滇西地区上地幔铅同位素组成的确定及其应用

滇西地区基性－超基性岩、碱性岩中的长石、石榴子石、橄榄石等单矿物及羊拉铜矿区二叠世海相玄武岩的铜铅同位素组成可以代表原始地幔的铅同位素组成，由此确定的该区上地幔铅同位素组成变化范围为^206Pb/^204Pb=17.877-18.506,平均18.108,^207Pb/^204Pb=15.470-15.587,平均15.479,^208Pb/^204Pb=37.797-38.567,平均38．177。研究发现，由于受地壳物质的混染和成岩后U、Th衰变产生的放射成因铅的影响，这些幔源岩石全岩铅同位素组成已不能代表原始上地幔的铅同位素组成；金顶铅锌矿床的铅并非上地幔来源，而是相当于下地壳来源的铅与兰坪盆地沉积岩铅二者的混合铅.

铊矿物及铊的植物找矿

迄今为止，世界发现铊的独立矿物49种，我国已发现铊矿物9种，其中铊明矾为贵州省发现的第一个铊的新矿物。铊矿物中铊与砷密切共生，而硫是联系二者的重要桥梁。铊的植物找矿包括植物指示和植物矿石。一些植物中铊含量非常高，可以作为寻找铊矿的有效指示植物。植物找矿作为一种新兴找矿技术，还有许多研究工作有需要去做。

Electrochromatographic evaluation of a silica monolith capillary column for separation of basic pharmaceuticals

A silica-based monolithic capillary column was prepared via a sol-gel process. The continuous skeleton and large through-pore structure were characterized by scanning electron microscopy (SEM). The native silica monolith has been successfully employed in the electrochromatographic separation of beta-blockers and alkaloids extracted from traditional Chinese medicines (TCMs). Column efficiencies greater than 250000 plates/m for capillary electrochromatography (CEC) separation of basic compounds were obtained. It was observed that retention of basic pharmaceuticals on the silica monolith was mainly contributed by a cation-exchange mechanism. Other retention mechanisms including reversed-phase and normal-phase mechanisms and electrophoresis of basic compounds also played a role in separation. A comparison of the differences between CEC and capillary zone electrophoresis (CZE) separation was also discussed.

Recognition interactions of metal-complexing imprinted polymer

Molecularly imprinted polymer, exhibiting considerable enantioselectivity for L-mandelic acid, was prepared using metal coordination-chelation interaction. By evaluating the recognition characteristics in the chromatographic mode, the recognition interactions were proposed: specific and nonspecific metal coordination-chelation interaction and hydrophobic interaction were responsible for substrate binding on metal-complexing imprinted polymer; while the selective recognition only came from specific metal coordination-chelation interaction and specific hydrophobic interaction.