Pervasive autocorrelation of the chemical index of alteration in sedimentary profiles and its palaeoenvironmental implications

The chemical index of alteration has been used widely for reconstruction of the palaeoclimate. However, the mechanisms and environmental factors controlling the chemical index of alteration of sediments are not yet fully understood. In this study, autocorrelations of the chemical index of alteration in nine sedimentary profiles, from both the land and the sea, spanning different geological times, are discussed. The sediments of these profiles have different origins (dust, fluvial or ocean sediments) and are from various climate situations and sedimentary environments. Autocorrelations of chemical index of alteration series are ubiquitously evident in all profiles. It is suggested here that autocorrelations may be caused by post-depositional changes such as persistent weathering and diagenesis. As a result, the chemical index of alteration may not reflect climatic conditions during the time of sediment deposition. This study strongly recommends the confirmation of the reliability and veracity of the chemical index of alteration before it is adopted to evaluate the weathering degree of parent rocks and to reconstruct the past climate. Significant autocorrelations in loess profiles were specifically observed, suggesting that the existing understanding of loess deposition in terms of climate conditions requires re-examination, and that previous reconstructions of rapid climate changes (for example, in centennial-millennial scales) should be treated with caution.

Grain size distribution of quartz isolated from Chinese loess/paleosol

Grain size distribution of bulk loess-paleosol and quartz chemically extracted from the loess/paleosol shows that mean size of the bulk samples is always finer than that of the quartz, The original aeolian depositions have been modified to various degrees by post-depositional weathering and pedogenic processes. The grain size distribution of the isolated quartz should be close to that of the primary aeolian sediment because the chemical pretreatment excludes secondary produced minerals. Therefore, the grain size of the quartz may be considered to more clearly reflect the variations of winter monsoon intensity.

Mineral provinces and matter provenance of the surficial sediments in the western Philippine Sea: implication for modern sedimentation in West Pacific marginal basin

The characteristics and distribution patterns of detrital minerals (0.063 similar to 0.125 mm) in marine sediments provide a significant indicator for the identification of the origin of sediment. The detrital mineral composition of 219 surface sediment samples was analysed to identify the distribution of sediments within the western Philippine Sea. The area can be divided into three mineral provinces: ( 1) province east of the Philippine Trench, the detrital minerals in this province are mainly composed of calcareous or siliceous organisms, with the addition of volcanogenic minerals from an adjacent island arc; (II) middle mineral province, clastic minerals including feldspar, quartz and colorless volcanic glass, sourced from seamounts with intermediate-acid volcanic rock, or erupting intermediate-acid volcano; (III) province west of the Palau-Kyushii Ridge, the matter provenance within this province is complex; the small quantity of feldspar and quartz may be sourced from seamounts or erupting volcano with intermediate - acid composition, with a component of volcanic scoria sourced from a volcano erupting on the Palau-Kyushu Ridge. it is suggested that, ( I) Biogenic debris of the study area is closely related to water depth, with the amount of biogenic debris controlled by carbonate lysocline. (2) Volcaniclastic matter derived from the adjacent island are can be entrained by oceanic currents and transported towards the abyssal basin over a short distance. The weathering products of volcanic rocks of the submarine plateau ( e. g. I Benham Plateau) and adjacent ridges provide an important source of detrital sedimentation, and the influence scope of them is constrained by the intensity of submarine weathering. (3) Terrigenous sediments from the continent of Asia and the adjacent Philippine island arc have little influence on the sedimentation of this study area, and the felsic mineral component is probably sourced from volcanic seamounts of intermediate-acid composition.

