A SIMPLE METHOD FOR PREDICTION OF GAS-PERMEABILITY OF POLYMERS FROM THEIR MOLECULAR-STRUCTURE

A method for the prediction of gas permeabilities (P) through polymers from their chemical structure has been developed on the basis of the ratio of molar free volume to molar cohesive energy, V(f)/E(coh). The permeation of small gas molecules through polymer membranes is dependent on the chain packing density measured by V(f) and segmental motion of polymer chains measured by E(coh). But no simple relationship between P and V(f) or E(coh) alone was found. The permeability data of more than 60 polymers covering 7 orders of magnitude for six gases have been treated with linear regression analysis. All plots of log P vs. V(f)/E(coh) gave good straight lines. It is also found that a linear relationship holds when plotting both the intercepts and slopes of log P vs. V(f)/E(coh) lines against square of the diameters of gas molecules. Therefore, the permeabilities of all the non-swelling gases through a great variety of polymers can be estimated using two correlations above. Moreover, this method is more accurate than others in the literature and may found useful for the selection of gas separation or barrier membrane materials.

SATELLITE REMOTE-SENSING PREDICTION OF JAPANESE PILCHARD FISHING GROUND IN THE HUANGHAI SEA AND THE EAST-CHINA-SEA

The thermophily, fishing season and central fishing ground of Japanese pilchard (Sardinops melanosticta) were studied by using satellite remote sensing (SRS) and other methods in Haizhou Bay and Tsushima waters during 1986-1990. A rapid prediction method of fishing ground is presented. Moreover, the results indicated that the thermophilic values of the fish stock are 11-20 degrees C and both fishing grounds are in increasing temperature process from the beginning to the end of the fishing period. The Japanese pilchards gather vigorously at the sea surface temperature of 15-17 degrees C. The water temperature is a key factor affecting the fishing season and the catch of the fishing ground. The increasing temperature process restricts the fishing season development and central fishing ground formation. The accuracy of 15 predictions made in the Haizhou Bay fishing ground is up to 91.3%, and 37 predictions made in the Tsushima, fishing ground shorten the fish detection time by 13.4% - 22% on the average.

A hybrid coupled ocean-atmosphere model and ENSO prediction study

A hybrid coupled ocean-atmosphere model is designed, which consists of a global AGCM and a simple anomaly ocean model in the tropical Pacific. Retroactive experimental predictions initiated in each season from 1979 to 1994 are performed. Analyses indicate that: (1) The overall predictive capability of this model for SSTA over the central-eastern tropical Pacific can reach one year, and the error is not larger than 0.8 degrees C. (2) The prediction skill depends greatly on the season when forecasts start. However, the phenomenon of SPB (spring prediction barrier) is not found in the model. (3) The ensemble forecast method can effectively improve prediction results. A new initialization scheme is discussed.

An approach to prediction of the South China Sea summer monsoon onset

In the present paper, correlation between the South China Sea summer monsoon (SCSSM) onset and heat content in the upper layer of the warm pool in the western Pacific Ocean is examined using the Scripps Institution of Oceanography dataset for the period of 1955-1998 and an approach to prediction the SCSSM onset is proposed. Correlation showes that there exists interdecadal variability of the SCSSM onset demarcated by 1970 with the largest correlation coefficient in the area west of the center of the warm pool rather than near its centers, implying certain effect from other factors involved besides ENSO. As the correlation is poor for the period before 1970, the heat content anomaly of the warm pool after 1970 is used to indicate early or late onset of the SCSSM beforehand. An ideal representative area (1A degrees x1A degrees) for the warm pool heat content was determined with its center at 3A degrees N/138A degrees E. The nearest TAO (TAO-Tropical Atmosphere Ocean-array) mooring to the center is at 2A degrees N/137A degrees E, and chosen to calculate the heat content for prediction. It is suggested that the TAO mooring at 2A degrees N/137A degrees E could be used to predict the SCSSM onset with the heat content in the upper layer, if the correlation between the SCSSM onset and the heat content of the warm pool runs like that of after 1970. On the other hand, if the situation does like the one before 1970, the representative station is determined at 13A degrees S/74A degrees E with relatively poor correlation, meaning that the warm pool in the western Pacific Ocean plays more important role in the SCSSM onset than the Indian Ocean.

