岭南东江流域mis2阶段红色沙质沉积物粒度分布特征分析

IEECAS SKLLQG

重离子碰撞中原子核阻止的同位旋效应

利用含有 3种对称势形式的同位旋相关的量子分子动力学 ,研究了中能重离子碰撞中原子核阻止的同位旋效应和随入射道条件的系统演化过程 .计算结果表明 ,原子核阻止灵敏地依赖束流能量、碰撞参数、碰撞系统的质量和核子 -核子碰撞截面的同位旋相关性 ,而 3种对称势和碰撞系统的中质比对它的影响不很明显 ,但在大约费米能量以下能区 ,原子核阻止同时依赖于介质中核子 -核子碰撞截面和对称势 .故认为在费米能量以上能区直至 1 50MeV/u ,原子核阻止是提取介质中核子 -核子碰撞截面的一个新的物理观测量 .

HIRFL-CSR实验环电子冷却装置参数优化

以 4 0 0 Me V/u的 2 38U91 +为例 ,用电子冷却模拟程序计算了冷却时间随冷却段长度、冷却段磁感应强度、磁场平行度、电子密度、电子束半径、电子温度的变化规律 ,并分析了影响冷却时间的因素 ,获得了电子冷却装置最优参数。

Production cross sections of superheavy nuclei based on dinuclear system model

The barrier distribution function method is introduced in the dinuclear system model in the calculation of the transmission probability, which is the first stage in the synthesis of superheavy nuclei. Dynamical deformation and averaging collision orientations are considered in the calculation of the fusion probability by solving master equation numerically. Survival probability with respect to xn evaporation channel (x = 1-5) in the de-excitation process of the thermal compound nucleus is calculated, in which the level density of the Fermi-gas model is used. Production cross sections of a series of superheavy nuclei formed in the reactions taken magic and deformed nuclei as target in Ca-48 induced reactions are studied systematically. The calculated results are in good agreement with available experimental data. Isotopic dependence of the production cross sections in the reactions Ca-48 + Pu is analyzed.

含油污泥堆腐处理技术研究

含油污泥主要来源于原油的勘探、开采和运输过程,在回收石油过程中由于采用加热后助剂提取方法,使油泥中大量微生物失活,为生物修复处理带来新的困难。针对这种含油污泥,采取投加固体菌剂的方法增加微生物种群,通过投加客土、肥料、水分及改变pH,调控微生物的营养和生存环境。利用正交实验L934方法选择了较理想的含油污泥生物修复条件。实验结果表明,处理含油污泥时投加客土是影响处理效果的重要因素,较理想的处理条件为:在自然温度条件下,客土投加量10%￣20%、肥料5%、菌剂5%(湿重)、水分30%(烘干基)和pH7.0。当TPH初始浓度为20.6￣22.3g·kg-1时,60d后其去除率>49%。在实验过程中,堆料的O2含量的变化能够反映出生物降解过程中微生物的活性及总石油烃(TPH)的处理效果变化趋势。

水文研究中的一种微机制图方法

微机制图具有速度快、精度高等特点 ,成为各个领域研究人员实用的研究手段。在水文研究中 ,利用SURFER软件 ,将实测的水文要素散点值输入计算机 ,通过数据的网格化处理 ,即可生成不同需求的趋势图。可定性、定量、定位地反映水文要素的空间分布和变化特征 ,为水文要素规律的研究提供分析图件。

岷江上游地区土地利用变化及潜在生态服务价值评估(英文)

为了定量分析岷江上游地区生态系统服务功能及其价值变化,运用遥感、地理信息系统和一系列数学方法对其评估,为更好的管理生态系统提供合理化建议。结果表明:土地利用转换主要发生在森林,农田和草地之间。从1986年到1994年,农田面积增加了60801hm2,比1986年增长了477%;林地面积减少了89012.17hm2,占原有面积的4.97%。人口增长和森林砍伐降低了森林生态系统服务价值,相应地农田生态系统服务价值升高。生态系统总的服务价值从1986年到2000年减少了771.11亿元。本文还探讨了生态系统服务价值变化的驱动力,其中国家政策在生态系统服务功能保护上起到了一定的作用。图2表7参33。

沈阳城市森林三维绿量测算

为了探讨城市森林三维绿量的测算方式及精度,该文利用2001年8月沈阳市真彩航片和抽样调查,借助ARC/GIS,以“立体量推算立体量”的方法测算沈阳城市森林三维绿量.结果表明,不同城市森林类型的单位面积三维绿量以风景游憩林最高,为5.35 m3/m2,附属林4.93 m3/m2,道路林3.65 m3/m2,生态公益林3.62 m3/m2,生产经营林2.35m3/m2;城市森林分布区的单位面积三维绿量为4.25 m3/m2;城区单位面积城市森林三维绿量为0.35 m3/m2.沈阳城市森林总体三维绿量为161 296 716.85 m3,其中附属林为60 116 966.36 m3,占37.27%,生态公益林43 321 771.43 m3,占26.86%,风景游憩林30 482 879.04 m3,占18.90%,道路林23 841 208.75 m3,占14.78%,生产经营林3 533 891.27 m3,占2.19%.经检验,该方法精度达到85.50%(α=0.05).

