Microcalorimetric studies of the iridium catalyst for hydrazine decomposition reaction

Microcalorimetric studies of H-2, NH3 and O-2 adsorption, as well as the NH3 decomposition activities evaluation were used to characterize the iridium catalysts for hydrazine decomposition with different supports (Al2O3, SiO,) and iridium contents (1.8, 10.8 and 22.1%). The higher H-2 chemisorption amounts on Ir/Al2O3 catalysts than those on the corresponding Ir/SiO2 counterparts revealed that the strong interaction of iridium and Al2O3 led to higher dispersion of iridium on Ir/Al2O3 catalysts than on Ir/SiO2 catalysts. The larger increase in strong H-2 adsorption sites on highly loaded Ir/Al2O3 than the corresponding Ir/SiO2 ones could be attributed to the interaction not only between iridium atoms but also between iridium and Al2O3. The microcalorimetric results for NH3 adsorption showed that no apparent chemisorption of NH3 existed on Ir/SiO2 catalysts while NH3 chemisorption amounts increased on Ir/Al2O3 catalysts with iridium loadings, which arose from the interaction of the catalysts support of Al2O3 With chloride anion. Both highly dispersed iridium active sites and chloride anion on Ir/Al2O3 catalysts could be beneficial to the intermediate NH3 decomposition in N2H4 decomposition. The similar O-2 plots of differential heat versus normalized coverage on Ir/Al2O3 and Ir/SiO2 catalysts could not be due to the metal-support interaction, but to the formation of strong Ir-O bond. (C) 2005 Elsevier B.V. All rights reserved.

Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells

A series of PtRu nanocomposites supported on H2O2-oxidized multi-walled carbon nanotubes (MWCNTs) were synthesized via two chemical reduction methods - one used aqueous formaldehyde (HCHO method) and the other used ethylene glycol (EG method) as the reducing agents. The effects of the solvents (water and ethylene glycol) and the surface composition of the MWCNTs on the deposition and the dispersion of the metal particles were investigated using N-2 adsorption. TEM. ICP-AES. FTIR and TPD. The wetting heats of the MWCNTs in corresponding solvents were also measured. The characterizations suggest that combination of the surface chemistry of the MWCNTs with the solvents decides the deposition and the dispersion of the metal nanoparticles. These nanocomposites were evaluated as proton exchange membrane fuel cell anode catalyts for oxidation of 50 ppm CO contaminated hydrogen and compared with a commercial PtRu/C catalyst. The data reveal superior performances for the nanocomposites prepared by the EG method to those by the HCHO method and even to that for tile Commercial analogue. Structure performance relationship of the nanocomposites was also studied. (C) 2005 Elsevier Ltd. All rights reserved.

Factors influencing the catalytic activity of SBA-15-supported copper nanoparticles in CO oxidation

Copper nanoparticles were deposited onto mesoporous SBA-15 support via two different routes: post-grafting method and incipient wet impregnation method. Both XRD and TEM reveal that the post-grafting can make Cu particles very small in size and highly dispersed into channels of SBA-15, while the impregnation method mainly forms large Cu particles on the external surface of SBA-15. TPR experiments show that CuO species formed by the post-grafting method is more reducible than that prepared by the impregnation method. The catalytic activity tests for CO oxidation manifests that the sample prepared by the post-grafting method has a much higher activity than that prepared by the impregnation method, with a lowering of 50 degrees C for T-50, showing a strong dependence of catalytic activity on the size and dispersion of Cu particles. Besides the preparation procedure, other factors including calcination temperature, reduction treatment, copper loading as well as the feed composition, have an important effect on the catalytic activity. The best performance was obtained when the catalyst was calcined at 500 degrees C and reduced at 550 degrees C. The calcination and reduction treatment at high temperature have been found to be necessary to completely remove the organic residue and to generate active metallic copper particles. (c) 2005 Elsevier B.V. All rights reserved.

