The enhanced immune protection of Zhikong scallop Chlamys farreri on the secondary encounter with Listonella anguillarum

It is well known that invertebrates are devoid of adaptive immune components and rely primarily on innate immunity to defend against pathogens, but recent studies have demonstrated the existence of enhanced secondary immune protection in some invertebrates. in the present study, the cumulative mortality of scallops received two successive Listonella anguillarum stimulations was recorded, and variations of immune parameters including phagocytosis (phagocytic rate and phagocytic index), phenoloxidase-like enzyme, acid phosphatase and superoxide dismutase activities were also examined. The scallops received a previous short-term L anguillarum stimulation were protected against a long-term stimulation of L. anguillarum. Significantly higher level of phagocytic activities and acid phosphatase activity were observed in the scallops received twice stimulations compared with those only received the secondary stimulation. These results indicated that a short-term immersion with L. anguillarum modulated the scallops' immune system and endowed the scallops with enhanced resistance to the secondary bacterial stimulation: phagocytosis and acid phosphatase were suspected to be involved in the protection. (C) 2008 Elsevier Inc. All rights reserved.

Impact of Brunswick river mouth training walls on adjacent beaches, Brunswick heads, New South Wales, Australia

River training walls have been built at scores of locations along the NSW coast and their impacts on shoreline change are still not fully understood. In this study, the Brunswick River entrance and adjacent beaches are selected for examination of the impact of the construction of major training walls. Thirteen sets of aerial photographs taken between 1947 and 1994 are used in a CIS approach to accurately determine tire shoreline Position, beach contours and sand volumes, and their changes in both time and space, and then to assess the contribution of both tire structures and natural hydrodynamic conditions to large scale (years-decades and kilometres) beach changes. The impact of the training walls can be divided into four stages: natural conditions prior to their construction (pre 1959), major downdrift erosion and updrift accretion during and. following the construction of the walls in 1959 similar to 1962 and 1966. diminishing impact of the walls between 1966 and 1987, and finally no apparent impact between 1987 similar to 1994. The impact extends horizontally about 8 km updrift and 17 km downdrift, and temporally up to 25 years..

黄骅坳陷港西开发区河流相储层构型与剩余油分布模式研究

In the production tail of oilfield, water-cut is very high in thick channel sand oil reservoir, but recovery efficiency is relative low, and recoverable remaining oil reserves is more abundant, so these reserves is potential target of additional development. The remaining oil generally distributed with accumulation in certain areas, controlled by the reservoir architecture that mainly is the lateral accretion shale beddings in the point bar, so the study of reservoir architecture and the remaining oil distribution patterns controlled by architecture are very significant. In this paper, taking the Minghuazhen formation of Gangxi oilfield as a case, using the method of hierarchy analysis, pattern fitting and multidimensional interaction, the architecture of the meandering river reservoir is precisely anatomized, and the remaining oil distribution patterns controlled by the different hierarchy architecture are summarized, which will help to guide the additional development of oil fields. Not only is the study significant to the remaining oil forecasting, but also it is important for the theory development of reservoir geology. With the knowledge of sequence correlation and fluvial correlation model, taking many factors into account, such as combination of well and seismic data, hierarchical controlling, sedimentary facies restraint, performance verification and 3-D closure, an accurate sequence frame of the study area was established. On the basis of high-resolution stratigraphic correlation, single layer and oil sand body are correlated within this frame, and four architecture hierarchies, composite channel, single channels, point bars and lateral accretion sandbody are identified, The result indicates that Minghuazhen Formation of Gangxi oilfield are dominated by meandering river deposition, including two types of channel sandbodies, narrow band and wide band channel sandbody, and each of them has different characteristics of facies variation laterally. Based on the identification of composite channel, according to the spatial combination patterns and identified signs of single channel, combined with channel sandbody distribution and tracer material data, single channel sandbodies are identified. According to empirical formula, point-bar scales of the study area are predicted, and three identification signs are summarized, that is, positive rhythm in depositional sequence, the maximum thick sand and near close to the abandoned channel, and point bars are identified. On the basis of point bar recognition, quantitative architecture models inner point bar are ascertained, taking the lateral accretion sand body and lateral accretion shale beddings in single well as foundation, and quantitative architecture models inner point bar as guidance, and result of tracer material data as controlling, the the lateral accretion sand body and lateral accretion shale beddings are forecasted interwell, so inner architecture of point bar is anatomied. 3-D structural model, 3-D facies model and 3-D petrophysical properties models are set up, spatial distribution characteristics of sedimentary facies and petrophysical properties is reappeared. On the basis of reservoir architecture analysis and performance production data, remaining oil distribution patterns controlled by different hierarchy architecture units, stacked channel, single channel and inner architecture of point bar, are summarized, which will help to guide the additional development of oil fields.

