Characterization of metal-containing molecular sieves and their catalytic properties in the selective oxidation of cyclohexane

Three types of metal-containing molecular sieves with AFI, AEL and CHA structures (Me = Co, Mn, Cr and V) were synthesized hydrothermally and characterized by XRD, XRF, TG, TPR, NH3-TPD and FT-IR. It was revealed that metals were incorporated into the framework of molecular sieves and induced the presence of charge centers. Both cobalt and manganese in the framework of AIPO-5, AlPO-11 and SAPO-34 were not reducible before the structure collapse. The redox behaviours of these catalysts in cyclohexane oxidation at 403 K using O-2 as oxidant were examined. CoAPO-11 exhibited best activity and good selectivities for the monofunctional oxidation products (88.5%). Cyclohexanol was the major product over most catalysts, whereas for Cr-containing molecular sieves, high selectivity of cyclohexanone was observed. Investigation of reaction mechanism based on CoAPO-11 and CrAPO-5 catalysts indicated that the decomposition of cyclohexyl hydroperoxide (CHHP), the intermediate in cyclohexane oxidation, followed the pathway: cyclohexanone <-- CHHP --> cyclohexanol -->cyclohexanone. (C) 2004 Elsevier B.V. All rights reserved.

氮和磷在饲养-堆腐环中的循环率及有机肥料养分利用率

A five-year experiment indicated that the average loss rate of N and P in harvested products through a feeding-composting cycle was about 50% and 15%,respectively.Under high yield condition,the amount of recycled N and P from 80% harvested products and through a feeding-composting cycle in farming systems was about 3751 and 814 kghm~(-2),equivalent to 25%34% of N and 32%56% of P from chemical fertilizers applied each year to the systems.The apparent recoveries of N and P in organic manure increased with the prolongation of fertilization,indicating a synergetic residual effect existed,and was 61% and 39% in average in the five-year experiment.The use of nutrients recycled in the farming systems could not only improve soil fertility,but also increase the recoveries of nutrients and reduce the use of chemical fertilizers.

抚顺西露天矿西排土场土地复垦植被构建研究

对抚顺西露天矿西排土场进行了土壤养分及环境质量分析,调查了西排土场植被演替现状,进行排土场植物复垦研究。结果表明排土场矸石土壤土壤贫瘠,为3类土壤,需对排土场进行生态恢复与重建。筛选出适合于排土场不同土地类型的复垦植物,提出排土场植物配置应以乔、灌、草的带状、块状、丛状复合混交,形成立体结构相对稳定的人工植物群落。

黑龙江大兴安岭地区森林害虫发生面积与气象因子的关系

对黑龙江大兴安岭地区6个气象台站的气象资料进行整理和分析,从中筛选出影响虫害发生面积的7个气象因子,并分别对其做相关分析,研究了气象因子对种群数量的影响,模拟虫害发生面积预测方程。结果表明:与虫害发生面积密切相关的因子有年积温(≥10℃)、年降水量和干燥度;虫害发生面积同三者的Pearson相关系数分别为0.701、-0.814和0.937;通过分析极端气候现象对虫害面积的影响,发现春季阴雨和虫害面积存在显著的正相关关系,冬冻和春寒对虫害发生面积并没有直接的影响。

土壤不同形态氮素在剖面中移动特征的模拟研究

应用室内土柱模拟试验方法 ,在可控水量条件下 ,研究不同水量淋溶情况下 ,土壤不同形态氮素在剖面中的分布和移动特征。研究表明 ,土壤有机氮组分中 ,氨基酸氮和 NH3- N是易于移动的形态 ,非酸解性氮则相对稳定 ;无机氮组分中 NO- 3 - N是易于移动的形态 ,NH+ 4 - N运移性差 ,非交换态 NH+ 4 - N为相对稳定形态 ;水、肥条件是决定 NO- 3 - N淋失的重要因素。研究结果为认识和掌握土壤氮素在剖面中的运移规律 ,为农田水分和氮素养分管理提供了科学依据 ;同时为深入揭示土壤中各种形态氮运移动态机制 ,展示了模拟实验技术的前景

沙地马铃薯不同灌溉方式的经济效益分析

从投资回收期和益本比2个方面,对靖边县沙地马铃薯半固定式喷灌、滴灌、大型喷灌机喷灌3种灌溉方式进行经济效益分析,在经济分析的基础上,采用层次分析法,对3种灌溉方式进行综合效益评价。结果表明,半固定式喷灌、滴灌、大型喷灌机喷灌的投资回收期分别为2.1 a,0.6 a,0.9 a,效益费用比分别为2.6,7.9,7.6,滴灌的经济效益十分明显;3种灌溉方式的优劣排序为:滴灌最好,半固定式喷灌次之,大型喷灌机喷灌较差。

