163 resultados para Potassium permanganate


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研究了碱金属和碱土金属离子修饰的掺Er^3+氟磷酸盐玻璃的光谱性质,讨论了碱金属和碱土金属对铒氟磷玻璃的吸收和发射截面、荧光半高宽,Judd-Ofelt强度参数和上转换发光强度等光谱性质的影响,并与一些传统氧化物玻璃系统进行了比较.研究表明碱金属K^+和碱土金属Sr^2+掺杂高的玻璃更适宜用作光放大器基质.含12mol%K^+的氟磷玻璃展现出7.83×10^-21cm^2的高发射截面和最小的荧光上转换强度;含23mol%Sr^2+的氟磷玻璃则有7.58×10^-21cm^2的高发射截面、65nm的荧光半高

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钾是作物生长发育的必需矿质元素,缺钾对大豆产量和营养品质影响显著。硅是植物的有益元素,在低钾胁迫条件下,硅对大豆生长是否有改善作用还未见相关报道,本研究以对低钾敏感的不同基因型大豆品种(铁丰35和铁丰31)为试验材料,在低钾条件下(1 mmol L-1),施加Na2SiO3,通过大豆生物量、根系形态学、生理学和抗氧化物酶活性等参数的变化,研究硅在大豆缺钾胁迫生长中的作用。主要研究结果如下: 1低钾胁迫对大豆生长发育和生理指标形状的影响 与正常钾生长条件(5 mmol L-1)相比,对低钾敏感的基因型大豆品种铁丰35,低钾胁迫使铁丰35品种主根、侧根,过氧化氢 (H2O2)和丙二醛含量(MDA),根系和叶片的超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、过氧化物酶(POD)活性和光合特性指标等发生显著变化,同样地,铁丰31品种根系的SOD、CAT、POD活性和MDA含量也发生显著变化。相反,铁丰31品种的其它形态学和生理学指标参数受低钾胁迫影响差异不显著。 2 Si和Na+对大豆生长发育和生理过程中低钾胁迫的减缓作用 为探明Si对大豆生长发育和生理过程中低钾胁迫的减缓作用,我们将Na2SiO3分别设立3个浓度处理水平(0.1, 2.0, 5.0 mmol L-1),对照CK0:5.0 mmol/L KNO3+0.0 mmol/L Na2SiO3,副对照CK1:1.0 mmol/L KNO3+4.0mmol/L NaCl,其中以Si2处理是2个品种减缓低钾胁迫效应最好的,对大豆生长发育和促进大豆根、茎和叶内钾浓度含量,低钾胁迫使SOD、POD、CAT活性,H2O2和MDA含量,以及光合特性(Pn, WUE)等指标参数得以显著地改善,但Na2SiO3对低钾敏感品种铁丰35的减缓作用远大于对低钾不敏感的品种铁丰31。为排除Na2SiO3中Na+对低钾大豆的生长作用,用等浓度NaCl进行检验,结果表明,Na+可以部分地减缓低钾胁迫,并且这减缓作用远小于等浓度的Si。本试验结果说明Si通过改变几个关键的生理过程,进而提高低钾胁迫条件下,大豆生长发育的表达活力,以有效地改善低钾对大豆生长的胁迫。 3 Si通过提高抗氧化胁迫进而减缓大豆生长发育中低钾胁迫 低钾胁迫使大豆地上和地下生物产量与对照CK0相比显著减少,增施Na2SiO3前后大豆其根冠比、过氧化氢积累、钾含量、膜质过氧化产物和抗氧化物酶活性变化显著。另外,Na2SiO3显著减缓了低钾胁迫使大豆根冠比、提高了低钾大豆根、茎、叶内钾浓度,Si还减缓了过氧化氢 (H2O2)和丙二醛含量(MDA),这说明Si抑制了低钾的过氧化胁迫,显著地抑制了因低钾胁迫而使超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、过氧化物酶(POD)等活性的升高,这些酶活性提高效应被施加的Na2SiO3消除,这些结果表明,Si通过提高抗氧化胁迫能力,进而减缓大豆生长发育的低钾胁迫,对低钾胁迫有非常重要的减缓调控作用。

