土地利用对潮棕壤电导率影响的研究

对中国科学院沈阳生态实验站潮棕壤水稻田、玉米地、撂荒地和人工林地4种土地利用方式经过14年后土壤电导率在土体10个土层中的剖面分布进行比较研究,结果表明:不同土地利用方式及不同深度土层土壤电导率差异显著。表层,玉米地土壤电导率显著低于其他3种土地利用方式;150 cm深度内土壤电导率平均值为林地>撂荒地>玉米地>水稻田。水稻田土层具有相对较高的土壤电导率,可能主要受植稻过程中土壤淋溶及复盐基作用的影响;林地深层相对较高的土壤电导率可能主要受树木根系分布的影响。不同土地利用方式下土壤剖面中电导率与有机C、全量N、P、S、有效态N、P、S、pH、交换性Ca���Mg、K、Na、CEC、DTPA浸提态Fe、Mn、Cu、Zn之间具有不同的相互关系,反映了不同土地利用方式下元素的生物地球化学循环对土壤电导率的影响。由此,土壤电导率可作为指征不同土地利用方式对土壤性质影响可行的土壤化学指标。表4,参13。

基于最大不动点模型的描述逻辑系统FL��的有穷基

研究了描述逻辑的有穷基问题,分析了有穷基在描述逻辑中的重要意义及其研究现状,并研究了形式概念分析中的属性蕴含和Duguenne-Guigues基问题.利用形式概念分析中Duguenne-Guigues基存在的证明结果,在F.Baader工作基础上设置了描述逻辑的描述背景,重新定义了描述背景下的属性蕴含,证明了带循环术语的描述逻辑系统FLε存在最大不动点语义(greatest fixed-points,gfp)模型,给出了带循环术语的描述逻辑系统FLε在最大不动点模型下的有穷基的存在性定理,并证明有穷基的可靠性和完备性.描述逻辑有穷基可以帮助知识工程师构建一个更适用于推理的描述逻辑知识库.

a state-adaptive access control model for web-based idrs system

Huazhong Univ Sci & Technol, Natl Tech Univ Ukraine, Huazhong Normal Univ, Harbin Inst Technol, IEEE Ukraine Sect, I& M/CI Joint Chapter

近150年北京春季物候对气候变化的响应

对北京春季6种物候的计算得出其代表性指标—山桃始花期,并分析物候对气温变化的响应模式。根据气温变化态势,将历史时期气温和物候资料划分为4个时间段,并采用u检验论证时间段间具有显著性差异,分析物候期对气温变化的响应模式和机制,得出:物候期的提前与推迟对温度的增高与降低的响应是非线性的,在同等增、降温幅度下,因降温而导致的物候期推迟幅度较因增温而导致物候期提前幅度小;平均气温增高1℃,北京春季物候期提前2.8~3.6d。并估算了未来北京春季物候变化趋势。

Solvothermal synthesis of well-dispersed MF2 (M = Ca, Sr, Ba) nanocrystals and their optical properties

MF2 (M = Ca, Sr, Ba) nanocrystals (NCs) were synthesized via a solvothermal process in the presence of oleic acid and characterized by x-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectra, UV/vis absorption spectra, photoluminescence (PL) excitation and emission spectra, and lifetimes, respectively. In the synthetic process, oleic acid as a surfactant played a crucial role in confining the growth and solubility of the MF2 NCs. The as-prepared CaF2, SrF2 and BaF2 NCs present morphologies of truncated octahedron, cube and sheet in a narrow distribution, respectively.

Study of morphology and phase diagram of the H-shaped (AC)B(CA) ternary block copolymers using self-consistent field theory

By using a combinatorial screening method based on the self-consistent field theory (SCFT) for polymer systems, the micro-phase morphologies of the H-shaped (AC)B(CA) ternary block copolymer system are studied in three-dimensional (3D) space. By systematically varying the volume fractions of the components A, B, and C, six triangle phase diagrams of this H-shaped (AC)B(CA) ternary block copolymer system with equal interaction energies among the three components are constructed from the weaker segregation regime to the strong segregation regime, In this study, thirteen 3D micro-phase morphologies for this H-shaped ternary block copolymer system are identified to be stable and seven 3D microphase morphologies are found to be metastable.

