2.45GHzECR离子源及ECR离子源的磁场设计和计算

本文第一章介绍了高电荷态电子加旋共振（ECR）离子源发展情况，对其发展的几个方向作了一定的讨论，着重介绍了IMP高电荷态ECR离子源。第二章讨论了ECR离子源的加热原理，并讨论了低电荷态ECR离子源的加热情况。在ECR离子源中，磁场有着重要的作用，磁场场面设计和计算也ECR离子源物理设计中关键的一环。第三章讨论了ECR离子源的磁场设计和计算。在设计、加工几例磁场系统的基础上，利用计算与实测结果对离子源的磁场设计和计算作了一定程度的讨论。并使用二维POSSION、三维TOSCA程序对超导离子源进行了初步设计和计算。第四章着重讨论了两个2.45GHzECR离子源实验台。描述了一台2.45GHz单电荷态ECR离子源的结构与应用。介绍了其微波系统与磁场结构，并对该离子源的一些问题进行了讨论。在微波输入功率约600瓦，引出高压22KV，引出孔径为φ6mm，引出间隙6mm时，该离子源的总束流I(H_1~+ + H_2~+ + H_3~+)为 90mA。同时，介绍了一台2.45GHz多电荷态ECR实验台的设计。

ECR离子源高真空微调针阀控制系统

本论文首先介绍ECR（电子回旋共振）离子源的基本原理及其发展，在此基础上讲述了近物所的14.5GHzECR离子源的结构和特点。本论文主要内容是介绍所研制的适用于30KV高压端的ECR离子源高真空微调针阀控制系统。此系统被控对象是位于ECR源上的高真空微调针阀，它与地面之间有20～30KV的电位差。论文中首先阐述此控制系统研究的背景，并对ECR离子源电气参数控制的特点进行了说明。根据被控对象的情况以及对系统提出的指标，详细讲述了此控制系统的软、硬件实现。硬件包括步进电机、步进电机驱动器、轴编码器等。软件包括译码编程。然后从总体介绍此控制系统的功能结构，再分步讲述发射器、接受器、译码等各功能模块的实现过程。此控制系统的最大特点是使用光路实现高压绝缘，这为解决位于ECR离子源高压端器件的控制问题提出新思路。本系统的光路采用红外线发射接收系统，以空气为传输介质，依据光信号的有无接收控制信息，此方式效果好、易于实现。在系统中，使用光路传输装置定位，聚集透镜聚集，增加信号强度，提高抗干拢能力。而且此光路传输系统价格便宜，易于实现，可靠性好。在整个控制系统方案调研期间，对各种控制方式进行了比较和实验，在此基础上，确定了一个比较经济实用和具有高可靠性的方案。经过设计电路原理图、绘制印制线路板、加工印制线路板、购买元器件、组装电路后，首先成功地进行了离线调试，最后，将整个系统模拟实际环境进行调试实验。整个系统实现了稳定可靠的工作，达到了预期的设计指标，精度好于要求的千分之一。由于时间紧张和条件的限制，该系统还未在现场设备上进行实验。因此，在今后的工作中，此控制系统还需要在条件具备时，在现场设备上进行实验和考验。此外，为满足国家大科学工程兰洲重离子冷却储存环的要求，我参与了在14.5GHz ECR离子源上进行afterglow工作模式的实验，首次产生了高电荷态脉冲束流Ar~(11+)和Ar~(12+)。论文最后一部分给出了初步实验结果，并对结果进行了分析和解释。

ECR离子源发射度探测器的研制

成功研制一套适合于ECR离子源引出束流发射度测量的探测器ESS（Electric-SweeP Scanner）。该探测器主要由测量探头、机械驱动装置、计算机控制及数据获取系统组成。ESS探测器所采用的测量方法是双狭缝加电扫描法，具有速度快、精度高，能够比较直观的反映束流的发射度相图、相空间密度分布等特点，是目前ECR离子源引出束流发射度测量的有效手段。本论文对发射度探测器ESS的原理、结构及物理和技术设计作了较详细的描述，并给出了相应的设计图纸及数值模拟结果。最后，利用Ess探测器对LECR3（Lanzhou No.3）离子源引出的04＋离子束的发射度作了初步测量。当04＋引出束流为343μA日寸，初步测量所得水平方向的发射度为227mm·mrad（约90％束流），并给出了相应的束流发射度相图和束流相空间密度分布。

GAS-PHASE SYNTHESIS OF DERIVATIVE OF C-60-C60S+

Gas phase ion-molecular reactions of C-60 with the ion system of CS2 have been studied in the ion source of mass spectrometer. It was found for the first time that the sulfuric derivative of C-60-C60S+ was the main ions in the ion source, they did not react with C-60 to form adduct ions due to their highly saturated structures. According to the dynamic analysis, the product ion came from the reaction of C-60 with the fragment ion S+. The adduct ion may have the structure of epsulfide that is advantageous in energy.