Preservation of black carbon in the shelf sediments of the East China Sea

Concentrations and carbon isotopic (C-14, C-13) compositions of black carbon (BC) were measured for three sediment cores collected from the Changjiang River estuary and the shelf of the East China Sea. BC concentrations ranged from 0.02 to 0.14 mg/g (dry weight), and accounted for 5% to 26% of the sedimentary total organic carbon (TOC) pool. Among the three sediment cores collected at each site, sediment from the Changjiang River estuary had relatively high BC contents compared with the sediments from the East China Sea shelf, suggesting that the Changjiang River discharge played an important role in the delivery of BC to the coastal region. Radiocarbon measurements indicate that the ages of BC are in the range of 6910 to 12250 years old B. P. (before present), that is in general, 3700 to 9000 years older than the C-14 ages of TOC in the sediments. These variable radiocarbon ages suggest that the BC preserved in the sediments was derived from the products of both biomass fire and fossil fuel combustion, as well as from ancient rock weathering. Based on an isotopic mass balance model, we calculated that fossil fuel combustion contributed most (60%. 80%) of the BC preserved in these sediments and varied with depth and locations. The deposition and burial of this "slow-cycling" BC in the sediments of the East China Sea shelf represent a significant pool of carbon sink and could greatly influence carbon cycling in the region.

Evolution and variability of the East Asian summer monsoon during the Pliocene: Evidence from clay mineral records of the South China Sea

The Late Pliocene is thought to be characterized by the simultaneous intensification of both the East Asian winter monsoon (EAWM) and East Asian summer monsoon (EASM). However, the evolution of the EASM during the Pliocene remains still controversial and only little is known about the dynamics of the EASM during the Pliocene on orbital time scales. Here we use clay mineral assemblages in sediments from Ocean Drilling Program (ODP) Site 1143 in the southern South China Sea (SCS) to obtain proxy records of past changes in the EASM climate during the Pliocene. Provenance analysis suggests that illite, chlorite and kaolinite originated mainly from the Mekong River drainage area. Smectite was derived mainly from the Indonesian islands. The kaolinite/illite ratio and the chemical index of alteration (CIA) of siliciclastic sediments allowed us to reconstruct the history of chemical weathering and physical erosion of the Mekong River drainage area and thus, the evolution of,the EASM during the Pliocene. Our clay minerals proxy data suggests a stronger EASM during the Early Pliocene than during the Late Pliocene. We propose that the long-term evolution of the EASM has been driven by global cooling rather than the uplift of the Tibetan Plateau. Spectral analysis of kaolinite/ illite ratio displays a set of strong periodicities at 100 ka, 30 ka, 28 ka, 25 ka, and 22 ka. with no clear obliquityrelated signal. Our study suggests that the Pliocene EASM intensity on orbital time scales is not only controlled by the Northern Hemisphere summer insolation, but also strongly influenced by equatorial Pacific ENSO-like ocean atmosphere dynamics. (C) 2010 Elsevier B.V. All rights reserved.

The distribution, enrichment and source of potential harmful elements in surface sediments of Bohai Bay, North China

A geochemical study of Bohai Bay surface sediments was carried out to analyze the potential harmful element (PHE: Ge, Mo, In, Sn, Sb,Te, Tl, Bi and V) concentrations, transportation and deposition, enrichment factors and sources. Germanium, Mo, In, Sn, Sb, Te, Tl, Bi and V concentrations in the surface sediments were: 1.43-1.71, 0.52-1.43, 0.04-0.12, 2.77-4.14, 1.14-2.29, 0.027-0.085, 0.506-0.770, 0.27-0.63 and 70.35-115.90 mu g/g, respectively. The distributions of total PHE concentrations, together with sequential extraction analyses, showed that the PHEs were mainly due to natural inputs from the continental weathering delivered to the bay by rivers and atmospheric transportation and deposition. However, high Mo, Sb, Te, Bi and V occurred in non-residual fractions, suggesting some anthropogenic inputs in addition to the natural inputs. Besides sources, the distributions of PHEs were influenced by the coupling of physical, chemical and biological processes. Enrichment factor (EF) was computed for each site for each element in order to assess the polluting elements and the degree of pollution at each site. Results revealed that the EFs were generally lower than 1.0, particularly for Ge, Mo, In, Sn, Tl and V; however, the EFs were higher (>1.5), particularly for Sb, Te and Bi, revealing moderate contamination. (C) 2010 Elsevier B.V. All rights reserved.