Novel acidic porous clay heterostructure with highly ordered organic-inorganic hybrid structure: one-pot synthesis of mesoporous organosilica in the galleries of clay

A new class of organic-inorganic hybrid porous clay heterostructures (HPCHs) have been prepared through the surfactant-directed assembly of organosilica in the galleries of montmorillonite. The reaction involved hydrolysis and condensation of phenyltriethoxysilane and tetraethoxysilane in the presence of intragallery surfactant templates (dodecylame and cetyltrimethylammonium ion). The surfactant templates were removed from the pores by solvent-extraction. The products were characterized by X-ray diffraction (XRD), N-2 adsorption, solid-state Si-29 and C-13 NMR, and FTIR. XRD patterns indicated a regular interstratification of the clay layers for HPCHs. Depending on loading of phenyl groups, HPCHs had BET surface areas of 390-771 m(2) g(-1), pore volumes of 0.3-0.59 cm(3) g(-1), and the framework pore sizes in the supermicropore to small mesopore range (1.2-2.6 nm). HPCHs were hydrophobic and acidic.

(类)钙钛石型催化剂上NO分解反应机理的研究

研究了NO分解反应中NO2和O2形成的反应机理,同时也关联了吸附氧的脱附方式.结果表明,NO2的形成主要是在催化剂表面通过NO和吸附氧反应进行的,吸附的氧脱附是通过NO2的形式进行的,而O2的形成则主要是通过NO2的分解进行.

Renewable-surface amperometric nitrite sensor based on sol-gel-derived silicomolybdate-methylsilicate-graphite composite material

A new type of silicomolybdate-methylsilicate-graphite composite material was prepared by the sol-gel technique and used for the fabrication of an amperometric nitrite sensor. The silicomolybdic anion acts as a catalyst, the graphite powder ensures conductivity by percolation, the silicate provides a rigid porous backbone and the methyl groups endow hydrophobicity and thus limit the wetting section of the modified electrode. Cyclic voltammetry, square-wave voltammetry and chronoamperometry were employed to characterize the sensor. The amperometric nitrite sensor exhibited a series of good properties: high sensitivity (1.771 mu A mmol(-1) dm(3)), a short response time (7 s), remarkable long-term stability and especially reproducibility of surface renewal in the event of electrode surface fouling.

Synthesis of lanthanide-alkylaluminium bimetallic complexes and studies on their catalytic activities for polymerization of some polar monomers

Three new lanthanide (Ln)-alkylaluminium (Al) bimetallic complexes with the formula [(mu-CF3CO2)(2)Ln(mu-CF3CHO2)AIR(2) . 2THF](2) (Ln = Nd, Y, R=i-C4H9 (i-Bu); Ln=Eu, R=C2H5(Et); THF=tetrahydrofuran) were synthesized by the reaction of Ln(CF,CO,), (Ln=Nd, Y) with HAI (i-Bu)(2) and of Eu(CF3CO2)(3) with AlEt(3), respectively. Their crystal structures were determined by X-ray diffraction at 233 K. [(mu-CF3CO2)(2)Nd (mu-CF3CHO2)Al(i-Bu)(2) . 2THF](2) (Nd-Al) and [(mu-CF3CO2)(2)Y(mu-CF3CHO2)Al(i-Bu)(2) . 2THF](2) (Y-Al) are isomorphous and crystallize in space group with a=12.441(3) Angstrom [12.347(5) Angstrom for Y-Al], b=12.832(3) Angstrom [12.832(4) Angstrom], c=11.334(3) Angstrom [11.292(8) Angstrom], alpha=104.93 (2)degrees [104.45(4)degrees], beta=98.47(2)degrees [98.81(4)degrees], gamma=64.60(2)degrees [64.30(3)degrees], R=0.519 [0.113], R(w)=0.0532 [0.110], Z=1 and [(mu-CF3CO2)(2)Eu(CF3CHO2)AlEt(2) . 2THF](2)(Eu-Al) in space group P2(1)/n with a=11.913(6) Angstrom, b=14.051(9) Angstrom, c=17.920(9) Angstrom, alpha=101.88(11)degrees, beta=gamma=90 degrees, R=0.0509, R(w)=0.0471 and Z=2. The six CF3CO2- (including CF3CHO2-) of each complex, among which pairs are equivalent, coordinated to Ln and Al in three patterns: (A) the two oxygen atoms in one of the three CF3CO2- type coordinated to two different Ln; (B) the two oxygen atoms in the second of CF3CO2- type coordinated to Ln and Al, respectively; (C) one of the two oxygen atoms in the third CF3CO2- type bidentately coordinated to two Ln and another oxygen coordinated to Al and one of the two Ln, respectively. Unlike types A and B, in type C the carboxyl carbon with a hydrogen atom bonded to it was found to appear as an sp(3)-hybridized configuration rather than an sp(2)-one. 1D and 2D NMR results further confirmed the existence of such a disproportionated CF3CHO2- ligand. Methyl methacrylate (MMA) and epichlorohydrin (ECH) could be polymerized by Y-Al or Eu-Al as a single-component catalyst and highly syndiotactic poly(MMA) was obtained. THF could also be polymerized by Y-Al in the presence of a small amount of ECH.

SYNTHESES AND X-RAY STRUCTURES OF BIS(T-BUTYLCYCLOPENTADIENYL)LANTHANIDE CHLORIDE COMPLEXES [(BU(T)CP)2LNCL]2 (LN = PR, GD, ER)

Reaction of lanthanide trichlorides with two equivalents of sodium t-butylcyclopentadienide in THF gave rise to the bis(t-butylcyclopentadienyl)lanthanide chloride complexes [(Bu(t)Cp)2LnCl]2 (Ln = Pr, Gd, Er), which were characterized by elemental analysis, IR and H-1 NMR spectroscopy. In addition, the crystal structures of [(ButCp)2PrCl]2 (1) and [(ButCp)2GdCl]2 (2) were determined by single crystal X-ray diffraction at room temperature. The coordination number for Pr3+ and Gd3+ is 8 and the bond lengths Pr-Cl and Gd-Cl are 2.864(2) and 2.771(3) angstrom, respectively. The structural studies showed the complexes to have C2h symmetry.