准噶尔盆地西缘车排子地区隐蔽油气藏识别与勘探目标研究

After the half century exploration, previous scholar evaluating thought that there were poor Petro-Geological conditions in Chepaizi area of Zhungar basin. Recently, with the great discovery in the Well Pai2,the study on the subtle reservoir in Chepaizi area are gained great attentions by the scholars all over the world day by day. Chepaizi uplift is a inherited palaeohigh, and its structural traps are undeveloped. The sedimentary faces of Shawan Formation of Neogene have apron type of alluvial fan, alluvial plain, alluvial fan delta, salt lake, shore and shallow lake and so on. The sedimentary faces of Shawan Formation of Well Pai2 is alluvial fan delta and shore and shallow lake, the first part of Shawan Formation(N1s1) is the main target for exploration. Using the seismic forward, property analysis, spectral factorization, logging restrain inversion and so on, The spatial distribution of the sand reservoir and its hydrocarbon, predicted and 20 lithology traps in 5 substratums were carried out. The traps have a total areal of 107.13 Km2, and the geological reserves in it can reach 8703.7×104t. After comprehensive research on the trap,reservoir, cap and the condition of the hydrocarbon accumulation, it is considered that the elements of hydrocarbon in Chepaizi area are various. Because it can’t generate hydrocarbon, the oil and gas conducting and accumulation are the most important factors in this area, and the validity of the lithology traps in monoclinal is another important factor. Research indicates that the master control factor of the subtle reservoir in Chepaizi area is fault and sand. The sand of beach and sandbar provide the space for the hydrocarbon accumulation, the fault provides the migration channel for the hydrocarbon. Most faults have a characteristics of up seal and the down open, which not only can conduct hydrocarbon, but also can prevent hydrocarbon overtopping, therefore the effect trap is results of good match of fault and sand.

末次冰盛期以来中国东部沙地空间分布特征及环境记录

The latest two extreme scenarios of last glacial maximum and Holocene climatic optimum marked extreme situations in China. This paper aims to reconstruct the fossil extensions and paleoclimate of deserts in eastern China during this typical period. Aeolian sequence responds the climate change by virtue of alternation of aeolian sand layer and sandy soil layer, which correspond aridity and humidity, respectively. There is a set of contrastive deposits made up of loose sand layer and overlying dark sandy soil below land surface. This developed soil and underlying deep aeolian sand respond to H.O. and late last glacial, i.e. LGM. The typical bottom sand layers of about 50 profiles of Hulun Buir Desert, Horqin Desert and Otindag Desert were dated using OSL to confirm that they did deposid in LGM. Based on the locations of these LGM sand, distrution of gobi-desert-loess and landform control, the distribution in LGM of the three deserts were reconstructed. For the block of eastern mountain, the extreme eastern boundary of Hulun Buir Desert and Otindag Desert are not just functioned by climate background. The east of Horqin Desert is plain, hence eastern boundary of this desert is maily controlled by climate. It is considered that quite a lot of aeolian sand of LGM origined from fluvial deposit by observing regional distribution of river and SEM of sand grains. The environment alternation of of LGM-H.O. is featured by extensive expanse of active dune in LGM and grassland in H.O. Combined grain-size, susceptibility, TOC, colour and SEM measurement, the OSL chronology of relatively continued profiles since LGM of the three deserts are divided into four periods: eolian sand (15-10ka)- sandy soil (10-5ka)- alternation of black sand and yellow sand- reworking of LGM sand as destroy of soil.