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本研究选用抗盐冬小麦品种—德抗961(DK961)和盐敏感品种—济南17(JN17)为试验材料。一方面,研究了冬小麦对盐分及臭氧胁迫的生理生态响应机制;另一方面,探讨了外源硝酸钾对小麦盐伤害的缓解机理,提出了盐胁迫下小麦优质高产的栽培技术规程。主要结论如下: 1 冬小麦产量与品质对不同浓度盐胁迫的响应 同一小麦品种在不同盐浓度胁迫下产量和品质存在显著差异,不同小麦品种在同一盐分浓度胁迫下产量和品质也有显著差异,说明盐胁迫下小麦产量和品质与小麦品种特性和耐盐性关系密切。在对照栽培条件下,两小麦品种的产量次序为JN17>DK961;在轻度(0.3%)盐胁迫下,耐盐品种仍获得了较高的产量(仅下降5.8%),而盐敏感品种下降幅度较大(为22.9%),此时的产量次序为DK961>JN17;DK961在0.5%盐胁迫下,产量较对照处理下降9.7%,而JN17下降了54.3%;在0.7%盐浓度环境中,DK961和JN17产量均出现了大幅降低,但DK961的产量仍显著高于JN17。 盐胁迫下的小麦品质指标表现为:在0.3%和0.5%盐浓度下,随着盐浓度的升高,蛋白质含量升高,淀粉含量下降;当盐浓度达到0.7%时,两者都快速下降。 2 不同耐盐性冬小麦品种对盐胁迫的生理生态响应 2.1品种与盐浓度对小麦生长特性的影响 盐胁迫造成了小麦的后期衰老加快,光合速率降低,生育期缩短。但这种影响会因小麦的耐盐性不同而有很大的差异:DK961在轻、中度盐浓度(0.3%、0.5%)下,生育期与无盐处理时无显著差异,但当盐浓度达到0.7%时,生育期出现了明显的缩短;相反,JN17生育期在各个盐浓度下都出现了显著变化。对盐敏感品种,盐胁迫导致小麦出苗期、拔节期推迟3-5 d,抽穗期和开花期提前6-7 d,成熟期提前10-15 d。盐胁迫对小麦生育期的影响主要是缩短生殖生长期。 2.2品种与盐浓度对小麦生理代谢的影响 不同冬小麦品种对盐胁迫产生的生理反应程度不同,耐盐小麦品种在一定的盐浓度范围内,盐胁迫症状不明显,生理反应比较迟钝,光合速率、气孔导度、光饱和点等基本维持在无盐处理的水平,丙二醛和活性氧清除酶活性增加不显著;盐敏感品种在各种盐浓度胁迫下或耐盐品种在过重的盐分浓度胁迫下,盐胁迫症状极为显著,小麦植株生长矮小,光合速率、气孔导度、光饱和点等大幅下降,丙二醛和活性氧自由基含量大幅上升,严重的情况下,小麦植株不能正常生长,甚至出现“干死”现象。 3 盐胁迫下冬小麦生理生态特征对臭氧浓度升高的响应 3.1 臭氧污染对小麦生理代谢的影响 3.1.1对小麦叶片气体交换的影响 气孔是小麦叶片与外界气体交换的“大门”,是臭氧进入叶片的主要通道,控制着蒸腾、光合、呼吸等重要生理过程。通常,高浓度臭氧环境中,小麦表现出较低的气孔导度。气孔的这种反应是植物限制臭氧进入叶片中的一种避害机制。 臭氧的强氧化性导致高浓度臭氧环境中小麦的光合速率下降。臭氧通过气孔进入叶片后,对植物叶片光合作用的抑制主要是由Rubiso酶含量/活性的降低引起的。研究发现,臭氧低于某一临界值时,产生的氧化伤害可以被植物体的抗氧化系统清除而不会对光合作用产生抑制,而高于该临界值时由Rubsico限制引起的光合速率降低将与臭氧吸收量呈线性关系。高浓度臭氧环境下,植物光合作用降低的生理原因,主要是臭氧导致叶绿素和可溶性蛋白分解,叶片衰老加快、叶绿体结构发生改变、活性氧清除酶活性升高,而与碳素固定有关的酶活性降低、光合产物向外运输受阻而导致的反馈抑制。 3.1.2对小麦生长特性的影响 研究表明,环境中臭氧浓度升高可引起小麦生长特性发生巨大改变。臭氧污染首先加快老叶的衰老,而对新叶的影响很小。然而老叶衰老能够将其中的营养转移到新生长叶片中,有利于维持植株的生长。臭氧环境下,老叶迅速衰老的同时,同一植株中的新生组织具有较高的Rubisco合成速率和总量,同化速率加强。这一现象被认为是植株在臭氧环境下的一种补偿机制。臭氧显著降低植株同化物向根系的分配,而同化物向根系分配的改变将导致根系与整株植物功能关系的改变。在水分亏缺环境下,植物根系的生长受到抑制,导致根系对土壤营养吸收能力的降低,从而间接降低叶片的光合速率。 3.2 盐胁迫引起的生理响应提高了小麦抵御臭氧伤害的能力 试验结果表明,盐胁迫引起的小麦生理响应(如,气孔导度降低、抗氧化酶活性升高等),显著增强了小麦抵抗臭氧伤害的能力。但这种保护作用是相对的,因为盐胁迫本身已对小麦生长产生显著的抑制作用。 3.2.1 气孔导度下降减少了臭氧的进入 研究发现,臭氧是通过气孔进入植物体内的,而盐胁迫引起的小麦气孔导度下降,显著减少了臭氧进入小麦体内的量,大大减轻了臭氧对小麦的伤害。