Prediction of marine sediment corrosion by fuzzy clustering analysis

Along with the development of marine industries, especially marine petroleum exploitation, more and more pipelines are buried in the marine sediment. It is necessary and useful to know the corrosion environment and corrosiveness of marine sediment. In this paper, field corrosion environmental factors were investigated in Liaodong Bay marine sediment containing sulfate-reducing bacteria (SRB) and corrosion rate of steel in the partly sediment specimens were determined by the transplanting burying method. Based on the data, the fuzzy clustering analysis (FCA) was applied to evaluate and predict the corrosiveness of marine sediment. On that basis, the influence factors of corrosion damage were discussed.

基于IP QoS技术的网络机器人遥操作研究

针对基于 Internet机器人遥操作中存在的问题 ,结合 Internet网络技术的最新发展 ,借助 IP Qo S技术的特点和优势 ,本文研究并设计了基于集成业务体系结构的网络机器人遥操作系统 .通过分析 IP Qo S技术和机器人遥操作技术相互结合的可行性与合理性 ,表明该系统能够克服目前在 Internet遥操作过程中存在的问题并可在未来支持 IP Qo S技术的 Internet中发挥作用 .本文提出了该系统的设计原型及实现方法 .

基于Internet的机器人遥操作系统QoS策略与同步问题研究

基于Internet的机器人遥操作系统提供了进行网络控制系统(NCS和多媒体通信等学科交叉领域研究的良好平台和契机。服务质量(QoS)的概念起源于多媒体和远程通信领域，大量的文献表明，将NCS和QOS结合起来的研究和应用还很少。本文分析、研究了基于Internet的机器人遥操作系统作为NCS, Internet上的多媒体应用和实时系统等多学科的交叉领域所具有的特点，对该系统同步和协调问题及具有QOS意识的网络机器人遥操作系统体系结构进行了深入、广泛的研究和探讨。就现有的基于Internet的机器人遥操作系统存在的缺乏对网络可用带宽的适应、缺乏多数据流协调等问题，提出了一种针对网络机器人遥操作系统的端到端QOS自适应体系结构AeQTA o在Internet QoS整体工程尚未完全启动的情况下，AeQTA的目的是将QOS的方法和策略尽量移植到端系统上，在端系统上提供QOS配置接口，实施QOS驱动的控制和管理策略，实现最大的网络效率、最可能好的应用性能和合理的业务流间资源分配的和谐统一。从时钟同步、速率控制、拥塞控制、多传感器信息同步和端到端的调度等几个方面剖析了基于Internet的机器人遥操作系统的协调和同步问题。针对NC S系统的同步容限的量化问题，提出了NCS多传感器反馈中的同步距离的概念和定义。然后，根据基于公式的、TCP－友好的速率控制的基本思路，结合使用应用需求QOS和网络QOS两种尺度调节的基于主媒体流的表象同步方法，将多传感器信息同步和速率控制统一起来，提出了一种速率控制方法TTFRC，提高了系统的实时性和TCP－友好性。为了给基于Internet的机器人遥操作系统研究提供一个真实的实验环境，为相关的策略和算法提供验证平台，我们建立了一个开放的、灵活的、可移植的、可裁减的且成本低的MOMR原型系统。目前，该原型系统已经为基于Internet的机器人遥操作系统深入的理论研究和实际经验积累做出了很大贡献。并且，在此基础上，由中国科学院沈阳自动化研究所和香港中文大学合作，己于2402年1月通过Internet实现了沈阳—香港—密西根三地的MONM远程协作。力求控制工程和计算机网络工程等多学科的结合是本论文工作的努力方向。

Prediction of soil adsorption coefficients from retention parameters on three reversed-phase liquid chromatographic columns

Reversed-phase high-performance liquid chromatographic (RP-HPLC) retention parameters, which are determined by the intermolecular interactions in retention process, can be considered as the chemical molecular descriptors in linear free energy relationships (LFERs). On the basis of the characterization and comparison of octadecyl-bonded silica gel (ODS), cyano-bonded silica gel (CN), and phenyl-bonded silica gel (Ph) columns with linear solvation energy relationships (LSERs), a new multiple linear regression model using RP-HPLC retention parameters on ODS and CN columns as variables for estimation of soil adsorption coefficients was developed. It was tested on a set of reference substances from various chemical classes. The results showed that the multicolumn method was more promising than a single-column method was for the estimation of soil adsorption coefficients. The accuracy of the suggested model is identical with that of LSERs.