The unique skeleton of siliceous sponges (Porifera; Hexactinellida and Demospongiae) that evolved first from the Urmetazoa during the Proterozoic: a review

Sponges (phylum Porifera) had been considered as an enigmatic phylum, prior to the analysis of their genetic repertoire/tool kit. Already with the isolation of the first adhesion molecule, galectin, it became clear that the sequences of sponge cell surface receptors and of molecules forming the intracellular signal transduction pathways triggered by them, share high similarity with those identified in other metazoan phyla. These studies demonstrated that all metazoan phyla, including Porifera, originate from one common ancestor, the Urmetazoa. The sponges evolved prior to the Ediacaran-Cambrian boundary (542 million years ago [myr]) during two major "snowball earth events", the Sturtian glaciation (710 to 680 myr) and the Varanger-Marinoan ice ages (605 to 585 myr). During this period the ocean was richer in silica due to the silicate weathering. The oldest sponge fossils (Hexactinellida) have been described from Australia, China and Mongolia and are thought to have existed coeval with the diverse Ediacara fauna. Only little younger are the fossils discovered in the Sansha section in Hunan (Early Cambrian; China). It has been proposed that only the sponges possessed the genetic repertoire to cope with the adverse conditions, e.g. temperature-protection molecules or proteins protecting them against ultraviolet radiation. The skeletal elements of the Hexactinellida (model organisms Monorhaphis chuni and Monorhaphis intermedia or Hyalonema sieboldi) and Demospongiae (models Suberites domuncula and Geodia cydonium), the spicules, are formed enzymatically by the anabolic enzyme silicatein and the catabolic enzyme silicase. Both, the spicules of Hexactinellida and of Demospongiae, comprise a central axial canal and an axial filament which harbors the silicatein. After intracellular formation of the first lamella around the channel and the subsequent extracellular apposition of further lamellae the spicules are completed in a net formed of collagen fibers. The data summarized here substantiate that with the finding of silicatein a new aera in the field of bio/inorganic chemistry started. For the first time strategies could be formulated and experimentally proven that allow the formation/synthesis of inorganic structures by organic molecules. These findings are not only of importance for the further understanding of basic pathways in the body plan formation of sponges but also of eminent importance for applied/commercial processes in a sustainable use of biomolecules for novel bio/inorganic materials.

三门峡宋家店黄土－古土壤序列的地层学研究及其古环境记录

The Sanmen Gorge area is located in the southernmost margin of the Chinese Loess Plateau with well developed eolian deposit sequence for the past 2.6 Ma, providing a key site for further understanding of the evolution history of the East Asian monsoon since late Pliocene. This study attempted to characterize the stratigraphy and paleoclimate record of the loess-paleosol sequence in the Songjiadian section. The work involved includes systematic field investigation, paleomagnetic and rock magnetic analyses, grain size and major chemical composition analyses, and multiple proxy measurements of magnetic susceptibility, color reflectance and the ratio of CBD-dissolvable iron to the total iron (FeD/FeT). By comparisons of the Songjiadian section with well studied loess sections in the west of the Sanmen Gorge, the spatial variations of the East Asian monsoon was evaluated for some periods during which typical loess or paleosols developed. The following conclusions have been obtained. 1. Stratigraphic correlation and paleomagnetic result demonstrate that the loess-paleosol sequence in the Songjiadian section was accumulated from 2.6Ma, and is generally a complete and continuous loess sequence. However, notable differences from type loess sections have been identified for a few loess and paleosol units, featured by absence or anomalous thickness in the Songjiadian section. 2. Magnetic susceptibility and chromaticity records clearly reveal the loess-paleosol cycles, and indicate that the Sanmen Gorge area has been warmer and more humid than the Lingtai and Jingchuan sections in the western central Loess Plateau since the Early Pleistocene. 3. Grain size distribution patterns are typical of eolian dust, and show a great similarity between various units of loess and paleosols, and between the S32 and the underlying Red Clay through the Songjiadian profile, suggesting the eolian origin for the loess, paleosols and the Red Clay. 4. Comparison of the FeD/FeT curves from different loess sections indicates a stronger chemical weathering in the Songjiadian section and notable enhancement around 1800, 800 and 600 ka BP, implying the strengthening of the East Asian monsoon during these periods. In contrast, it was weakened at 1100 ka BP. Generally, the summer monsoon shows a gradually decreasing trend during the entire Pleostocene, but the spatial pattern typified by an increasing trend in weathering intensity from north to south remained the same. 5. The loess unit L9 in the Songjiadian section displays two geomagnetic field anomalies with the midpoint ages of 0.917 and 0.875 Ma respectively, with a segment of 12 ka. They are demonstrated to be equivalent to the Santa Rosa and Kamikatsura geomagnetic excursions. 6. Magnetite is the main magnetic carrier for both loess and paleosols. Maghemite concentration is higher in paleosols than in loess, and is an important carrier for the enhanced magnetic susceptibility in paleosols. Magnetic fabric analysis suggests a dominant N-S wind direction prevailing in the L9 and L15, while the summer winds were dominantly in NNE-SSW direction during the S8 period, notably differing from previous studies.