本实验中,无盐栽培条件下,臭氧引起的小麦光合速率降低,达到了显著水平;而盐胁迫下,由臭氧引起的小麦光合速率降低,未达到显著水平。这说明盐胁迫引起的气孔导度降低,起到了减轻臭氧对小麦生长抑制的作用。 3.2.2 渗透调节能力的增强弱化了臭氧的伤害 盐胁迫引起的可溶性糖、可溶性蛋白、脯氨酸等渗透调节物质含量的升高,大大增强了小麦抵御臭氧伤害的能力。如,臭氧往往造成植物蛋白质的分解,降低蛋白质含量;但盐胁迫下,可溶性蛋白含量是上升的,两方面协调,维持了植株蛋白质水平,促进了小麦生长。另一方面,渗透调节物质的积累,有利于小麦同化物的合成、转化和运输,加快了循环的节奏,这也是盐胁迫降低臭氧对小麦伤害的重要原因之一。 3.2.3 抗氧化能力增强降低了臭氧的氧化伤害 盐胁迫引起的小麦酶促保护系统抗氧化酶(SOD、POD等)活性升高,提高了小麦体内活性氧清除能力。臭氧污染可产生大量的活性氧自由基,对小麦产生强氧化伤害,抑制小麦生长。通常情况下,臭氧胁迫也可引起小麦抗氧化酶活性的提高,来适应这种污染环境。本实验表明,在盐和臭氧的交互作用下,小麦抗氧化酶活性的升高呈现了叠加效应,小麦的活性氧清除能力大大加强,减缓了小麦衰老进程,有利于小麦生长。 4 外源硝酸钾对冬小麦盐胁迫伤害的缓解机理及高产栽培技术规程 4.1 不同浓度硝酸钾处理对盐胁迫下小麦幼苗生理代谢的影响 植株体内K+/Na+比值是衡量小麦抗盐性的一项重要指标。盐胁迫下,小麦体内Na+含量快速上升,而K+含量相对下降,K+/Na+比值快速降低,打破了植株体内离子平衡,对小麦造成Na+“单盐毒害”,严重抑制小麦生长。可溶性糖、脯氨酸等低分子量渗透调节物质含量升高;膜质过氧化程度加重,电解质外渗量及丙二醛含量升高;活性氧自由基增多,抗氧化酶活性升高。 外源KNO3显著提高了小麦植株组织内K+/Na+比值,盐胁迫症状减轻,可溶性糖、脯氨酸等低分子量渗透调节物质含量比单独NaCl胁迫时降低;膜质过氧化程度减轻,电解质外渗量及丙二醛含量降低;活性氧自由基减少,抗氧化酶活性恢复到接近正常水平。但过量施用硝酸钾同样不利于小麦的生长。实验结果表明,小麦生长环境中最佳的K+/Na+ = 16:100。 4.2 抽穗期叶面喷施硝酸钾对盐胁迫下小麦花后生长及籽粒产量的影响 根据小麦生长环境中最佳的钾/钠 = 16:100的实验结果,设计了对100 mM NaCl生长环境中小麦抽穗期叶面喷施10 mM KNO3溶液试验(Hoagland 营养液中已含6 mM KNO3),得出外源硝酸钾有利于盐胁迫下小麦生长的恢复及籽粒产量的提高,DK961和JN17的穗粒数分别比单纯盐胁迫时提高了1.9%和7.1%;千粒重分别提高了2.3%和2.8 %;产量分别提高了4.5%和12.3%;叶面喷施钾肥后,盐胁迫对耐盐小麦产量指标影响变小,小麦各项指标恢复到接近于对照水平。盐敏感小麦品种受到盐胁迫的伤害较重,产量下降幅度较大,施钾肥后小麦盐胁迫症状虽有改善,但仍与对照相差较远。所以,盐胁迫下小麦高产优质栽培中,耐盐品种的选用是首要的。 4.3外源硝酸钾对盐胁迫下花后小麦旗叶气体交换的影响 盐胁迫下小麦叶面喷施钾肥,旗叶光合速率在灌浆期比不施钾处理显著升高,且维持高光合速率时间延长,小麦后期衰老速率减缓。由于施钾处理使旗叶光合速率提高,功能期延长,使籽粒可溶性总糖含量和蔗糖含量高于不施钾的处理,促进了淀粉合成底物的供应,由此促进了淀粉的合成。盐胁迫下小麦抽穗期施钾,可促进小麦旗叶、籽粒的碳、氮代谢,淀粉合成速率加快。同时游离氨基酸含量增加,籽粒中蛋白质合成底物的供应增加,蛋白质产量提高。适宜的钾肥处理能够显著促进小麦植株碳、氮代谢过程,加速碳水化合物和蛋白质的合成,使籽粒蛋白质、淀粉产量提高。 4.4外源硝酸钾对盐胁迫下小麦花后旗叶抗衰老酶活性的影响 盐胁迫可使小麦代谢过程中产生的活性氧自由基增多,刺激酶促防御系统的保护酶(如,SOD、POD、CAT等)活性提高,但当盐浓度超过其上限时,酶活性达到一定的极限,活性氧自由基不能及时的清除,代谢发生紊乱,植株加速衰老或不能正常生长,出现“早死”现象。外源硝酸钾可有效缓解这一抑制作用,提高小麦在盐胁迫下的代谢能力,减少活性氧自由基的产生,减轻活性氧清除系统的压力,能较长时间维持叶片细胞结构的完整性,提高小麦抵抗盐胁迫的能力。 4.5 盐胁迫下小麦优质高产栽培技术规程 研究结果表明:选用高产优质抗盐小麦新品种,并合理配合施用钾肥是获得小麦优质高产的一项有效措施: 1) 选用高产优质抗盐小麦新品种 在品种选用上,首先要考虑苗期耐盐力好、个体分蘖强、成穗率高三大因素,在此基础上选择多穗、粒大、粒多的性状。 2)配合施用钾肥 钾肥基施和抽穗期叶面喷施皆对盐胁迫下小麦生长有促进作用。钾肥的施用量应根据土壤盐浓度而定,小麦生长环境中最佳的K+/Na+比值为16:100。