西天山造山带古生代构造演化与地壳增生—来自花岗岩和蛇绿岩的证据

The Central Asian Orogen Belt (CAOB), which is different from the subductional orogen and the collisional orogen, is known as the most important site of crustal growth in the Phanerozoic, and it has been a ‘hot spot’ for studying the orogenic belts. The Chinese West Tianshan Orogen is occupying the west-southern part of the CAOB and is of great importances to understand the orogenic processes and the continental growth in the Central Asia. The West Tianshan Orogen had undergone complex tectonic evolutional processes in Paleozoic times and large volumes granitic rocks have recorded important information about these processes. Litter is known about Phanerozoic continental growth in the Western Tianshan area so far, compared with the other areas of the CAOB, such as eastern Junggar, western Junggar, Altai and Alakol. The aim of this dissertation is to set up the chronology frame of granitoids in western Tianshan, provide new evidence for the tectonic evolution and discuss the Paleozoic continental growth in this area, on the basis of the studies on the isotopic chronology, major element, trace element and Nd-Sr isotopic geochemistry of granitoids and the isotopic chronology and geochemistry of the ophiolites in this area, especially the Kule Lake ophiolites. 25 precise SHRIMP U-Pb zircon and LA-ICPMS U-Pb zircon ages have been obtained in this dissertation. The granitic rocks in western Tianshan had been formed during two periods: the granitic gneiss with an age of 896Ma, possibly representing the forming age of the Precambrian basement; the granitic rocks with ages varying from 479Ma to 247Ma, recording the Paleozoic orogenic process of western Tianshan. The granitoids in western Tianshan are composed of intermediate-basic rocks, intermediate rocks, intermediate-acid rocks and acid rocks, mainly intermediate-acid rocks and acid rocks. They are mostly granite, granodiorite, quartz syenite and monzodiorite. Different types of granitic rocks are exposed in different tectonic units. The granitoids on the northern margin of the Yili Plate mainly formed in late Paleozoic (413Ma ~ 281Ma), those with ages varying from 413Ma to 297Ma show continental arc affinities and the magnesian calc-alkalic metaluminous diorite of 281Ma display the geochemical characteristics similar to those of granites formed during the post-orogenic period. The granitiods on the southern margin of the Yili Plate include the adakite diorite of 470Ma which was formd by partial melting of thickened lower crust, the post-collisional alkali-feldspar granite of 430Ma, the volcanic arc granite of 348Ma and the Triassic post-collisional granite. The granitoids in the Central Tianshan Plate formed in 479Ma ~ 247Ma, mainly in 433Ma ~ 321Ma. The granitic rocks with ages of 479Ma ~ 321Ma are magnesian calc-alkalic to alkalic rocks with continental arc affinities. A few post-collisional granitoids of 276Ma ~ 247Ma may have inherited the geochemical characteristics of pre-existing arc magma. The granitic rocks in Southern Tianshan (northern margin of the Tarim plate) formed two stages, 420Ma ~ 411Ma and ca. 285Ma. The magnesian calcic to alkalic granites of 420Ma ~ 411Ma may formed during the extension process of the continental margin. The granite of 285Ma includes mostly ferroan calc-alkalic to alkali-calcic rocks with high SiO2 and high alkaline contents, and obviously negative anomaly of Eu, Ba, Sr, P, Ti, similar to the geochemical characteristics of the A-type granite which is formed during post-collisional extension. The Kule Lake ophiolite in southern Tianshan shows the affinity of N-MORB. A SHRIMP zircon U-Pb age of 425±8Ma has obtained for gabbros. Some zircons have given another group of 206Pb/238U age 918Ma, which may indicate the information of the pre-exist old basement rock. The small oceanic basin represented by Kule Lake ophiolite probably developed on the split northern margin of Tarim block. A model for Paleozoic tectonic evolution of the West Tianshan Orogen has been proposed here on the basis of the new results obtained in this dissertation and the previous published data. In Early Cambrian, the Terskey Ocean occurred along the North Nalati fault (NNF), and it separated the Yili plate from the Central Tianshan plate which was probably connected with the Tarim plate. The Terskey Ocean probably subducted towards south under the Central Tianshan plate and towards north under the Yili plate simultaneously. In the early stage of Late Ordovician, the Terskey Ocean had been closed, and the Yili and Central Tianshan plates collided. Meanwhile, extension happened within the joint Central Tianshan and Tarim plates gradually and the Paleo-South Tianshan Ocean had been formed. In Early Silurian, the Paleo-South Tianshan Ocean began to subduct beneath the composite Yili-Central Tianshan plate, which was intruded by volcanic arc granitoids. In Middle Silurian, the Paleo-South Tianshan Ocean, which had reached a certain width, was subducting strongly. And this subduction may have produced voluminous granitoids in the Central Tianshan plate. In the latest stage of Carboniferous, the Paleo-South Tianshan ocean closed, and the Yili-Central Tianshan plate and Tarim plate collided. In Late Cambrian, Paleo-Junggar Ocean occurred to north of the Yili plate; and started to subduct towards south under the Yili plate in Ordovician. This subduction may have produced a magma arc on the northern margin of the Yili plate. In Late Carboniferous, the Paleo-Junggar Ocean had been closed. The Yili-Central and Junggar plates amalgamated together. The West Tianhan Orogen may undergo a post-collisional collapse since Permian. And the magmatic activities may continue to early Triassic. The initial 87Sr/86Sr ration of the granitic rocks in the western Tianshan Mountains varies from 0.703226 to 0.716343, and Nd（t）from -6.50 to 2.03. The characteristics of Sr-Nd isotope indicate that the source of granitic material is not a sole source, which may be produced by mantle-crust magma mixing. In Paleozoic time, lateral growth of the continental crust along active continental margins was dominant, whereas the vertical growth of continental crust resulted from post- collisional mantle derived magmas was not obvious.