层析静校正技术研究和应用

Static correction is one of the indispensable steps in the conventional onshore seismic data processing, particularly in the western part of China; it is theoretically and practically significant to resolve the issue of static correction. Conventional refraction static correction is put forward under the assumption that layered medium is horizontal and evenly distributed. The complicated nature of the near surface from western part of China is far from the assumption. Therefore, the essential way to resolve the static correction problem from the complex area is to develop a new theory. In this paper, a high-precision non-linear first arrival tomography is applied to solve the problem, it moved beyond the conventional refraction algorithm based on the layered medium and can be used to modeling the complex near surface. Some of the new and creative work done is as follows: One. In the process of first arrival tomographic image modeling, a fast high-order step algorithm is used to calculate the travel time for first arrival and ray path and various factors concerning the fast step ray tracing algorithm is analyzed. Then the second-order and third-order differential format is applied to the step algorithm which greatly increased the calculation precision of the ray tracing and there is no constraint to the velocity distribution from the complex areas. This method has very strong adaptability and it can meet the needs of great velocity variation from the complicated areas. Based on the numerical calculation, a fast high-order step is a fast, non-conditional and stable high-precision tomographic modeling algorithm. Two, in the tomographic inversion, due to the uneven fold coverage and insufficient information, the inversion result is unstable and less reliable. In the paper, wavelet transform is applied to the tomographic inversion which has achieved a good result. Based on the result of the inversion from the real data, wavelet tomographic inversion has increased the reliability and stability of the inversion. Three. Apply the constrained high-precision wavelet tomographic image to the static correction processing from the complex area. During tomographic imaging, by using uphole survey, refraction shooting or other weathering layer method, weathering layer can be identified before the image. Because the group interval for the shot first arrival is relatively big, there is a lack of precision for the near surface inversion. In this paper, an inversion method of the layer constraint and well constraint is put forward, which can be used to compensate the shallow velocity of the inversion for the shot first arrival and increase the precision of the tomographic inversion. Key words: Tomography ，Fast marching method，Wavelet transform, Static corrections, First break

潜山油藏裂缝分布规律研究－－以辽河盆地大民屯凹陷潜山油藏为例

With the example of Damintun Depression, Liaohe Oilfield, different methods to study fracture distribution were propsosed, i.e. combined crop, core, log, with seismic attribute and paleo-stress field to predict fractural reservoir. The following conclusions are drawn: 1. Secondary fracture and dissolution pore are the main reservoir space of fractured reservoir in Damintun buried hills through observing more than 270 meters core in 27 wells. Among them, structural fracture is the main reservoir spcace in Archaean metamorphism whose main mineral are silicates, while dissolution pore and structural fracture are the main reservoir space in Protozoic carbonate which has been proved with high dissolution. Structural fracture is not only the main reservoir space but also the influent path. 2. Actual core observation and log identification proved that the formation of buried hills have the following zone: weathering crust, fracturaed zone and compact zone, among which the weathering crust and fractured zone are the main reservoir. 3. The mineralogical component of rock is the inner factor and the tectonization is the outer factor, which control the development of structural fracture. The content of brittle material in rock influences the development of structural fracture. Dissolution, chemical eluviations, weathering and fill-up affect the development of structural fracture. 4. Basement faults control the distribution of structural fracture in Damintun Depression. The trend of fracture is consistent with that of faults and there is often large-scale fractural zone around faults. 5. Based on log response, the fracture is identified with core observation, imaging well log and ANN, which can provide geological basis for optimized perforation. 6. The methods for predicting fracture with structure restoration, seismic inversion and paleo-stress simulation aiming at different types of buried-hills reservoir, and then the spatial distribution of the fracture and density is obtained, which can provide geological basis for well site adjustment.

