The diphasic nc-Si/a-Si : H thin film with improved medium-range order

A series of silicon film samples were prepared by plasma enhanced chemical vapor deposition (PECVD) near the threshold from amorphous to nanocrystalline state by adjusting the plasma parameters and properly increasing the reactions between the hydrogen plasma and the growing surface. The microstucture of the films was studied by micro-Raman and Fourier transform infrared (FTIR) spectroscopy. The influences of the hydrogen dilution ratio of silane (R-H = [H-2]/[SiH4]) and the substrate temperature (T-s) on the microstructural and photoelectronic properties of silicon films were investigated in detail. With the increase of RH from 10 to 100, a notable improvement in the medium-range order (MRO) of the films was observed, and then the phase transition from amorphous to nanocrystalline phase occurred, which lead to the formation of diatomic hydrogen complex, H-2* and their congeries. With the increase of T-s from 150 to 275 degreesC, both the short-range order and the medium range order of the silicon films are obviously improved. The photoconductivity spectra and the light induced changes of the films show that the diphasic nc-Si/a-Si:H films with fine medium-range order present a broader light spectral response range in the longer wavelength and a lower degradation upon illumination than conventional a-Si:H films. (C) 2004 Elsevier B.V. All rights reserved.

Hydrogen related defects in neutron-irradiated silicon grown in hydrogen ambient

Isochronal thermal-annealing behavior of NTD floating-zone silicon grown in hydrogen ambient (called NTD FZ(H) Si) is presented. The dependencies of resistivity and carrier mobility on annealing temperature are determined by room-temperature Hall electrical measurements. Using infrared absorption spectroscopy, hydrogen-related infrared absorption bands evolution for NTD FZ(H) Si were measured in detail. It is demonstrated that compared with NTD FZ(Ar) Si, NTD FZ(H) Si exhibits the striking features upon isochronal annealing in temperature range of 150 similar to 650 degreesC: there appears the formation of an excessive shallow donor at annealing temperature of 500 degreesC. It is shown that the annealing behavior is directly related to the reaction of hydrogen and irradiation-induced defects. The evolution of infrared absorption bands upon temperature reflects a series of complex reaction process: irradiation-induced defects decomposition, breaking of Si-H bonds, migration and aggregation of atomic hydrogen, and formation of the secondary defects. (C) 2002 Elsevier Science B.V. All rights reserved.

辽宁南芬生态适宜性评价与空间生态规划研究

空间生态规划着重于研究城乡土地和空间资源，达到城乡土地和空间资源合理配置。辽宁本溪市南芬区属山地资源型工矿城镇，由于空间用地类型配置不合理，中心城区环境污染严重，而广阔的乡村空间资源未尽其用。为此，有必要对南芬全区城乡空间进行生态规划。本文在理论上补充空间生态规划中生态适宜性评价理论，在方法上提出了基于适宜性评价的空间生态规划方法后，就南芬主要用地类型工业用地、居住用地、作物用地和林业用地分别进行生态适宜性评价和用地配置研究，并综合适宜性评价结果和探讨了南芬空间生态分区及空间生态规划途径。 主要结果为：(1) 工业用地最适宜区、次适宜、勉强适宜和不适宜区面积分别为91.23km2、182.72km2、182.08km2和162.97km2；居住用地分别为208.08km2、169.95km2、149.51km2和91.46km2；作物用地分别为124.23km2、130.65km2、159.02km2和205.1km2；林业用地分别为201.7km2、150.43km2、130.21km2和136.66km2。(2) 工业用地现状位于最适宜区、次适宜区、勉强适宜区、不适宜区的面积分别为9.81km2、10.66km2、6.54km2和11.73km2；居住用地分别为9.05 km2、12.57km2、15.7km2和11.53km2；作物用地分别为16.61km2、7.88km2、22.25km2和24.15km2；林业用地分别为193.91km2、104.88km2、81.74km2和67.27km2。(3)综合评价表明，工业用地、居住用地、作物用地、林业用地适宜区面积分别为46.75km2；71.32km2；94.46km2；406.47km2。南芬生态空间区划为生态保护区、生态居住区（2个）和生态工业区（3个）。(4) 最后详细阐述了南芬城乡空间生态规划途径及其内涵，即：生态优先、整体优化、经济优效和社会持续。

长白山阔叶红松林种子雨组成与时空格局

种子雨是森林植物种群更新的主要方式之一，是森林生态系统自我繁衍和恢复的主要手段。为了解长白山阔叶红松林种子雨的组成及其时空变化，参照BCI 50ha 样地技术规范，在长白山阔叶红松林25ha长期监测样地内设置了150个种子收集器，从2006年5月15日到2007年11月8日，每15天收集掉落于收集器中的果实、种子及其相关附属物等。所收到的样品分别鉴定其种类并分为成熟种实、未成熟种实、花絮、果实或种子碎片及其附属物4类，记录各类别的数量，然后分别烘干称重。 研究期间，共收集到11科12属22种木本植物的种子及其它生殖器官残体，包括成熟种实16种，未成熟种实17种，花序12种，翅2种，果实或种子碎片及其附属物10种。累计收集到种实136664粒，其中成熟种实32358粒，占所有种实总数的23.80%。种实数最多的树种是紫椴(Tilia amurensis)，其次为水曲柳(Fraxinus mandshuica)，两个树种种实数占总数的89.54%。种实总重量为3320.93g，其中成熟种实总重量为1242.85g，占37.4%。成熟种实中水曲柳和紫椴的重量最大，其次是色木槭(Acer mono)，假色槭(A. pseudo-sieboldianum)、糠椴(T. mandshuric)和红松(Pinus koraiensis)。 种子雨数量年际变化明显，2006年种子雨密度为1370.25粒/m2，2007年为249.47粒/m2，差异极显著(P<0.001)。但不同年份种子雨的季节动态趋势一致，均有两个明显的大高峰期和一个小高峰期。不同物种种子雨扩散的时间格局大致可以分为“单峰”和“双峰”两种类型，在时间上体现了不同物种的更新策略。 150个收集器均收到了成熟种实，各收集器中的种实数呈偏态分布，种实数在150-250之间的收集器数量最多，共68个，种实数小于50的收集器有5个，种实数大于250的收集器共37个。样地内成熟种实数量及其空间分布差异明显，收集器中种实数在1000个以上的有3个，最多达1511个，聚集分布于样地的西北角；收集器中种实数最少的只有22个种实。种实重量的空间分布与种实数分布一样存在较明显的空间差异，只是差异性相对偏弱一些，且与种实数量的空间分布不一致。