Redox cycling of Ni-YSZ anode investigated by TPR technique

Effect of redox cycling on a Ni-YSZ anode prepared from 50 wt.% NiO and 50 wt.% YSZ was investigated by using temperature-programmed reduction (TPR), XRD and SEM techniques. XRD results showed that NiO was formed during re-oxidation. Both the XRD and TPR results depicted that the conversion of nickel to NiO depended on the re-oxidation temperature. The oxidation of Ni to NiO occurred quickly in the initial several minutes and then reached a quasi equilibrium. The TPR profiles tracing the redox cycling showed that it brought continuous changes in the NiO micro-structure at 800 degrees C, whereas at 600 degrees C it had only little effects on the reduction of NiO. Re-oxidation resulted in the formation of spongy aggregates of NiO crystallites. Redox cycling at 800 degrees C led to a continuous decrease in the primary crystallite size of NiO and a high dispersion of the Ni particles. A continuous expansion of the slice sample was observed in both of the oxidized and reduced states during the redox cycling at 800 degrees C, whereas this process did not occur during the redox cycling at 600 degrees C. (c) 2005 Elsevier B.V All rights reserved.

二元体系胶体晶体性质的实验研究

利用Kossel衍射技术和反射光谱对由总体积分数为0.02的二元聚苯乙烯胶体体系(94 nm+141 nm)形成的胶体晶体的性质进行了研究,实验结果显示胶体晶体的形成时间,平均粒子间距,晶体结构都与二元胶体体系中两种粒子的数密度比相关,当94 nm聚苯乙烯粒子相对于141 nm聚苯乙烯粒子的数密度比趋向1∶1时,胶体晶体的形成时间延长,当94 nm聚苯乙烯粒子相对于141 nm聚苯乙烯粒子的数密度比由1∶0向0∶1变化时,胶体晶体的平均粒子间距变大,另外实验中发现在两种粒子的数密度比为5∶1时,胶体晶体出现了超晶格结构. 

高能离子在稠密等离子体中的传输和能量沉积

用相对论福克-普朗克方程对高能离子在稠密氘氚等离子体中的碰撞动力学进行了研究,用球谐函数来展开方程的解：格林函数,然后简明地求出了不同能量质子和α粒子在等离子体中的停止时间、减速距离、纵向弥散距离和横向偏转距离.与以前研究离子在等离子体中运动的方法相比,没有假设高能离子在等离子体中损失能量远远小于入射离子能量,求解了纵向弥散距离;并且可以求解横向偏转距离.这些计算对实验上用高能离子加热冷的稠密等离子体,然后进行科学研究具有指导作用,并且可以用来研究快点火的可能性.

Upper level and phase controlling group velocity in V-type system

With the external field coupling the two upper levels, we investigate the light pulse propagation properties with weak probe field in a V-type system. Due to the external upper level (UL) coupling field, the dispersion of the system has been influenced by the relative phase. It is shown that the UL field and the relative phase can be regarded as switches to manipulate light propagation between subluminal and superluminal. (c) 2007 Elsevier B.V. All rights reserved.

展宽器元件失调及带通分析

通过光线追迹法给设计的反射式单光栅展宽器建立了一个数学计算模型。利用这个数学模型计算和分析了元件失调对反射式单光栅展宽器二阶色散量和输出光束发散角的影响，并考虑了反射式单光栅展宽器中衍射光栅和球形凹面镜的尺寸与展宽器带通的关系。发现当平面反射镜M1的纵向偏离角为0．2°时．展宽器的二阶色散量最大，偏离角大于或小于0．2°时，展宽器的二阶色散量随之减小；得到了元件失调会增加输出光束发散角的结论；并发现展宽器中衍射光栅和球形凹面镜尺寸的有限大小对带通有限制作用。提出了利用反射镜M1纵向的适当偏离增大展宽器二阶

BaF2替代BaO对钡镓锗酸盐玻璃光学性质的影响

在摩尔分数组成x(BaO),r(Ga2O),r(GeO2)为0．20，0．15,0．65的玻璃中，分别以摩尔分数0．05，0．10．0．15和0．20的BaF2替代BaO,研究了氟化物对玻璃折射率和光吸收性质的影响。结果表明，在玻璃中加入氟化物．玻璃折射率和色散降低，玻璃的紫外吸收边向短波侧迁移，而红外吸收边无明显变化。不含氟化物的氧化物玻璃中含有大量的OH基．这些OH基在2．24μm、2．97μm和4．23μm附近引起光吸收．在含氟化物的玻璃中，2．24μm的吸收峰消失，而2．97μm和4．23μm附近