塔克拉玛干沙漠地球化学研究

The Taklamakan Desert, lying in the center Tarim Basin of sourthern Xinjiang, is the largest sand sea in China and well known in the world as its inclemency. For understanding the formation and evolution of the Taklamakan Desert, it is very important to identify the provenance of aeolian sediments in the extensive dune fields, but the opinions from earlier studies are quite different. In this study, we examined the major- and trace-element compositions, mineral compositions and grain-size distributions of some Quaternary aeolian and nonaeolian sediments collected from the Taklamakan Desert, together with the variation of chemical and mineralogical compositions of different grain-size fraction. At the same time, we also studied the chemistries of some natural water samples (river water and groundwater) with the items of TDS, pH, Alkalinity, conductivity and major cation and anion compositions. Our results of analysis show some significant opinions as follow: Most of the frequency-distribution curves of grain size of dune sand samples are simgle peak, but that of the river and lacustrine sediment are most double peak or multi-peak. The grain-size distribution of dunefield sand changed gradually from north to south with the major wind direction in large scale, but there are many differences in regional scale. The major, REE, trace element compositions and mineral compositions are very different among the coarse, fine fraction and bulk samples due to the influence of grain-size. Most of the fine fractions are geochemically homogenous, but the coarse fractions and bulk samples are heterogenous. All the surface and ground waters are limnetic or sub-salty, their chemical compositions are mainly controlled by rock-weathering and crystallization- evaporation processes, and mainly come from the evaporate, while the contributions of the carbonate and silicate are little, excluding the influence on oasis water by carbonate. The mineral compositions of selected samples are stable, mainly composed of the strongly resistant mineral types. The mineral maturity of them are more immature at whole compared with other sandy sediments in the world, and they have experienced less degree of chemical weathering and recycling, being lying in the early stage of continental weathering. Among these sediments, the river sediments are relatively primitive. The sources of these sediments are maybe mainly terrigenous, silicic and subaluminous/ metalunious rocks, such as the granodiorite and its metamorphic rock. The geochemical compositions of dunefield sand are similar with those of the river sediments and dune sands near the river way; There are not only the resemblances but also the differences on geochemistry and granularity between north and south dunesands; The sediments from same section have different age but same trace-element compositions; The sediments from the south edge of Tarim Basin are all somewhat geochemically similar with the palaeo-river-sediment on the south edge of studying area. The REE data support the idea that the south dunesands are a little older than the north dunesands, and the tectonic settings of source area are mainly active continental margin based on the major-element compositions, so they indicate that the sediment of Taklamakan Desert maybe come mainly from the rock-weathering production of north part of the Kunlun Mountains. Compared with the sands of other dune field in north of China, the sands of the Taklamakan Desert are distinct by REE composition, but similar with the Luochuan loess, center China, and the two sandy dusts of Beijing, eastern China.

