LiMAlF_6(M=Ca,Sr)基质中Ce~3+、Eu~3+、Tb~3+的光谱研究

合成了Ce3+、Eu3+、Tb3+激活的LiMAlF6(M=Ca,Sr)磷光体，研究了它们的光谱特性．观察到稀土离子在LiCaAlF6和LiSrAlF6中的光谱十分相似．这与它们所处的晶场环境相同有关．发现Ce3+在此基质中有较弱的330nm发射，这一Ce3+的发光中心可用于作为材料质量的评价.

Me_2CeO_4(M=Ca,Sr,Ba)的结构与发光特性

1998年Science上报导了一种新的一维结构发光体—Sr_2CeO_4,引起人们的关注。美国已制备出满足场发射显示器(FED)用 Sr_2CeO_4蓝色荧光粉,而且确信其用于场发射显示器具有很大的潜力。本文中合成了M_2CeO_4(M=Ca,Sr, Ba),讨论了其发光与结构的相关性。Me_2CeO_4(M=Ca,Sr, Ba)均采

Tb(111) and Ca(11) ion equilibria in the presence of glutamic acid and glutamine

Tb(111) and Ca(11) ion equilibria in the Presence of glutamic acid and glutamine were studied by potentiometric titration at 37 degrees C and an ionic strength of 0.15mol/L(NaCl). The stability constants for Tb(111) and Ca(11) complexes in the systems were obtained. The species and their distribution in the systems were discussed.

Luminescence properties of Ce3+ in KMF3(M=Mg, Ca, Sr, Ba) hosts with perovskite structure

KMF3(M = Mg, Ca, Sr, Ba) compounds were synthesized by solid state reaction under argon atmosphere. Their structures were determined by X-ray diffraction. It belongs to cubic system with perovskite structure. The excitation and emission spectra of KMF3:Ce3+ were measured. According to the characteristics of spectral structures, the occupation site of Ce3+ is discussed.

离子型晶体的点电荷电量的确定和晶体的化学键性质MX(M=Mg,Ca,Sr,Ba,X=O,S,Se,Te;不含MgTe)

离子型晶体的点电荷电量的确定和晶体的化学键性质ＭＸ（Ｍ＝Ｍｇ，Ｃａ，Ｓｒ，Ｂａ，Ｘ＝Ｏ，Ｓ，Ｓｅ，Ｔｅ；不含ＭｇＴｅ）孟庆波武志坚张思远（中国科学院长春应用化学研究所稀土无机材料实验室，长春１３００２２）ＮｅｔＣｈａｒｇｅａｎｄＣｈｅｍｉｃａｌＢｏｎ...

Preparation of Pb-Ca-Na master alloy using molten chloride salt electrolysis

An electrolysis technique for co-deposition of Ca2+ and Na+ at the liquid lead cathode was put forward. The experiment was carried out at an electrolysis temperature below 650 degrees C and had a current efficiency of 98%, which are respectively 100 similar to 300 degrees C lower and 15% similar to 30% higher than those reported both at home and abroad.

Comparative study on the doping effect of 3d elements in Bi(1.5)Pb(0.2)Sr(2)Ca(2)Cu(2.8)M(0.2)O(y) (M=Sc,Ti,V,Cr,Mn,Fe,Co,Ni, or Zn)

With XRD, R-T, and ac chi measurements a comparative study on the doping effects of 3d elements in Bi(1.5)Pb(0.2)Sr(2)Ca(2)Cu(2.8)M(0.2)O(y) (M = Sc, Ti, V, Cr, Mn, Fe, Co, Ni, or Zn) has been carried out. The effects of the former five members are significantly different, both on phase formed and on T-c, from the latter four. It seems that the effect on phase stabilization correlates with the valency of the doped cation. In connection with the instability of the 2223 phase, the correlation has been discussed.

Magnetic and electric properties of Bi(La)Sr(Ca)Mn2O6

Bi1-xLaxSrMn2O6 and BiSr1-xCaxMn2O6 are prepared by solid state reaction. They are n-type semiconductors with ferromagnetism at room temperture. When Bi is substituted partly by rare earth, a negative magnetoresistance effect is observed in the pellet of Bi1-xLaxSrMn2O6. There are semiconductor-metal transitions at 820 K in BiSrMn2O6. The transitions are attributed to the magnetic transition at high temperature. The substitution of Ca for Sr makes the transition temperature increase. However, when Bi is partly substituted by La, the solid solution does not change into metal. (C) 1996 Academic Press, Inc.