Chemical bond characteristics, thermal expansion property and compressibility of AR(2)O(4) (A = Ca, Sr, Ba; R = rare earths)

Theoretical researches were performed on the CaFe2O4-type binary rare earth oxides AR(2)O(4) (A = Ca, Sr, Ba; R = rare earths) by using chemical bond theory of dielectric description. The chemical bond properties of these crystals were explored, and then the thermal expansion property and compressibility were studied. The theoretical values of linear thermal expansion coefficient (LTEC) and bulk modulus were presented. The calculations revealed that the LTECs and the bulk moduli do have linear relationship with the ionic radii of the rare earths. In the cases of Sc and Y, both the LTEC and bulk modulus values are larger than the lanthanide series. We attribute this to the difference in the electronic configuration between Sc (Y) and lanthanide series. For SrY2O4 and BaY2O4 crystals, the theoretical values of LTEC and bulk modulus agree well with experimental ones.

Reduction of Eu3+ to Eu2+ in MAl2Si2O8 (M = Ca, Sr, Ba) in air condition

In general, the reduction of Eu3+ to Eu2+ in solids needs an annealing Process in a reducing atmosphere. in this paper, it is of great interest and importance to find that the reduction of Eu3+ to Eu2+ can be realized in a series of alkaline-earth metal aluminum silicates MAl2Si2O8 (M = Ca, Sr, Ba) just in air condition. The Eu2+-doped MAl2Si2O8 (M = Ca, Sr, Ba) powder samples were prepared in air atmosphere by Pechini-type sol-gel process. It was found that the strong hand emissions of 4f(6)5d(1)-4f(7) from Eu2+ were observed at 417, 404 and 373 nm in air-annealed CaAl2Si2O8, SrAl2Si2O8 and BaAl2Si2O8, respectively, under ultraviolet excitation although the Eu3+ precursors were employed. In addition, under low-voltage electron beam excitation, Eu2+-doped MAl2Si2O8 also shows strong blue or ultraviolet emission corresponding to 4f(6)5d(1)-4f(7) transition.

Super-hydrophobicity of silica nanoparticles modified with vinyl groups

Super-hydrophobic films with vinyl-modified silica nanoparticles (V-SiOx-NPs) were successfully prepared. The rough surface, which was composed of microstructures of disordered V-SiOx-NPs and nanostructures on the surface of V-SiOx-NPs, rather than the chemical composition devoted to the super-hydrophobicity of film. The relationship between contact angle and diameter of V-SiOx-NPs was then investigated. The sessile contact angles (CA) of films with 150-1600nm V-SiOx-NPs were around 166 regardless the diameter, while the film with 85 nm V-SiOx-NPs had the lowest CA of about 158. The packing manner of V-SiOx-NPs determined the air fraction on the surface and then the CA.

Preparation and luminescent properties of rare earth ions in M2B5O9Cl : Re(M = Ca, Sr, Ba; Re=Eu, Tb)

M2B5O9X: Re(M = Ca, Sr, Ba; X = Cl, Br; Re = Eu, Th) phosphors were synthesized via solid state method. The products were characterized with X-ray powder diffraction and luminescence spectrometer. The luminescent properties as well. as the influences of the matrix composition and other doping ions on the luminescence of the rare earth ions of the co-doped phosphors were investigated. The coexistence of Eu3+, Eu2+ and Th3+ were observed in these matrices. The phenomenon may be explained by the electron transfer theory. The sensitization of Ce3+ ion improves the intensity of emission of Eu2+, and Tb3+. The competition between electron transfer among conjugate rare earth ions and energy migration might be the reasons for the observation. We predict a novel trichromatic phosphor co-doped with Eu3+ Tb3+ in M2B5O9X.

Selective synthesis of mesoporous and nanorod CeVO4 without template

A simple and efficient method has been established for the selective synthesis of mesoporous and nanorod CeVO4 with different precursors by sonochemical method. CeVO4 nanorod can be simply synthesized by ultrasound irradiation of Ce(NO3)(3) and NH4VO3 in aqueous solution without any surfactant or template. While mesoporous CeVO4 with high specific surface area can be prepared with Ce(NO3)(3), V2O5 and NaOH in the same way. Mesoporous CeVO4 has a specific surface area of 122 m(2) g(-1) and an average pore size of 5.2 nm; CeVO4 nanorods have a diameter of about 5 nm, and a length of 100-150 nm. The ultrasound irradiation and ammonia in the reactive solution are two key factors in the formation of such rod-like products. X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), thermogravimetric (TG) and differential thermal analyses (DTA), UV/vis absorption spectroscopy and Brunauer-Emmett-Teller (BET) were applied for characterization of the as-prepared products.