贵州万山汞矿区土壤汞污染现状的初步调查

运用AAS和GC-CVAFS法分别测定了贵州万山汞矿区表层土壤中的总汞(THg)和甲基汞(MeHg),探讨了土壤中THg和MeHg的含量分布特征:矿区土壤THg和MeHg含量分别为1.1～790 mg/kg和0.13～15 μg/kg;对照区土壤THg和MeHg含量分别为0.10～1.2 mg/kg和0.10～0.28 μg/kg.矿区不同耕作类型土壤中,稻田和菜地土壤MeHg含量明显高于旱田土壤.

黔东南锦屏金矿成矿模式的模拟实验

利用中国科学院地球化学研究所矿床地球化学国家重点实验室的实验设备对黔东南锦屏金矿进行了成矿模式的模拟实验。通过剪切实验，变形、破裂实验，成矿物质活化、迁移实验。成矿模式模拟实验和多次应力实验，获得了成矿物质以碎粒流和塑性流动的方式顺层及穿层充填并在褶曲核部富集的结果。多次应力实验使成矿物质叠加富集。实验结果初步证实了锦屏石英脉金矿的成矿模式，为该区构造控制金矿提供了重要的实验资料，也为今后研究该区金矿的成矿规律和找矿提供了有益的信息.

Optimization and parameter study for chiral separation by capillary electrophoresis

Orthogonal design and uniform design were used for the optimization of separation of enantiomers using 2,6-di-O-methyl-beta-cyclodextrin (DM-beta-CD) as a chiral selector by capillary zone electrophoresis, The concentration of DM-beta-CD, buffer pH, running voltage, and capillary temperature were selected as variable parameters, their different effects on peak resolution were studied by the design methods. It was concluded that orthogonal design offers a rapid and efficient means for testing the importance of individual parameters and for determining the optimum operating conditions. However, for a large number of both factors and levels, uniform design is more efficient, The effect of addition of methanol and citric acid buffer on the separation of enantiomers was also examined.