高分辨率非线性岩性物性联合反演方法和应用

In the prediction of complex reservoir with high heterogeneities in lithologic and petrophysical properties, because of inexact data (e.g., information-overlapping, information-incomplete, and noise-contaminated) and ambiguous physical relationship, inversion results suffer from non-uniqueness, instability and uncertainty. Thus, the reservoir prediction technologies based on the linear assumptions are unsuited for these complex areas. Based on the limitations of conventional technologies, the thesis conducts a series of researches on various kernel problems such as inversions from band-limited seismic data, inversion resolution, inversion stability, and ambiguous physical relationship. The thesis combines deterministic, statistical and nonlinear theories of geophysics, and integrates geological information, rock physics, well data and seismic data to predict lithologic and petrophysical parameters. The joint inversion technology is suited for the areas with complex depositional environment and complex rock-physical relationship. Combining nonlinear multistage Robinson seismic convolution model with unconventional Caianiello neural network, the thesis implements the unification of the deterministic and statistical inversion. Through Robinson seismic convolution model and nonlinear self-affine transform, the deterministic inversion is implemented by establishing a deterministic relationship between seismic impedance and seismic responses. So, this can ensure inversion reliability. Furthermore, through multistage seismic wavelet (MSW)/seismic inverse wavelet (MSIW) and Caianiello neural network, the statistical inversion is implemented by establishing a statistical relationship between seismic impedance and seismic responses. Thus, this can ensure the anti-noise ability. In this thesis, direct and indirect inversion modes are alternately used to estimate and revise the impedance value. Direct inversion result is used as the initial value of indirect inversion and finally high-resolution impedance profile is achieved by indirect inversion. This largely enhances inversion precision. In the thesis, a nonlinear rock physics convolution model is adopted to establish a relationship between impedance and porosity/clay-content. Through multistage decomposition and bidirectional edge wavelet detection, it can depict more complex rock physical relationship. Moreover, it uses the Caianiello neural network to implement the combination of deterministic inversion, statistical inversion and nonlinear theory. Last, by combined applications of direct inversion based on vertical edge detection wavelet and indirect inversion based on lateral edge detection wavelet, it implements the integrative application of geological information, well data and seismic impedance for estimation of high-resolution petrophysical parameters (porosity/clay-content). These inversion results can be used to reservoir prediction and characterization. Multi-well constrains and separate-frequency inversion modes are adopted in the thesis. The analyses of these sections of lithologic and petrophysical properties show that the low-frequency sections reflect the macro structure of the strata, while the middle/high-frequency sections reflect the detailed structure of the strata. Therefore, the high-resolution sections can be used to recognize the boundary of sand body and to predict the hydrocarbon zones.

陕北何家集区延长组长4＋5－长6储层特征研究

Abstract： Hejiaji area lies on eastern part of Shanbei Slope in Ordos Basin and the primary oil-bearing bed is Chang 4＋5 and Chang 6 of Yanchang Formation. It is indicated that the sedimentary facies and reservoir characteristics restricted the hydrocarbon accumulation regularity by the geological information. Therefore, Applied with outcrop observation，core description, geophysical logging interpretation, thin section determination, Scanning Electron Microscope, reservoir lithology and physical property analysis and other analytic machinery, the sedimentary facies ,micro-characteristic and master control factors on hydrocarbon reservoir of Yanchang Formation in Hejiaji area are studied deeply by means of sedimentology，reservoir geology and petroleum geology and provide a reliably reference for later prospect . Delta facies are identified in Hejiaji area and of which distributary channels in delta plain microfacies controlled the distribution of sand bodies and accumulation of oil and gas.The distribution of sand bodies distributed from northeast to southwest are dominated by sedimentary facies . It was shown that the sandstones are medium to granule arkose，which the mud matrix is r and including，calcite，the content of matrix is lower and that mostly are cements which are mainly quartz and feldspar overgrowths and chlorite films, in the second place are hydromica and ferrocalcite. All the sandstones have entered a period of late diagenetic stage in which the dominant diagenesis types in the area are compaction, cementation and dissolution. Remnant intergranular porosity and feldspar dissolved pore are main pore types which are megalospore and medium pore. Medium-fine throat, fine throat and micro-fine throat are the mainly throat type. Pore texture can be classified as megalospore and fine throat type, medium-pore and micro-fine throat type mainly, and they are main accumulate interspace in research region. The reservoir of Yanchang Formation in Hejiaji area is low- pore and low- permeability in the mass which have strong heterogeneity in bed, interbedded and plane. Studying the parameter of pore and permeability comprehensively and consulting prevenient study results of evaluation of reservoir, the reservoir is classifiedⅡ，Ⅲ and Ⅳ three types in which the Ⅱand Ⅲ can be divided into Ⅱa and Ⅱb, Ⅲa and Ⅲb respectively. Ⅱb and Ⅲa are the main reservoir type in Hejiaji area which are about 72.73％and 80％percent of whole reservoir and effective reservoir respectively.