藏东南巨厚松散堆积体发育条件、成灾模式及防治对策——以川藏公路然乌至鲁朗段为例

The unique geologic, geomorphic and climatic conditions of southeast Tibet have made the region to develop the multi-style and frequently occurring geologic hazards, especially the collapses and landslides and debris flows along the section of Ranwu-Lulang in Sichuan-Tibet highway. However, most of those geologic hazards have close relationship with the loose accumulations. That is, the loose accumulations are the main carrier of most geologic hazards. Thereof, the huge-thick accumulations along the highway is regarded as the objective in the thesis to study the geologic background, hazarding model and mitigation methods comprehensively, based on the multi-disciplinary theories and former materials. First of all, in the paper, based on field engineering geologic investigations, the genetic type and the characteristics of spatiotemporal distribution of the huge-thick loose accumulations along the highway, have been analysized from the factors of regional geology and geomorphy and climate, as well as the coupling acting of those factors with inoculation and eruption of the loose accumulations geologic hazards. The huge-thick loose accumulations has complex genetic types and specific regulations of spatiotemporal distribution, closely controlled by the outer environment of the region. The accumulations are composed of earth and boulder, with disorder structure and poor sorting, specific forming environments and depositing conditions. And its physical and mechanic properties are greatly distinguished from rock and common earth inland. When Sichuan-Tibet highway was firstly constructed along the north bank of Purlung Tsangpo River, the huge-thick loose accumulations was cut into many high and steep slopes. Through the survey to the cut-slopes and systematic investigation to their failures, the combination of height and angle of the accumulations slope has been obtained. At the same time, the types of genetic structure of those cut-slopes are also analysized and concluded, as well as their failure models. It is studied in the paper that there are piaster, duality, multielement and complexity types in genetic structure, and rip-dump-repose, rip-shear-slip and weathering-flake types in failure models. Moreover, it is briefly introduced present engineering performance methods and techniques dealing with the deformation and failure of the accumulations cut-slope. It is also suggested that several new techniques of slope enforcement and the method of landslide and rockfall avoiding should be applied. The research of high and steep cut-slope along the highway has broadened the acknowledgement of the combination of cut-slope height and angle. Especially, the dissertation also has made the monographic studies about the geologic background and hazarding models and prevention methods of some classic but difficult accumulations geologic hazards. They are: (1) Research of the engineering geologic background of the 102 landslide group and key problems about the project of tunnel. The 102 landslide group is a famous accumulational one composed of glacial tills and glaciofuvial deposit. The tunnel project is a feasible and optional one which can solve the present plight of “sliding after just harnessing” in the 102 section. Based on the glacial geomorphy and its depositing character, distribution of seepage line, a few drillhole materials and some surveying data, the position of contact surface between gneiss and accumulations has been recognized, and the retreating velocities of three different time scales (short, medium and long term) have been approximately calculated, and the weathering thickness of gneiss has also been estimated in the paper. On the basis of above acknowledgement, new engineering geomechnic mode is established. Numerical analysis about the stability of the No.2 landslide is done by way of FLAC program, which supplies the conclusion that the landslide there develops periodically. Thereof, 4 projects of tunnel going through the landslide have been put forwards. Safety distance of the tunnel from clinohefron has been numerically analysized. (2) Research of the geologic setting and disaster model and hazard mitigation of sliding-sand-slope. From the geologic setting of talus cone, it is indicated that the sliding-sand-slope is the process of the re-transportation and re-deposit of sand under the gravity action and from the talus cone. It is the failure of the talus cone essentially. The layering structure of the sliding-sand-slope is discovered. The models of movement and failure of the sliding-sand-slope has been put forwards. The technique, “abamurus+grass-bush fence+degradable culture pan”, is suggested to enforcement and green the sliding-sand-slope. (3) Characteristics and hazarding model and disaster mitigation of debris flow. The sources of solid material of three oversize debris flows have been analysized. It is found that a large amount of moraine existing in the glacial valley and large landslide dam-break are the two important features for oversize debris flow to be taken place. The disaster models of oversize and common debris flows have been generalized respectively. The former model better interpret the event of the Yigong super-large landslide-dam breaking. The features of common debris flow along the highway section, scouring and silting and burying and impacting, are formulated carefully. It is suggested that check dam is a better engineering structure to prevent valley from steeply scouring by debris flow. Moreover, the function of check dam in enforcing the slope is numerically calculated by FLAC program. (4) Songzong ancient ice-dammed lake and its slope stability. The lacustrine profile in Songzong landslide, more than 88 meters thick, is carefully described and measured. The Optical Simulated Luminescence (OSL) ages in the bottom and top of the silty clay layer are 22.5±3.3 kaB.P., 16.1±1.7 kaB.P., respectively. It is indicated by the ages that the lacustrine deposits formed during the Last Glacial Maximum ranging from 25ka B.P. to 15ka B.P. The special characteristics of the lacustrine sediment and the ancient lake line in Songzong basin indicated that the lacustrine sediment is related to the blocking of the Purlung Tsangpo River by the glacier in Last Glacial Maximum from Dongqu valley. The characteristics of the lacustrine profile also indicate that the Songzong ice-dammed lake might run through the Last Glacial Maximum. Two dimensional numerical modeling and analysis are done to simulate the slope stability under the conditions of nature and earthquake by FLAC program. The factor of safety of the lacusrtine slope is 1.04, but it will take place horizontal flow under earthquake activity due to the liquefaction of the 18.33 m silt layer. The realign to prevent the road from landslide is suggested.