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Ginkgo biloba extract (GBE), a valuable natural product for cerebral and cardiovascular diseases, is mainly composed of two classes of constituents: terpene lactones (e.g., ginkgolide A and B, bilobalide) and flavone glycosides (e.g., quercetin and kaempferol). Its electrophysiological action in heart is yet unclear. In the present study, using whole-cell patch clamp technique, we investigated electrophysiological effects of GBE on cation channel currents in ventricular myocytes isolated from rat hearts. We found that GBE 0.01-0.1% inhibited significantly the sodium current (I-Na), L-type calcium current (I-Ca) and transient outward potassium current (IKto) in a concentration-dependent manner. Surprisingly, its main ingredients, ginkgolide A (GB A), ginkgolide B (GB B) and bilobalide (GB BA) at 0.1 mM did not exhibit any significant effect on these cation channel currents. These results suggested that GBE is a potent non-selective cation channel modulator in cardiaomyocytes. Other constituents (rather than GB A, GB B and GB BA) might be responsible for the observed inhibitory effects of GBE on cation channels. (C) 2004 Elsevier Inc. All rights reserved.

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A new amino silica monolithic column was developed for DNA extraction in a miniaturized format. The monolithic column was prepared in situ by polymerization of tetraethoxysilane (TEOS) and N-(beta-aminoethyl)-gamma-aminopropylmethyldimethoxysilane (AEAPMDMS). DNA was loaded in 50 mM tris(hydroxylmethyl)aminomethane-EDTA buffer at pH 7.0 and eluted with 300 mM potassium phosphate solution at pH 10.0. Under optimal condition, a 6.0-cm monolithic column provided a capacity of 56 ng DNA with an extraction efficiency of 71 +/- 5.2% (X +/- RSD). When the amino silica monolithic column was applied to extract genomic DNA from the whole blood of crucian carp, an extraction efficiency of 52 +/- 5.6% (X +/- SD) was obtained by three extractions. Since the chaotropic-based sample loading and organic solvent wash steps were avoided in this procedure, the purified DNA was suitable for downstream processes such as PCR. This amino silica monolithic column was demonstrated to allow rapid and efficient DNA purification in microscale.