陕北桥镇油田延长组长2、长1油层组沉积相及储层研究

The Ordos Basin is a large-scale craton superimposed basin locating on the west of the North China platform, which was the hotspot of interior basin exploration and development. Qiaozhen oil field located in the Ganquan region of south-central of Ordos Basin. The paper is based on the existing research data, combined with the new theory and progress of the sedimentology, sequence stratigraphy, reservoir sedimentology, petroleum geology, etc, and analyzes systematically the sedimentary and reservoir characteristics in the chang2 and chang1 oil-bearing strata group of Yanchang formation On the basis of stratigraphic classification and comparison study, the strata chang2 and chang1 were divided into five intervals. Appling the method of cartography with single factor and dominance aspect, we have drawn contour line map of sand thickness, contour line map of ratio between sand thickness and stratum thickness. We discussed distribution characteristics of reservoir sand body and evolution of sedimentary facies and microfacies. And combining the field type section , lithologic characteristics, sedimentary structures, the sedimentary facies of single oil well and particle size analysis and according to the features of different sequence, the study area was divided into one sedimentary facies、three parfacies and ten microfacies. The author chew over the characteristics of every facies, parfacies and microfacies and spatial and temporal distribution. Comprehensive research on petrologic characteristics of reservoir , diagenesis types, pore types, distribution of sand bodies, physical properties, oiliness, reservoir heterogeneities, characteristics of interlayer, eventually research on synthetic classifying evaluation of reservoir.The reservoir is classified four types: Ⅰ、Ⅱ、Ⅲ、Ⅳ and pore type, fracture-porosity type. Take reservoir's average thickness, porosity, permeability, oil saturation and shale content as parameters, by using clustering analysis and discriminant analysis, the reservoir is classified three groups. Based on the evaluation, synthetizing the reservoir quality, the sealing ability of cap rock, trap types, reservoir-forming model ,in order to analyze the disciplinarian of accumulation oil&gas. Ultimately, many favorable zones were examined for chang23，chang223，chang222，chang221，chang212，chang12，chang11 intervals. There are twenty two favorable zones in the research area. Meanwhile deploy the next disposition scheme.

浑善达克沙地全新世气候变化与风沙活动—夏日淖湖泊沉积记录

Atmospheric dust as an important factor for climate feedbacks is mainly derived from and drove by the aeolian activities of the semi-arid regions in Asia. Therefore, reconstructing the history of aeolian activities in this region has a great significance in understanding the dynamics of past and future climate changes. This paper made a systematical sedimentology, geochemisty and high-resolution chronology analysis on the sediments from the Xiarinao Lake, which located in Hunshandake Desert, Inner Mongolia, and compared with the meteorological records for identifying the indicator of aeolian activities and climate changes. Based on above work, the evolution history of the aeolian activities and climate changes since 11,000 a BP was reconstructed and the dynamics of the aeolian activities and climate changes in the Hunshandake Desert was discussed. The indicator of aeolian activities was established through the comparison of the clastic and chemical records with the meteorological registers in recent 50 years: 1. The sediments of Xiarinao Lake are mainly derived from eaolian clastic materials and composed of two major components: one is the sand fraction (<4 ) similar to the composition of sand dunes, the other is the silt fraction (>4 ) similar to the atmospheric dust. The sand content and the median grain size, particularly the sand content, show a close association with the intensity of wind, indicating that the particle-size composition of the sediments reflect the variations of the aeolian activities. 2. The proportion of soluble salts relative to the total carbonates in the sediments was correlated to the arid degree registered in meteorological records, suggesting that arid degree might be associated with changes of wind speed and the relative proportion of soluble salts to the total carbonate could be used as the indicator of aridity. 3. The δ18O of authigenic calcite in the Xiarinao Lake show a well correlation with both the atmosphere precipitation and variation of the moisture indicated by the concentrations of soluble salts, suggesting that δ18O of anthigenic calcite is a reliable indicator of humidity. Based on above studies, the evolution history of the aeolian activities and climate changes since 11,000 a BP was reconstructed. At the same time, their association and underlying dynamics was discussed: 1. The evolution history of the eaolian activity was reconstructed by the sand content and median grain size. The result showed that aeolian activities had experienced several different climate periods in the Holocene: the aeolian activities fluctuated with a 500-year cycles during the interval from 10,900 to 8200 a BP; no significant aeolian activities had been developed from 8200 to 6300 a BP; during the interval of 6300 to 2600 a BP, sand content and media grain size had increased gradually, the sand content increased from about 5% to 25%, indicating the intensity of aeolian activity increased in the Hunshandake Desert; since 2600 a BP, intensity of aeolian activity has become stronger and activated the sand dunes. 2. The relative arid degree indicated by the proportion of soluble salts relative to the total carbonate show that both the wind speed and dry degree had being increased since 11,000 a BP. During the interval of 10900 to 6300 a BP, no detectable soluble salt was found in the sediments, indicating the humidity condition; the proportion increased to 20% from 6300 to 4200 a BP, showing the climate became drier; the little change of proportion (20%) suggest that the climate was relative stable during the interval of 4200 to 2600 a BP; after 2600 a BP, the proportion increased, showing the climate became further dry. 3. The δ18O evolution of the lake water was established through analysis of authigenetic calcite δ18O for revealing the variations of relative effective humidity in the Hunshandake Desert. δ18O maintained around -6 ‰ during the interval of 10900 to 8200 a BP, showing the climate was a little dry relative to that of the whole Holocnene; in the period of 8200 to 6300 a BP, δ18O had the most negative values, indicating that it was the most humid interval in Holocene; from 6300 to 4200 a BP, δ18O increased from about -7.5 ‰ to about -3 ‰ gradually, suggesting increased aridity; since 4200 a BP, the climate has become stable and dry. On the whole, the records in this study show that the variation of the relative humidity and aridity is consistent with that of summer monsoon in the Hunshandake Desert. The relationships among the grain size, soluble salts relative content, and the authigenic calcite δ18O indicate aeolian activities is controlled by the aridity in the studied area, and the increased aeolian activities is closely associated with the temperature changes under the relative dry condition. The high wind speed under the low temperature leads to the increased aeolian activity, and the temperature change associated with the aeolian activities might be related with the perturbations of the Siberian High Pressure.

