一个新的CuxSbOy化合物的合成

在研究Bi系超导样品中各组分间的相图关系时,我们发现了一个新的Cu_xSbO_y化合物。关于Cu—Sb—O体系只有CuSb_2O_5化合物已见报导1 实验部分试样制备采用固相反应方法,将Sb_2O_3,CuO(A,R级)混匀、碾磨,于900℃在刚玉坩锅中灼烧24小时。X—ray衍射分析在日本D/max—Ⅱв衍射仪上进行

高Jc Ag-Bi-Pb-Sr-Ca-Cu-O超导材料

Bi_2Sr_2Ca_2Cu_3O_y-Ag_x、Bi_(1.7)Pb_(0.3)Sr_2Ca_2Cu_3O_y-Ag_x和Bi_(1.7)Pb_(0.3)Sr_2Ca_2Cu_(3.2)O_y-Ag_x系列的超导材料是用固相反应的方法合成的。原料为分析纯AgNO_3、PbO、Bi_2O_3、CaCO_3、SrCO~3和CuO。把试剂按所需配比混和研磨后,在800℃烧12h,研磨压片,片子在850℃烧结200h,破碎、研磨后,按配比加入AgNO_3·800℃灼烧12h,再次研磨、压片,850℃再烧结200h,炉冷至室温。

BiPbSbSrCaCuO的超导电性

据报,在BiPbSrCaCuO中加Sb形成BiPbSbSrCaCuO体系的T_c可达130K。但其组成、结构、性质等均未见详细报道。我们合成了一系列BiPbSbSrCaCuO,发现了一个具有2212相结构、但T_c却为～110K的超导相。 试样制备包括将Bi_2O_3,PbO,Sb_2O_3,SrCO_3,CaO和CuO(AR级)混匀、碾磨、于

铜管不锈钢管腐蚀性能及铁牺牲阳极保护研究

铜管一直是电厂凝汽器的主要应用管材，但由于其抗冲刷和抵御污染物腐蚀的能力差，特别不耐氨蚀，美国和欧洲大量使用不锈钢管替代铜管作为冷凝管，然而不锈钢管在我国的运用仅处于初步阶段。 常使用锌、铝阳极对铜管进行牺牲阳极保护，然而存在着电位差过大、阳极溶解过快的问题。铁基牺牲阳极与铜电位差适当、来源广泛、价格便宜，在一些工程上有所应用，但是目前针对铁基牺牲阳极的理论研究报道很少。 本文选用紫铜管、304不锈钢管作为实验用管材，首先运用实验室全浸实验、极化曲线和电化学阻抗研究了二者在海水和淡水中的腐蚀性能以及CO2、溶解氧对其腐蚀的影响。结果表明：CO2会加速二者的腐蚀，溶解氧却对它们的腐蚀影响不同，促进铜管的腐蚀却抑制不锈钢管的腐蚀；随浸泡时间的延长，紫铜管由于表面产物膜的生成耐蚀性提高，304不锈钢管的耐蚀性却降低；淡水中，304不锈钢管和紫铜管都具有很好的耐蚀性能。随后，运用失重法和极化曲线对比研究了紫铜管、304不锈钢管的氨蚀性能，运用SEM分析和电化学阻抗研究了紫铜在不同浓度氨溶液中的腐蚀机理。发现，304不锈钢管的耐氨蚀能力远远好于铜管；溶解氧是影响氨蚀的关键因素，其对二者氨蚀的影响也不同；紫铜管在低氨浓度和高氨浓度溶液中腐蚀机理和产物不同，低氨浓度时形成保护性的产物膜（CuO 和Cu(OH)2），高氨浓度时由活化溶解控制，生成可溶的[Cu (NH3)4]2+。 选用工业纯铁、35钢为牺牲阳极材料。恒电流实验结果表明它们具有良好的牺牲阳极性能；通过极化曲线和自腐蚀电位测试分析，认为将二者用于铜管牺牲阳极保护是可行的；实验室阴极保护效果测试表明，工业纯铁和35钢对紫铜管具有良好的保护效果，保护度达90%以上。