三硼酸锂晶体上1064 nm, 532 nm, 355 nm三倍频增透膜的设计

采用矢量法设计了三硼酸锂晶体上1064 nm、532 nm和355 nm三倍频增透膜,结果表明1064 nm、532 nm和355 nm波长的剩余反射率分别为0.0017％、0.0002％和0.0013％。根据误差分析,薄膜制备时沉积速率精度控制在＋5.5％时,1064 nm、532 nm和355 nm波长的剩余反射率分别增加至0.20％、0.84％和1.89％。当材料折射率的变化控制在＋3％时,1064 nm处的剩余反射率增大为0.20％,532 nm和355 nm处分别达0.88％和0.24％。与薄膜

Rashba electron transport in one-dimensional quantum waveguides

The properties of Rashba wave function in the planar one-dimensional waveguide are studied, and the following results are obtained. Due to the Rashba effect, the plane waves of electron with the energy E divide into two kinds of waves with the wave vectors k(1)=k(0)+k(delta) and k(2)=k(0)-k(delta), where k(delta) is proportional to the Rashba coefficient, and their spin orientations are +pi/2 (spin up) and -pi/2 (spin down) with respect to the circuit, respectively. If there is gate or ferromagnetic contact in the circuit, the Rashba wave function becomes standing wave form exp(+/- ik(delta)l)sin[k(0)(l-L)], where L is the position coordinate of the gate or contact. Unlike the electron without considering the spin, the phase of the Rashba plane or standing wave function depends on the direction angle theta of the circuit. The travel velocity of the Rashba waves with the wave vector k(1) or k(2) are the same hk(0)/m*. The boundary conditions of the Rashba wave functions at the intersection of circuits are given from the continuity of wave functions and the conservation of current density. Using the boundary conditions of Rashba wave functions we study the transmission and reflection probabilities of Rashba electron moving in several structures, and find the interference effects of the two Rashba waves with different wave vectors caused by ferromagnetic contact or the gate. Lastly we derive the general theory of multiple branches structure. The theory can be used to design various spin polarized devices.

Broadband Emitting Superluminescent Diodes With InAs Quantum Dots in AlGaAs Matrix

Superluminescent diodes were fabricated by using InAs-AlGaAs self-assembled quantum dots (QDs) as the active region. The ultrawide emitting spectrum of 142 nm was achieved. The short migration length of indium adatoms on AlGaAs surface increases the size dispersion of InAs QDs, resulting in the broadening of optical gain spectrum.

Spin-polarized ballistic transport in diluted magnetic semiconductor quantum wire systems

The energy dispersion of an electron in a double quantum wire with a diluted magnetic semiconductor barrier in between is calculated. An external magnetic field modifies significantly the energy dispersion of the electron which is different for the two spin states. The conductance exhibits many interesting peaks and dips which are directly related to the energy dispersions of the different electron spin states. These phenomena are attributed to the interwell coupling which can be tuned by the magnetic field due to the s-d exchange interaction.

Thermally stable chromophores for nonlinear optical applications

Three thermal organic second-order nonlinear optical chromophores were synthesized. The decomposition temperature was determined by DSC, and the absorption spectra was measured. The second-order polarizabilities at zero energy and the dispersion of second-order polarizabilities were measured by solvatochromic method. (C) 2002 Elsevier Science Ltd. All rights reserved.

土壤种子库研究进展

在浏览国内外大量文献的基础上,从土壤种子库研究意义、国内外研究现状和目前研究的热点问题等方面论述土壤种子库的研究进展。针对目前土壤种子库研究的热点问题,主要从土壤种子库的分类、种子质量和种子休眠之间的关系、种子库的水平分布及种子库与地上植被的关系等方面进行讨论,指出其在遗传结构和扩散等研究内容及方法方面所存在的问题,并提出了相应的建议。