河流成因储层沉积微相与剩余油分布及形成机理研究

Based on the study of fluvial sandstone reservoir in upper of Guantao group in Gudao and Gudong oilfields, this paper first introduces A.D.Miall's(1996a) architectural-element analysis method that was summarized from ground outcrop scale into the reservoir formation research of the study area, more subtly divides sedimentary microfacies and establishes sedimentary model of research area.on this base, this paper summarizes the laws of residual oil distribution of fluvial formation and the control effect of sedimentary microfacies to residual oil distribution, and reveals residual oil formation mechanism. These results have been applied to residual oil production, and the economic effect is good. This paper will be useful for residual oil research and production and enhancement of oil recovery in similar reservoir. The major conclusions of this paper are as follows. 1. Using the architectural-element analysis method to the core data, a interfacial division scheme of the first to the dixth scale is established for the studied fluvial formation. 2.Seven architectural-elements are divided in upper of Guantao group of study area. The sandstone group 5～1+2 of Neogene upper Gutao group belongs to high sinuous fine grain meandering river, and the sandstone group 6 is sandy braided river. 3. Inter layer, the residual oil saturation of "non-main layer" is higher than "main layer", but the residual recoverable reserve of former is larger. Therefore, "main layer" is the main body of residual oil distribution. The upper and middle part of inner layer has lower permeability and strong seeping resistance. Addition to gravity effect in process of driving, its driving efficiency is low; residual oil saturation is high. Because of controlling of inside non-permeable interlayer or sedimentary construction, the residual oil saturation of non-driving or lower driving efficiency position also is high. On plane, the position of high residual oil saturation mostly is at element LV, CS, CH (FF), FF etc, Which has lower porosity and permeability, as well as lens sand-body and sand-body edge that is not controlled by well-net, non-perfect area of injection and production, lower press difference resort area of inter-well diffiuent-line and shelter from fault, local high position of small structure. 4.Microscopic residual oil mainly includes the non-moved oil in the structure of fine pore network, oil in fine pore and path, oil segment in pore and path vertical to flow direction, oil spot or oil film in big pore, residual oil in non-connective pore. 5.The most essential and internal controlling factor of fluvial formation residual oil distribution is sedimentary microfacies. Status of injection and production is the exterior controlling factor of residual oil distribution. 6. The controlling effect of formation sedimentary microfacies to residual oil distribution indicates inter-layer vertical sedimentary facies change in scale of injection and production layer-series, planar sedimentary face change and inner-layer vertical sedimentary rhythm and interbed in single layer to residual oil distribution. 7. It is difficult to clear up the inter-layer difference in scale of injection and production layer-series. The using status of minor layer is not good and its residual oil saturation is high relatively. It is obvious that inter-layer vertical sedimentary facies changes control inter-layer residual oil distribution at the same or similar conditions of injection and production. For fluvial formation, this vertical sedimentary facies change mainly is positive gyration. Namely, from down to top, channel sediment (element CHL, LA) changes into over-bank sediment (element LV, CR, CS). 8. In water-injection developing process of transverse connecting fluvial sandstone oil formation, injection water always comes into channel nearby, and breaks through along channel and orientation of high pressure gradient, does not expand into side of channel until pressure gradient of channel orientation changes into low. It brings about that water-driving status of over-bank sedimentary element formation (LV, CR, CS) is not good, residual oil saturation is high. In non-connective abandoned channel element (CH) formation with channel, because this reverse is difficult to control by injection and production well-series, its using status is not good, even terribly not good, residual oil is enrichment. 9. The rhythm and sedimentary structure, sedimentary facies change in single sand body brings about vertical changes of formation character, growth character of inner layer interbed. These are important factor of controlling and affecting vertical water spread volume and inner layer residual oil forming and distribution in single sand body. Positive rhythm, is the principal part of fluvial sandstone inner layer sedimentary rhythm. Namely, from down to upside, rock grain granularity changes from coarse to fine, seeping ability changes from strong to feebleness. It brings about that water-driving status of inner layer upside is not good, residual oil saturation is high. Inner layer interbed has different degree affecting and controlling effect to seeping of oil and water. Its affecting degree lies on interbed thickness, extending scale, position, and jeted segment of production or injection well. The effect of interbed at upside of oil formation to oil and water seeping is less; the effect of interbed at middle of oil formation to oil and water seeping is more. 10. Indoor experiment and research indicate that wettability, permeability step, vertical permeability, position of Kmax and ratio of oil viscousity and water viscousity all have great effect on the water-driving recovery ratio. 11. Microscopic residual oil distribution is affected and controlled by formation pore network structure, pressure field distribution, and oil characteristic. 12.The residual oil forming mechanism: the over-bank sedimentary element and upper part of a positive rhythm sandstone have fine pore and throat network, permeability is low, displacement pressure of pore and throat is high. The water-driving power usually falls short of displacement pressure that brings about injection water does not spread into these pore and throat network, thereby immovable oil area, namely residual oil, is formed. At underside of channel sedimentary element and positive rhythm sandstone, porosity and permeability is relatively high, connecting degree of pore and throat is high, displacement pressure of pore and throat is low. Thereby injection water is easy to enter into pore and throat, driving oil in them. Because the pore space is irregular, the surface of pore wall is coarse and non-flat. That the oil locate on concave hole of pore wall and the dead angle of pore, and the oil attaches on surface of pore wall by surface tension, are difficult to be peeled off, becoming water-driving residual oil (remaining oil). On the other hand, Because flowing section lessens, flowing resistance increase, action of capillary fore, or seeping speed decreases at process of transfer at pass narrow throat path in the course carried by driving water. The "oil drop", "oil bead", or "oil segment" peeled off by driving water is difficult to carry and to drive out by water at less pressure difference. Thereby they are enclosed in pore to form discontinuous residual oil. 13.This results described above have been applied in nine develop blocks of Gudao and Gudong oilfield. Its applying effect is marked through local injection production adjustment, deploying replacement well, repair hole, replacement envelop, block off water and profile control etc. Relative method and technology can be applied to other oil production area of Shengli oilfield, and obtain better economic and societal effect.