黄绵土不同形态有机氮径流流失规律

利用不同坡度径流小区 ,在自然降水条件下 ,研究侵蚀泥沙不同形态有机氮的流失规律 ,结果表明 :在 4次产流泥沙中 ,除氨基糖氮含量减少外 ,其它有机形态氮均存在增加趋势 ,以氨态氮含量增加最为显著。随坡度的下降 ,水解全氮、氨态氮和氨基酸氮含量呈增加趋势 ;泥沙中水解全氮、氨基酸氮、氨态氮、非酸水解氮均存在不同程度的富集 ,其富集率随坡度的下降而增大 ,以氨基酸氮富集程度高 ,泥沙中氨基糖态氮反而无富集现象存在 ;当坡度分别为 2 5°、2 0°、15°、10°和 5°时 ,水解全氮流失量分别为 1135 .0、76 3.7、485 .5、313.0和 15 4.4kg/ km2 ,而氨基酸氮流失量则为 2 34.8、182 .7、12 1.1、76 .8和 33.9kg/ km2 ,占水解全氮的 2 0 .6 %～ 2 4.9%。氨态氮流失量为 742 .5、5 0 3.3、32 2 .2、2 0 8.9、97.4kg/ km2 ,占水解全氮的 6 3.1%～ 6 6 .7%。氨基糖氮占酸水解氮 1.1%～ 2 .9%。非鉴别氮占水解全氮的 5 .8%～ 12 .6 %。而酸水解氮与非酸水解氮之比分别为 ...

杨树细根及草根的生产力与周转的研究

对北方杨树人工林 0～ 40cm土层中杨树细根和草根 (≤ 2mm )年生物量、分解量、死亡量、生长量和周转率进行观测研究 .结果表明 ,杨树细根的年生物量为 2 .0 6 2t·hm-2 ,死根生物量为 0 .746t·hm-2 ,分解量为0 15 8t·hm-2 ,生长量为 2 .35 1t·hm-2 ,周转率为每年 1.14次 .活草根的年生物量、死根生物量、分解量、生长量和周转率分别 0 .5 0 1、0 .0 35、0 .0 2 3、0 .6 91t·hm-2 和 1.38.同时给出了杨树细根干重损失随分解时间变化的方程 :lnx/x0 =0 .95 15e-0 .0 0 14t.

Theoretical studies on electronic structures, spectra and charge transporting properties of a series of Pt((CN)-N-Lambda)(2) complexes

We report a quantum-chemical study of electronic, optical and charge transporting properties of four platinum (II) complexes, pt((CN)-N-Lambda)(2) ((CN)-N-Lambda=phenylpyridine or thiophenepyridine). The lowest-lying absorptions at 442, 440, 447 and 429 nm are all attributed to the mixed transition characters of metal-to-ligand charge transfer (MLCT) and ligand-centered (LC) pi - pi(*) transition. While, unexpectedly, the lowest-lying phosphorescent emissions at 663, 660, 675 and 742 nm are mainly from metal-to-ligand charge transfer ((MLCT)-M-3) ligand-centered (LC) pi ->pi* transition. Ionization potential (IP), electron affinities (EA) and reorganization energy P (lambda(hole/electron)) were obtained to evaluate the charge transfer and balance properties between hole and electron.

Sol-gel synthesis and characterization of SiO2@CaWO4, SiO2@CaWO4 : Eu3+/Tb3+ core-shell structured spherical particles

Nanocrystalline CaWO4 and Eu3+ (Tb3+)-doped CaWO4 phosphor layers were coated on non-aggregated, monodisperse and spherical SiO2 particles by the Pechini sol-gel method, resulting in the formation of SiO2@CaWO4, SiO2@CaWO4:Eu3+/Tb3+, core-shell structured particles. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), photoluminescence (PL), low-voltage cathodoluminescence (CL), time-resolved PL spectra and lifetimes were used to characterize the core-shell structured materials. Both XRD and FT-IR indicate that CaWO4 layers have been successfully coated on the SiO2 particles, which can be further verified by the FESEM and TEM images. The PL and CL demonstrate that the SiO2@CaWO4 sample exhibits blue emission band WO42- with a maximum at 420 nm (lifetime = 12.8 mu s) originated from the 4 groups, while SiO2@CaWO4:Eu3+ and SiO2@CaWO4:Tb3+ show additional red emission dominated by 614 nm (Eu3+:D-5(0)-F-7(2) transition, lifetime = 1.04 ms) and green emission at 544 nm (Tb3+:D-5(4)-F-7(5) transition, lifetime = 1.38 ms), respectively.