192 resultados para ZnS-CdS
Resumo:
CdSe nanoclusters overcoated with CdS shell were prepared with macapoacetic acid as stabilizer. The optical properties of CdSe nanoclusters and the influence of CdS shell on the electronic structures of CdSe cores were studied by optical absorption, photoluminescence (PL) and photoluminescence excitation (PLE) spectroscopies. Based on PL and PLE results and the theoretical calculation on fine structure of bandedge exciton, a model of formation of excimer within the small clusters was proposed to explain the large Stokes shift of luminescence from absorption edge observed in PL results. (C) 2000 Elsevier Science B.V. All rights reserved.
Resumo:
Eu2+-doped ZnS nanoparticles with an average size of around 3 nm were prepared, and an emission band around 530 nm was observed. By heating in air at 150 degrees C, this emission decreased, while the typical sharp line emission of Eu3+ increased. This suggests that the emission around 530 nm is from intraion transition of Eu2+: In bulk ZnS:Eu2+, no intraion transition of Eu2+ was observed because the excited states of Eu2+ are degenerate with the continuum of the ZnS conduction band. We show that the band gap in ZnS:Eu2+ nanoparticles opens up due to quantum confinement, such that the conduction band of ZnS is higher than the first excited state of Eu2+, thus enabling the intraion transition of Eu2+ to occur.
Resumo:
CdS nanoparticies were prepared in air and their stability by air annealing was studied. A small change in crystal structure and particle size was observed by air annealing, but a rapid reduction in fluorescence was found. Through investigation, it is revealed that it is the surface change or reconstruction rather than the variation of the size or structure that decreases the fluorescence. The emission of the particles consists with two peaks which are dependent on the excitation energy. The two peaks are considered to be arisen from "two" different sizes of nanoparticles and may be explained in terms of selectively excited photoluminescence. Finally we discuss why the discrete state of nanoparticles are able to be resolved in the photoluminescence excitation spectrum, but could not be differentiated in the absorption spectrum.
Resumo:
In the framework of the effective-mass envelope-function theory, the electronic and optical properties of a spherical core-shell quantum-dot quantum well (QDQW) structure with one and two wells have been investigated. The results show that the energies of electron and hole states depend sensitively on the well thickness and core radius of quantum-dot quantum well structure. An interesting spatially separated characteristic of electron and hole in QDQW is found and enhanced significantly in the two-wells case. The normalized oscillator strength for the optical transition between the electron and hole states in QDQW exhibits a deep valley at some special well thickness. The Coulomb interaction between the electron and hole is also taken into account. [S0163-1829(98)02412-6].
Resumo:
CdS clusters are formed in the pores of a mesoporous zeolite in which the size of the clusters may be adjusted. The size of the clusters increases as the CdS loading is increased. X-ray diffraction investigation shows that the lattice constants of the clusters contract upon increasing size. This contraction is attributed to an increase of the static pressure exercised by the zeolite framework as the clusters grow bigger. Both the excitonic and trapped emission bands are detected and become more intensive upon decreasing size. Three absorption bands appear in the photoluminescence excitation (PLE) spectra and they shift to the blue as cluster size decreases. Based on the effective-mass approximation, the three bands are assigned to the 1S-1S, 1S-1P and 1S-1D transitions, respectively. The size-dependence of the PLE spectra can also be explained. (C) 1997 Elsevier Science Ltd.
Resumo:
We reported the synthesis of CdS semiconductor nanoparticles using a simple one-pot reaction by thermolysis of cadmium acetylacetonate in dodecanethiol. Optical measurements of the as-obtained CdS nanoparticles revealed that their optical properties were closely related to surface effects. Based upon the cocktail of poly (N-vinylcarbazole) (PVK) and CdS nanoparticles, a bistable device was fabricated by a simple solution processing technique. Such a device exhibited a remarkable electrical bistability, which was attributed to the electric field-assisted charge transfer between PVK and the CdS nanoparticles capped by dodecaethiol. The conduction mechanism changed from an injection-controlled current to a bulk-controlled one during switching from OFF-state to ON-state.
Resumo:
Thermoluminescence (TL) of CdS clusters encapsulated in zeolite-Y is reported for the first time. The TL of the clusters is much stronger than that of the bulk CdS and increases as the CdS loading decreases. This inverse dependence of TL intensity upon CdS loading is caused mainly by the size-effect of the clusters. All samples exhibit almost the same glow peak position and shape, indicating that traps or surface states are not sensitive to the cluster sizes.