A Study on the Unimolecular Decomposition of the Doubly Charged Ions Produced from 4 Chloro-toluene Isomers

The unimolecular charge separations and neutral loss decompositions of the doubly charged ions [C7H7Cl](2+), [C7H6Cl](2+) and [C7H5Cl](2+) produced in the ion source by 70 eV electron impact from 3 chloro-toluenes and benzyl chloride isomers were studied

CHEMICAL-IONIZATION MASS-SPECTROMETRY OF BENZOYL PEROXIDE - A RADICAL AROMATIC-SUBSTITUTION RESULTING IN BIPHENYLCARBOXYLIC ACID IN THE GAS-PHASE

A radical aromatic substitution resulting in biphenylcarboxylic acid is inferred for the decomposition of benzoyl peroxide from the chemical ionization and collision-induced dissociation mass spectra. The thermolysis of benzoyl peroxide gives rise to a benzoyloxy radical, which undergoes rapid decarboxylation and hydrogen abstraction leading to phenyl radical and benzoic acid, respectively. Attack of the resulting phenyl radical on the benzoic acid results in bipbenylcarboxylic acid. On the other hand, the phenyl radical abstracts a hydrogen atom to yield benzene, which is then subjected to the attack of a benzoyloxy radical, affording phenyl benzoate. This substitution reaction rather than the recombination of benzoyloxy and phenyl radicals is found to be responsible for the formation of phenyl benzoate under the present conditions.

A STUDY ON 2E SPECTRA OF BIPHENYL DERIVATIVES

A study of doubly charged ion mass spectra (2E spectra), the substituents effect and the target gas pressure deppendence of biphenyl derivitives was presented in this work. The decomposition of doubly charged ion formed in the ion source is dominant by the losses of H, C2H2, C2H4 and HR(R represents substituent). [C12H8]2+, [C12H6]2+ and [C10H6]2+ among others are the most stable product ions. The substituents effect is Various in different decomposition reactions, and in some cases it can not be predicted by Hammett equition. While the TIC of 2E spectra was markedly influenced by the target gas pressure, but the fragmentation pattern of the 2E spectra is independent of it.

Application of 2-(11H-benzo[a] carbazol-11-yl) Ethyl Carbonochloridate as a Pro-column Derivatization Reagent of Amino Acid by High Performance Liquid Chromatography with Fluorescence Detection

On a reversed phase Hypersil BDS C-18 (200 mm x 4. 6 mm, 5 mu m) column, 20 amino acids, which were derivatized using 2-(11H-benzo [a] carbazol-11-yl) ethyl carbonochloridate (BCEC-Cl) as pre-column derivatization reagent, were separated in conjunction with a gradient elution. Optimum derivatization was obtained by reacting of amino acids with BCEC-Cl at room temperature for 5 min in the presence of sodium borate catalyst in acetonitrile solvent. The fluorescence excitation and emission wavelengths were 279 nm and 380 nm respectively. The identification of amino acid derivatives from hydrolyzed bovine serum albumin and bee pollen was carried out by post-column mass spectrometry with electrospray ion source in positive ion mode. Linear correlation coefficients of the amino acid derivatives were > 0.9990, and detection limits (at signal to noise of 3:1) were 1.49 - 19.74 fmol for the labeled amino acids.

Neutron source from thin foil confined by two laser pulses

Neutron production from a thin deuterium-tritium (D-T) foil irradiated by two intense femtosecond laser pulses from opposite sides with zero phase difference is studied analytically and numerically. For the interaction of a laser pulse of amplitude a = 7, focal area 100 mu m(2) and areal density 4.4 x 10(18) cm(-2) with a D-T plasma foil, about 1.17 x 10(21) neutron s(-1) can be obtained, much more than from other methods. The profiles of the ion and electron densities are also calculated.

Laser-driven inertial ion focusing

A Hohlraum-like configuration is proposed for realizing a simple compact source for neutrons. A laser pulse enters a tiny thin-shelled hollow-sphere target through a small opening and is self-consistently trapped in the cavity. The electrons in the inner shell-wall region are expelled by the light pressure. The resulting space-charge field compresses the local ions into a thin layer that becomes strongly heated. An inward expansion of ions into the shell cavity then occurs, resulting in the formation at the cavity center of a hot spot of ions at high density and temperature, similar to that in inertial electrostatic confinement.