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Microcystins (MCs) are a family of related cyclic hepatotoxic heptapeptides, of which more than 70 types have been identified. The chemically unique nature of the C20 beta-amino acid, (2S, 3S, 8S, 9S)-3-amino-9-methoxy-2,6,8-trimethyl-10-phenyldeca4,6-dienoic acid (Adda), portion of the MCs has been exploited to develop a strategy to analyze the entirety. Oxidation of MCs causes the cleavage of MC Adda to form 2-methyl-3-methoxy-4-phenylbutanoic acid (MMPB). In the present study, we investigated the kinetics of MMPB produced by oxidation of the most-often-studied MC variant, MC-LR (L = leucine, R = arginine), with permanganate-periodate. This investigation allowed insight regarding the influence of the reaction conditions (concentration of the reactants, temperature, and pH) on the conversion rate. The results indicated that the reaction was second order overall and first order with respect to both permanganate and MC-LR. The second-order rate constant ranged from 0.66 to 1.35 M/s at temperatures from 10 to 30 degrees C, and the activation energy was 24.44 kJ/mol. The rates of MMPB production can be accelerated through increasing reaction temperature and oxidant concentration, and sufficient periodate is necessary for the formation of MMPB. The initial reaction rate under alkaline and neutral conditions is higher than that under acidic conditions, but the former decreases faster than the latter except under weakly acidic conditions. These results provided new insight concerning selection of the permanganate-periodate concentration, pH, and temperature needed for the oxidation of MCs with a high and stable yield of MMPB.