海绵钛生产中铜丝除钒废物回收过程的矿物学研究

海绵钛是钛工业的基础原材料。近年来国内海绵钛产业发展迅速，到2007年其产量已达到两万多吨。海绵钛生产产生大量的废渣、废气、废液等污染物质，对环境造成严重污染，是制约海绵钛产业发展的瓶颈。虽然国家早就将海绵钛生产的环境污染治理问题列为国家重大攻关课题，但长期以来却未从根本上得到很好的解决。本论文以海绵钛生产中铜丝除钒工艺产生的废物为对象，对其中的物质组成及其来源进行了分析，探索对该废物处置与综合回收技术。 除钒杂质是四氯化钛精制作业中极为重要的环节，铜丝除钒是国内采用的主要工艺技术，其产生的废物中含有铜、钒等有用资源。本文首先对海绵钛生产中四氯化钛精制环节铜丝除钒工艺产生的废物的物质组成进行研究，在确定其主要成分是含铜、钒的化合物基础上，设计了综合回收铜、钒等有用资源的技术方案——采用氢氧化钠进行碱处理形成铜钛沉淀物和含钒碱溶液；铜钛沉淀物用硫酸浸出得到硫酸铜溶液和钛沉淀物；硫酸铜溶液进一步电解得到电解铜；含钒碱溶液采用盐酸处理沉淀钒，再经焙烧得到五氧化二钒。在研究过程中主要采用环境矿物学的研究方法，利用化学分析、X射线衍射分析、扫描电镜观察等手段，查明该废物及回收过程产物的特点。 本文通过实验研究，得到以下主要结论： 1.海绵钛生产中铜丝除钒工艺产生的废物主要是水洗池废液，约占90%以上；水洗池废液中铜、钒的浓度很高，分别是5.4g/L、3.6g/L。水洗池沉淀物中的铜、钒主要是以(Cu0.95V2O5)CuO，Ni2V2O7的结晶态形式存在。 2.在废物的化学分析结果和X射线衍射分析结果的基础上，设计了对废物综合回收电解铜、五氧化二钒等资源的技术方案。该回收技术路线下电解铜的初步回收率可达97%，钒的一次回收率约为78%。 3.对回收过程中的各阶段产物进行了化学分析、物相分析和微观形貌观察，研究结果表明铜、钒、钛等资源得到了较好有分离和回收。

The effect of additives on Cu/HZSM-5 catalyst for DME synthesis

The addition of ZnO or ZrO2 into CuO/HZSM-5 was investigated for DME synthesis from syngas by using the reactive frontal chromatography method, TPR and in situ TPR. These promoters enhanced the catalytic activity of Cu/HZSM-5 and promotion with ZnO and ZrO2 produced a maximum activity, which could be explained by the improvement of the dispersion of Cu and the promotion of CuO reduction. The Cu+ species existing during the reaction have been detected, based on which a Cu-0 <-> Cu+1 redox cycle model was put forward.

Catalytic steam reforming of ethanol to produce hydrogen and acetone

Steam reforming of ethanol over CuO/CeO2 was studied. Acetaldehyde and hydrogen were mainly produced at 260degreesC. At 380degreesC, acetone was the main product, and 2 mol of hydrogen was produced from 1 mol of ethanol. The formation of hydrogen accompanied by the production of acetone was considered to proceed through the following, consecutive reactions: dehydrogenation of ethanol to acetaldehyde. aldol condensation of the acetaldehyde, and the reaction of the aldol with the lattice oxygen [O(s)] on the catalyst to form a surface intermediate, followed by its dehydrogenation and decarboxylation. The overall reaction was expressed by2C(2)H(5)OH + H2O --> CH3COCH3 + CO2 + 4H(2). Ceria played an important role as an oxygen supplier. The addition of MgO to CuO/CeO2 resulted in the production of hydrogen at lower temperatures by accelerating aldol condensation. (C) 2004 Elsevier B.V. All rights reserved.

Factors influencing the catalytic activity of SBA-15-supported copper nanoparticles in CO oxidation

Copper nanoparticles were deposited onto mesoporous SBA-15 support via two different routes: post-grafting method and incipient wet impregnation method. Both XRD and TEM reveal that the post-grafting can make Cu particles very small in size and highly dispersed into channels of SBA-15, while the impregnation method mainly forms large Cu particles on the external surface of SBA-15. TPR experiments show that CuO species formed by the post-grafting method is more reducible than that prepared by the impregnation method. The catalytic activity tests for CO oxidation manifests that the sample prepared by the post-grafting method has a much higher activity than that prepared by the impregnation method, with a lowering of 50 degrees C for T-50, showing a strong dependence of catalytic activity on the size and dispersion of Cu particles. Besides the preparation procedure, other factors including calcination temperature, reduction treatment, copper loading as well as the feed composition, have an important effect on the catalytic activity. The best performance was obtained when the catalyst was calcined at 500 degrees C and reduced at 550 degrees C. The calcination and reduction treatment at high temperature have been found to be necessary to completely remove the organic residue and to generate active metallic copper particles. (c) 2005 Elsevier B.V. All rights reserved.