Resumo:
The excitation spectrum of CdS dusters in zeolite-Y is consistent with their absorption spectrum, both showing two absorption bands that are assigned to the Is-is and Is-lp transitions, respectively. A new emission at 400 nn is considered to be the recombination of the bounded excitons. The emission firstly increases then decreases with increasing cluster size or loading. The emission by excitation into the Is-is band is stronger and sharper than that by excitation into the Is-lp band. This phenomenon is attributed to the size inhomogeneity and the strong electron-phonon interaction of the dusters. Copyright (C) 1996 Elsevier Science Ltd
Resumo:
CdS clusters in zeolite-Y have been prepared by the exchange of Cd2+ into the zeolite following by sulfurization with Na2S in solution. Blue-shifts from the bulk caused by quantum size effect and the change of absorption upon CdS loading are observed. Two absorption bands are detected for one of the sample and are assigned to the 1s-1s band and exciton transition, respectively. The exciton feature is more pronounced in the excitation spectrum than in the absorption spectrum, and the luminescence excited at the exciton band is stronger than that at the 1s-1s band. Copyright (C) 1996 Elsevier Science Ltd
Resumo:
用时间分辨光谱研究了很大的Te组分范围内的ZnS1-xTex(x=0.005-0.85)合金的发光动力学特性,结果表明:不同形态的Te等电子中心具有不同的辐射复合寿命,从几个ns到几十个ns的范围内变化,当x=0.15左右时,寿命达到最大值(约40 ns).其物理机理源于不同的Te等电子中心具有不同的局域化特性.当Te组分较小时,等电子中心从Te1逐渐演变到Te2,Te3或Te4时,相应发光寿命增加,表现出不断增强的激子发光局域化特性;而当Te组分较大时,Te原子团变得较大,其局域势与基体原子势的相互作用增强,等电子中心的局域化特性减弱,而基体价带扩展态特征变得明显起来,相应发光寿命逐渐减小.还研究了激子束缚能随Te组分的变化以及发光强度随温度的变化关系,所得结果进一步支持了时间分辨光谱研究所得到的结论.
Resumo:
测量了ZnS:Mn纳米粒子以及相应体材料在不同压力下的光致发光谱.随压力增大,来源于Mn2+离子的4T1-6A1跃迁的桔黄色发光明显红移.体材料和10,4.5,3.5,3 nm的ZnS:Mn纳米粒子中Mn2+发光的压力系数分别是-29.4±0.3和-30.1±0.3,-33.3±0.6,-34.6±0.8,-39±1 meV/GPa,压力系数的绝对值随粒子尺寸减小而增大,该种尺寸关系由晶体场场强Dq和Racah参数B值的尺寸依赖性引起.1nm样品的Mn2+发光的特殊压力行为是因为样品的粒子尺寸比较小,另外,分布在Y型沸石中的纳米粒子的表面状况也不同于其它样品.
Resumo:
研究了4块ZnS∶Te薄膜样品(Te组分从0.5%到3.1%)的光致发光谱在常压下的温度特性.对于Te组分较小的2块样品观察到2个发光峰,分别来自Te1和Te2等电子陷阱;而对Te组分较大的2块样品则只观察到1个来自Te2等电子陷阱的发光.我们还研究了这些发光峰在低温15K下的流体静压压力行为.观察到与Te1有关的发光峰压力系数比ZnS带边的要大很多,而与Te2有关的发光峰压力系数则比带边小.根据Koster-Slater模型,价带态密度半宽随压力的增加是Te1中心有较大压力系数的主要原因,而Te1和Te2中心的不同压力行为则是由于压力对两者缺陷势增强的不同效果引起的.
Resumo:
以甲基丙烯酸为表面包覆剂在水/醇溶液中合成了ZnS:Eu~3+, ZnS:Tb~3+纳米晶,用傅里叶变换红外光谱和X射线粉末衍射谱表征了样品的表面与晶型,样品均为立方闪锌矿型,没有出现与稀土离子相关的相;用光致发光和激发谱研究了样品中的发光过程,其中ZnS:Tb~3+纳米晶中存在纳米基质与Tb~3+之间的能量传递,并引起Tb~3+的特征发射。