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Due to specific adsorption to variable charge soils, low molecular weight organic acids (LMWOAs) have not been sufficiently extracted, even if common extractants, such as water and 0.1 M sodium hydroxide (NaOH), were employed. In this work, the method for extracting LMWOAs in soils with 0.1 M NaOH was improved for variable charge soils; e.g. 1.0 M potassium fluoride (KF) with pH 4.0 was applied as an extractant jointed with 0.1 M NaOH based on its stronger ability to change the electrochemical properties of variable charge soils by specific adsorption. With the proposed method, the recoveries of oxalic, tartaric, malic, citric and fumaric acids were increased from 83 4, 93 1, 22 2, 63 +/- 5 and 84 +/- 3% to 98 +/- 2, 100 +/- 2, 85 +/- 2, 90 +/- 2 and 89 +/- 2%, respectively, compared with NaOH alone. Simultaneously, the LMWOAs in Agri-Udic Ferrosol with field moisture were measured with a satisfactory result.

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A sediment core was collected from the centre of Wanghu Lake, in the Middle Reaches of the Yangtze River. The recent part of the core was dated using a combination of Pb-210 and spheroidal carbonaceous particle (SCP) techniques. Extrapolating this chronology dated the laminated section of the core, between 723 and 881 mm, to the first half of the 18th century and this section was selected for detailed study. The thicknesses of the laminae were measured using reflecting and polarizing microscopes whilst geochemistry was determined by an electron probe. The thickness of the dark layers was found to be positively correlated with titanium concentrations, and negatively correlated with aluminium and potassium concentrations. The thickness of the light layers was found to be negatively correlated with the concentrations of titanium. It is concluded that the dark layers were deposited from the Fushui River, a tributary of the Yangtze River, under periods of normal flow whilst the light Layers were mainly deposited from the Yangtze River itself during flood periods. Documentary evidence for floods occurring in the take catchment corresponded with thick laminations of high titanium concentration. Further, two of the three thickest, light laminations with low titanium concentrations were found to be synchronous with recorded flood dates of the main Yangtze River in its Middle Reaches, but one was synchronous with a local drought. These data suggest that the Lake sediment provides an archive of the relative water levels of the Yangtze and Wanghu including floods of both the main Yangtze River and the local hydrological regime. (c) 2006 Elsevier B.V. All rights reserved.

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Changes in acidity of Udic Ferrosols, caused by growth of Choerospondias axillaris (Roxb.) Burtt et Hill, in comparison to wild grass, were investigated for pH distribution in the soil profile, exchangeable acidity, and cation status in the soil leachate of a simulated leaching experiment. Soils were sampled in profiles at 5 cm intervals to a depth of 100 cm. In the 1.5-60 cm layer the soils with 10-year old C. axillaris had significantly lower pH (P < 0.05), with the largest difference being 0.41: and in the 25-75 cm soil depths, especially in the 30-55 cm layer, the soils had a significantly higher exchangeable acidity, ranging 1.93 to 3.02 cmol(c) kg(-1). There was also higher aluminum, potassium, and sodium contents in the soil leachate under C. axillaris than with wild grasses. This suggested that the growth of C. axillaris accelerated acidification of Udic Ferrosols and promoted soil clay mineral weathering.

