclic waterflood, changing fluid direction when injection-production well pattern is perfected, improve water quality, enhance displacement efficiency in flooding.

中学生自我评价、泛化信任和应对方式及其于心理健康的关系

The aim of this research is to explore the relationships between Self-evaluation, general trust, coping styles and psychological health of secondary school students. Three studies were carried out. A total of 1024 middle school students ranging in age from 11 to 20 years complete SCL-90, secondary school students self-evaluation scale, questionnaire of coping styles and GTS. It is found that: 1. There were three self-evaluation in middle school students: the self-evaluation in study, in human relations and in appearance. 2. The three factors of self-evaluation are all correlated to gender, grade and single children. 3. General trust of secondary school students is no difference in gender, grade and single children. 4. Aside from the negative exterior copied ones, three self-evaluation and general trust significantly predict the other three coping styles. 5. When we control the gender , grade and and the only-child in multiple linear regression, we found that the coping style has more effect on their psychological health than the gender , grade and and the only-child and influencing of negative coping style is highest. 6. Three self-evaluations and general trust have direct influences on psychological health of secondary school students. Taking coping styles as intermediate variables , three self-evaluations and general trust have direct influences on psychological health of secondary school students.

Preparation of supported PtRu/C electrocatalyst for direct methanol fuel cells

In this work, high-surface supported PtRu/C were prepared with Ru(NO)(NO3)(3) and [Pt(H2NCH2CH2NH2)(2)]Cl-2 as the precursors and hydrogen as a reducing agent. XRD and TEM analyses showed that the PtRu/C catalysts with different loadings possessed small and homogeneous metal particles. Even at high metal loading (40 wt.% Pt, 20 wt.% Ru) the mean metal particle size is less than 4 nm. Meanwhile, the calculated Pt crystalline lattice parameter and Pt (220) peak position indicated that the geometric structure of Pt was modified by Ru atoms. Among the prepared catalysts, the lattice parameter of 40-20 wt.% PtRu/C contract most. Cyclic voltammetry (CV), chronoamperometry (CA), CO stripping and single direct methanol fuel cell tests jointly suggested that the 40-20 wt.% PtRu/C catalyst has the highest electrochemical activity for methanol oxidation. (c) 2004 Elsevier Ltd. All rights reserved.