MMgF_4(M=Ca,Sr,Ba)体系中Eu和Tb的电荷迁移

于不同气流中,合成了MMgF_4:xEU,yTb复合氟化物燐光体.该体系中Eu~(3+)和Eu~(2+)共存.Tb的存在影响Eu的价态存在形式.ESR测试表明,随Tb的掺入浓度增加,Eu~(2+)的浓度呈规律性变化.随Eu的掺入,样品的XPS谱中出现了四价铽的Tb_3d(5/2)特征伴峰.认为Eu~(3+)和Tb~(3+)之间存在电荷迁移平衡.即Eu~(3+)+Tb~(3+)(?)Eu~(2+)+Tb~(4+).通过半定量手段研究了SrMgF_4中这一平衡的平衡常数.

Ce~（3＋）在钙钛矿型KMF_3（M＝Mg、Ca���Sr、Ba）基质中的发光特性

采用高温固相反应法，在Ａｒ气氛中合成了ＫＭＦ３（Ｍ＝Ｍｇ、Ｃａ、Ｓｒ、Ｂａ）基质化合物和掺杂Ｃｅ３＋的磷光体。经Ｘ射线衍射分析确定，ＫＭｇＦ３和ＫＣａＦ３属于立方晶系、钙钛矿型结构，ＫＳｒＦ３和ＫＢａＦ３具有类似的结构。测定了ＫＭＦ３∶Ｃｅ３＋的发光光谱，观察到与其结构对应的分为二种不同的光谱结构，讨论了Ｃｅ３＋的取代格位

THE EFFECT ON PHYSICAL-PROPERTIES OF THE SUBSTITUTION OF CA OR BA FOR SR IN NDSRNIO4

A new solid solution series, NdSr(1-x)M(x)NiO(4) (M = Ca: 0.0 less than or equal to x less than or equal to 1.0; M = Ba: 0.0 less than or equal to x less than or equal to 0.6), was synthesized by solid state reaction, and the structures, magnetic and electrical properties and optical spectra of this series have been studied. All the samples crystalized in tetragonal systems, with the exception of NdCaNiO4, which crystallized in the orthohombic system. IR spectra of NdSr1-xCaxNiO4 indicated that the lengths of two Ni-O bonds decrease with increasing Ca content. The electrical conduction changed from metallic-type to semiconductive-type when x greater than or equal to 0.4 (M = Ca, Ba), and the room temperature resistivities of NdSr1-xCaxNiO4 increased with the increase of Ca content. Magnetic susceptibility measurements revealed that Ni+3 ions in all the samplies were in low-spin state over the temperature range 77-300 K.

A STUDY ON THE LUMINESCENCE PROPERTIES OF EU3+ AND DY3+ IN M(2)RE(8)(SIO4)(6)O-2 (M=MG, CA RE=Y, GD, LA)

In this paper, the luminescence properties of Eu3+ and Dy3+ in the oxyapatites M(2)RE(8)(SiO4)(6)O-2 (M=Mg, Ca; RE=Y, Gd, La) were studied. The spectral characters of Eu3+ were discussed in relation to the crystal structure. The dependence of the red-to-orange intensity ratio and the position of the charge transfer band of Eu3+ and the yellow-to-blue intensity ratio of Dy3+ together with their fluorescence intensities (I-R for Eu3+ and I-Y for Dy3+) On the M(2+) and the substitution of BO45- and PO43- for SiO44- was discussed. Finally, the concentration quenching of Dy3+ luminescence was reported.

STUDIES ON THE COORDINATION OF TB(III) AND CA(III) WITH AMINO-ACID UNDER THE PHYSIOLOGICAL CONDITION

Tb(Ca)-glycine, Tb(Ca)-alanine, Tb(Ca)-glycine-alanine systems were studied by potentiometry (37%, I = 0.15 mol/L NaCl). The stability constants of complexes and distribution of species in ternary system were obtained. The results show Ca<Tb for the stability of binary complexes, Ca>Tb for the ternary complexes. The species convert each other with changing pH values.

A STUDY OF SURFACE OXYGEN SPECIES FROM LA-ME-O (ME=MG, CA, SR, BA) CATALYSTS FOR METHANE OXIDATIVE COUPLING

CO2-TPD was used to study the surface basicity of La-Me-O mixed oxides and O-2-TPD, CH4-TPD were employed to study the surface active oxygen species. Comparing the CO2-TPD with O-2-TPD, we can see that the basicity of catalyst is in parallel with the catalystic activity. The stronger basicity is more profitable for the catalyst to adsorb oxygen to form active oxygen species and to activate CH4 by breaking a C-H bond, By comparing the catalytic activity, the results showed that La-Ba-O(La/Ba=7/3) catalyst had the strongest basicity, and it gave the highest CH4 conversion and C-2 selectivity, The results from the pulse reaction showed that the lattice oxygen participated in the OCM reaction without gas oxygen, and it was the selective oxygen species.