西江流域环境河水地球化学研究

River is a major component of the global surface water and CO2 cycles. The chemistry of river waters reveals the nature of weathering on a basin-wide scale and helps us understand the exogenic cycles of elements in the continent-river-ocean system. In particular, geochemical investigation of large river gives important information on the biogeochemical cycles of the elements, chemical weathering rates, physical erosion rates and CO2 consumption during the weathering of the rocks within the drainage basin. Its importance has led to a number of detailed geochemical studies on some of the world's large and medium-size river systems. Flowing in the south of China, the Xijiang River is the second largest river in the China with respect to its discharge, after the Yangtze River. Its headwaters drain the YunGui Plateau, where altitude is approximately 2000 meters. Geologically, the carbonate rocks are widely spread in the river drainage basin, which covers an area of about 0.17xl06 km2, i.e., 39% of the whole drainage basin. This study focuses on the chemistry of the Xijiang river system and constitutes the first geochemical investigation into major and trace elements concentrations for both suspended and dissolved loads of this river and its main tributaries, and Sr isotopic composition of the dissolved load is also investigated, in order to determine both chemical weathering and mechanical erosion rates. As compared with the other large rivers of the world, the Xijiang River is characterized by higher major element concentration. The dissolved major cations average 1.17, 0.33, 0.15, and 0.04 mmol I"1 for Ca, Mg, Na, and K, respectively. The total cation concentrations (TZ+) in these rivers vary between 2.2 and 4.4 meq I'1. The high concentration of Ca and Mg, high (Ca+Mg)/(Na+K) ratio (7.9), enormous alkalinity and low dissolved SiO2/HCO3 ratio (0.05) in river waters reveal the importance of carbonate weathering and relatively weak silicate weathering over the river drainage basin. The major elements in river water, such as the alkalis and alkaline-earths, are of different origins: from rain water, silicate weathering, carbonate and evaporite weathering. A mixing model based on mass budget equation is used in this study, which allows the proportions of each element derived from the different source to be calculated. The carbonate weathering is the main source of these elements in the Xijiang drainage basin. The contribution of rainwater, especially for Na, reaches to approximately 50% in some tributaries. Dissolved elemental concentration of the river waters are corrected for rain inputs (mainly oceanic salts), the elemental concentrations derived from the different rock weathering are calculated. As a consequence, silicate, carbonate and total rock weathering rates, together with the consumption rates of atmospheric CO2 by weathering of each of these lithologies have been estimated. They provide specific chemical erosion rates varying between 5.1~17.8 t/km2/yr for silicate, 95.5~157.2 t/km2/yr for carbonate, and 100.6-169.1 t/km2/yr for total rock, respectively. CO2 consumptions by silicate and carbonate weathering approach 13><109and 270.5x10 mol/yr. Mechanical denudation rates deduced from the multi-year average of suspended load concentrations range from 92-874 t/km2/yr. The high denudation rates are mainly attributable to high relief and heavy rainfall, and acid rain is very frequent in the drainage basin, may exceed 50% and the pH value of rainwater may be <4.0, result from SO2 pollution in the atmosphere, results in the dissolution of carbonates and aluminosilicates and hence accelerates the chemical erosion rate. The compositions of minerals and elements of suspended particulate matter are also investigated. The most soluble elements (e.g. Ca, Na, Sr, Mg) are strongly depleted in the suspended phase with respect to upper continent crust, which reflects the high intensity of rock weathering in the drainage basin. Some elements (e.g. Pb, Cu, Co, Cr) show positive anomalies, Pb/Th ratios in suspended matter approach 7 times (Liu Jiang) to 10 times (Nanpan Jiang) the crustal value. The enrichment of these elements in suspended matter reflects the intensity both of anthropogenic pollution and adsorption processes onto particles. The contents of the soluble fraction of rare earth elements (REE) in the river are low, and REE mainly reside in particulate phase. In dissolved phase, the PAAS-normalized distribution patterns show significant HREE enrichment with (La/Yb) SN=0.26~0.94 and Ce depletion with (Ce/Ce*) SN=0.31-0.98, and the most pronounced negative Ce anomalies occur in rivers of high pH. In the suspended phase, the rivers have LREE-enriched patterns relative to PAAS, with (La/Yb) SN=1 -00-1 .40. The results suggest that pH is a major factor controlling both the absolute abundances of REE in solution and the fractionation of REE of dissolved phase. Ce depletion in river waters with high pH values results probably from both preferential removal of Ce onto Fe-Mn oxide coating of particles and CeC^ sedimentation. This process is known to occur in the marine environment and may also occur in high pH rivers. Positive correlations are also observed between La/Yb ratio and DOC, HCO3", PO4", suggesting that colloids and (or) adsorption processes play an important role in the control of these elements.