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The effects of nutrients on the photosynthetic recovery of Nostoc flagelliforme during re-hydration were investigated in order to see if their addition was necessary. Net photosynthesis was negligible in distilled water without nutrient-enrichment. Addition of K+ resulted in significant enhancement of net photosynthesis, whereas other nutrients (Fe3+, Mg2+, Na+, NO3-, PO43-, Cl-) and trace-metals (A(5)) showed little effect. The recovered net photosynthetic activity increased with the increased K+, and reached the maximum at concentrations above 230 mu M. Desiccation and re-hydration did not affect the dependence of photosynthetic recovery on K+. It was concluded that dried field populations of N. flagelliforme require exogenous addition of potassium for photosynthetic recovery and that growth may be potassium-limited in nature.

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A 3-dB paired interference (PI) optical coupler in silicon-on-insulator (SOI) based on rib waveguides with trapezoidal cross section was designed with simulation by a modified finite-difference beam propagation method (FD-BPM) and fabricated by potassium hydroxide (KOH) anisotropic chemical wet etching. Theoretically, tolerances of width, length, and port distance are more than 1, 100, and 1 mu m, respectively. Smooth interface was obtained with the propagation loss of 1.1 dB/cm at the wavelength of 1.55 mu m. The coupler has a good uniformity of 0.2 dB and low excess loss of less than 2 dB.

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(Na1-xKx)(0.5)Bi0.5TiO3 (NKBT) (x = 0.1, 0.2, and 0.3) thin films with good surface morphology and rhombohedral perovskite structure were fabricated on quartz substrates by a sol-gel process. The fundamental optical constants (the band gaps, linear refractive indices and absorption coefficients) of the films were obtained through optical transmittance measurements. The nonlinear optical properties were investigated by Z-scan technique performed at 532 nm with a picosecond laser. A two-photon absorption effect closely related with potassium-doping content was found in thin films, and the nonlinear refractive index n(2) increases evidently with potassium-doping. The real part of the third-order nonlinear susceptibility chi((3)) is much larger than its imaginary part, indicating that the third-order optical nonlinear response of the NKBT films is dominated by the optical nonlinear refractive behavior. These results show that NKBT thin films have potential applications in nonlinear optics. (C) 2007 Elsevier B.V. All rights reserved.

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A 3-dB multimode interference optical coupler based on rib waveguides with trapezoidal cross section was designed and fabricated on silicon-on-insulator wafer. Potassium hydroxide (KOH) anisotropic chemical etching of silicon was used to fabricate the waveguides to obtain smooth interface. A modified finite-difference beam propagation method was used to simulate the multimode rib waveguide with slope interfaces. The rms roughness of etching interface is as small as 1.49 nm. The propagation loss of the waveguide is 1.3 dB/cm at wavelength of 1.55 mum. The fabricated 3-dB coupler has a good uniformity of 0.2 dB.

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A folding nonblocking 4 X 4 optical matrix switch in simplified-tree architecture was designed and fabricated on a silicon-on-insulator wafer. To compress chip size, switch elements (SEs) were connected by total internal reflection mirrors instead of conventional S-bends. For obtaining smooth interfaces, potassium hydroxide (KOH) anisotropic chemical etching of silicon was employed. The device has a compact size of 20 X 3.2 mm(2) and a fast response of 8 +/- 1 mu s. Power consumption of 2 x 2 SE and excess loss per mirror were 145 mW and -1.1 dB, respectively. (c) 2005 Society of Photo-Optical Instrumentation Engineers.

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A folding rearrangeable nonblocking 4 x 4 optical matrix switch was designed and fabricated on silicon-on-insulator wafer. To compress chip size, switch elements (SEs) were interconnected by total internal reflection (TIR) mirrors instead of conventional S-bends. For obtaining smooth interfaces, potassium hydroxide anisotropic chemical etching of silicon was utilized to make the matrix switch for the first time. The device has a compact size of 20 x 1.6 mm(2) and a fast response of 7.5 mu s. The power consumption of each 2 x 2 SE and the average excess loss per mirror were 145 mW and -1.1 dB, respectively. Low path dependence of +/- 0.7 dB in total excess loss was obtained because of the symmetry of propagation paths in this novel matrix switch.