Positive- and negative-ion matrix-assisted laser desorption/ionization mass spectrometry of saccharides

Matrix-assisted laser desorption/ionization (MALDI) mass spectrometry (MS) of oligosaccharides and polysaccharides has been investigated in detail, It is demonstrated that cationized species of oligosaccharides, [M+Na](+) and [M+K](+), are dominant products under the MALDI condition, and negative ions of oligosaccharides are not formed to any significant extent in this process, The molecular masses of polysaccharides are similarly determined by positive- and negative-ion MALDI-MS with the help of column chromatography. The distinction between positive- and negative-ion MALDI mass spectra of oligo-and polysaccharides indicates that the MALDI processes for saccharides vary with molecular mass. The matrix plays a more important role in the ionization process for oligosaccharides, while in the desorption process for polysaccharides. (C) 1998 John Wiley & Sons, Ltd.

Time and space-resolved measurement of a gas-puff laser-plasma x-ray source

The dynamic interaction processes between a nano-second laser pulse and a gas-puff target, such as those of plasma formation, laser heating, and x-ray emission, have been investigated quantitatively. Time and space-resolved x-ray and optical measurement techniques were used in order to investigate time-resolved laser absorption and subsequent x-ray generation. Efficient absorption of the incident laser energy into the gas-puff target of 17%, 12%, 38%, and 91% for neon, argon, krypton, and xenon, respectively, was shown experimentally. It was found that the laser absorption starts and, simultaneously, soft x-ray emission occurs. The soft x-ray lasts much longer than the laser pulse due to the recombination. Temporal evolution of the soft x-ray emission region was analyzed by comparing the experimental results to the results of the model calculation, in which the laser light propagation through a gas-puff plasma was taken into account. (C) 2003 American Institute of Physics.

Studies of ion energy and yield from argon clusters heated by intense femtosecond laser pulses

Using time-of-flight spectrometry, the interaction of intense femtosecond laser pulses with argon clusters has been studied by measuring the energy and yield of emitted ions. With two different supersonic nozzles, the dependence of average ion energy (E) over bar on cluster size (n) over bar in a large range of (n) over bar approximate to 3 x 10(3) similar to 3 x 10(6) has been measured. The experimental results indicate that when the cluster size (n) over bar <= 3 x 10(5), the average ion energy (E) over bar proportional to (n) over bar (0.5), Coulomb explosion is the dominant expansion mechanism. Beyond this size, the average ion energy gets saturated gradually, the clusters exhibit a mixed Coulomb-hydrodynamic expansion behavior. We also find that with the increasing gas backing pressure, there is a maximum ion yield, the ion yield decreases as the gas backing pressure is further increased.

Ion acceleration in laser-excited plasma wake fields

The dynamics of the plasma ions in the wake fields of short, ultraintense laser pulses in underdense plasmas are investigated analytically and numerically. Owing to the large ion-to-electron mass ratio, the motion of plasma ions in-such wake fields has often been assumed to be neglectable. It is shown that when the laser intensity exceeds 10(20) W/cm(2), the ion motion can no longer be ignored. In this case, ion momentum peaks appear behind the laser pulse, which correspond with the ion density peaks. The laser-excited wake field appears to be effective for ion acceleration, in particular to ions with high-charge numbers. The dependence of ion acceleration on the laser intensity, pulse width, and background plasma density is discussed. (c) 2006 Optical Society of America.

Ion cascade acceleration from the interaction of a relativistic femtosecond laser pulse with a narrow thin target

Particle-in-cell simulations are performed to study the acceleration of ions due to the interaction of a relativistic femtosecond laser pulse with a narrow thin target. The numerical results show that ions can be accelerated in a cascade by two electrostatic fields if the width of the target is smaller than the laser beam waist. The first field is formed in front of the target by the central part of the laser beam, which pushes the electron layer inward. The major part of the abaxial laser energy propagates along the edges to the rear side of the target and pulls out some hot electrons from the edges of the target, which form another electrostatic field at the rear side of the target. The ions from the front surface are accelerated stepwise by these two electrostatic fields to high energies at the rear side of the target. The simulations show that the largest ion energy gain for a narrow target is about four times higher than in the case of a wide target. (c) 2006 American Institute of Physics.