浑善达克沙地的光释光测年研究

Eolian deposits are important for paleoclimatic and paleoenvironmental reconstructions in arid and semi-arid regions. In China active sand dunes mainly occur in the northwest inland basins ,whereas deserts dominated by semi-stabilized sand dunes are mainly distributed in the northeastern semi-arid and sub-humid regions. Recent studies indicate that prompt desertification in northeastern China has been serious.Thus northeastern China is one of the key sites on which to study the history of past environmental changes. However, previous studies focused mainly on big scale environmental changes, whereas changes in the environment during the Holocene have not been well studied. This research uses optically stimulated luminescence to date fossil sand dunes in Hunshandake desert in order to offer the accurate time scale to reconstruct the history of eolian activity in the region. Furthermore,we compare this region with other deserts in northern China.The main conclusions is following: Active dune formation in northeastern China lasted from the Last Glacial Maximum to about 10 000aB.P. It has also been shown that the warm climate of the Holocene was interrupted by a cold/dry dune-forming episode at about 2 800-1 800aB.R. The Holocene Optimum occurred between 10 000-2 800aB.R, and a later warm/humid dune stabilization phase lasted from at least 1 900-1 500aB.R. The youngest age on the uppermost soil unit in Hunshandake desert yielded an age of 90aB.P.,on which the younger sand deposits,and the youngest age on the sand in Hulun Buir desert is 40aB.R. The mean annual precipitation of these regions is up to 450 mm. But these deserts locate in middle latitudes regions, where the climate is sub-humid, semi-arid continental monsoon.Under present climatic conditions, there should be no active sand dunes in northeastern China. So the appearance of active sand in northeastern China is not due to natural factors,but to extensive land reclamation and cultivation.

Titanium species in titanium silicalite TS-1 prepared by hydrothermal method

The titanium species existing in titanium silicalite TS-1, which is prepared by hydrothermal method, were investigated using chemical analysis, XRD, FT-IR, Si-29 MAS NMR, UV-VIS, ESR. It has been observed that several kinds of titanium species may exist in titanium silicalite. The form that titanium atoms incorporate into the framework of titanium silicalite synthesized using tetrapropylammonium bromide (TPABr) as template differs from that using the classical method. But, the symmetry of titanium silicalite, changes from monoclinic to orthorhombic with the increase of titanium content in both methods. The Ti-O-2(-) originated from framework titanium and H2O2 has the moderate stability and may be active site in oxidation reaction. TS-1 synthesized using TPABr as template does not contain anatase, but contains a kind of partly condensed titanium species with six-fold coordination. The titanium species may correspond to 270-280 mn band in UV-VIS spectra and also can form Ti-O-2(-). But, this kind of Ti-O-2(-) is very stable and cannot be catalytic active site. So, the six-fold coordination titanium species may be inactive in both the oxidation reaction and the decomposition of H2O2. The hypothesis has been further proved by the phenomena that the titanium species is easily washed off using acid, and acid treating will not influence the catalytic performance of TS-1. (C) 2001 Elsevier Science B.V. All rights reserved.