东天山红山高硫型浅成低温铜-金矿床氧化带的形成机理和硫酸盐矿物的系列发现及意义

Located in the Paleozoic uplift along the southern margin of Tu-Ha basin in eastern Xinjiang, the newly discovered Hongshan Cu-Au deposit occurs in the superimposed Mesozoic volcanic basin upon the north section of later Paleozoic Dananhu-Tousuquan accretionary arc. Kalatage Cu-Au orebelt is controlled by NWW-trend faults, and includes Hongshan and Meiling Cu-Au deposits. The host rocks of Hongshan ore district are mainly rhyolitic-dacitic ignimbrites, whereas Cu-Au mineralization is closely related to quartz porphyry, rhyolitic porphyry and granitic porphyry. Mineralization styles are dominantly veinlet-disseminated and veinlet, occasionally stockwork. The mineral association is chalcopyrite, pyrite, bornite, chalcocite and sphalerite. The hydrothermal alteration consists of silicfication, sericitization, alunitization, pyrophylitization, illitization, hydromuscovitization, and chloritization. Hongshan Cu-Au deposit, on the edge of the desert, is one of the driest areas in eastrn Tianshan. Moreover， the highest temperature has been up to 60℃, and the average rainfall receives only 34.1mm/y. The light rainfall and rapid evaporation in the vicinity of this deposit have allowed the formation of a great variety of water-soluble sulfates. Oxidization zone of this deposit lies on the upper part of primary sulfide orebodies appearing with a depth of 50-60m, which is dominant in sulfate minerals. 1. Based on the field observation, the volcanic and sub-volcanic rock composition, hydrothermal alteration, ore structure and mineralization characteristics, this paper proposed that the Hongshan Cu-Au deposit belongs to a transitional type from high-sulfide epithermal to porphyry Cu-Au deposit, which corresponds with the typical HS-epithermal deposit such as Zijinshan Au-Cu deposit in Fujian Province, SE-China. 2. The Hongshan copper-gold deposit was controlled by the tectonic, stratum, magma activity and volcanic apparatus, whereas Au mineralization is closely related to quartz porphyry, rhyolitic porphyry and fine grained pyritization in hydrothermal activity, and Cu mineralization is closely related to quartz porphyry and hydrothermal explosive breccia. 3. Oxidation zone of Hongshan Cu-Au deposit lies on the upper part of primary sulfide orebodies deposit. 23 sulfate minerals were identified in this work. The results of samples XRD and chemical analysis were furthermore confirmed through thermal, infrared spectrum and mössbauer spectrum analysis. Among those, nine minerals as Ferricopiapite, Cuprocopiapite, Rhomboclase, Parabutlerite, Krausite, Yavapaiite, Metasideronatrite Kroehnkite and Paracoquimbite were founded in China for the first time. And Paracoquimbite was secondly reported in the world (first case reported at 1938 in Chile). 4. EPMA analysis shows that Al impurity in crystal lattice is important to polytype formation of paracoquimbite and coquimbite besides stack fault. 5. Compared with Meiling Cu-Au deposit in the same Kalatage ore belt from the characteristics of δ34S of barite, lithofacies, hydrothermal alteration and homogeneous temperature, Hongshan Cu-Au deposit belongs to the same metallogenic system of HS-epithermal type as Meiling Cu-Au deposit. But Hongshan Cu-Au deposit has less extensive alteration and shallower denudation. 6. Sulfur isotope analyses show that δ34S values of pyrites vary in the range of +1.86‰~+5.69‰, with an average of 3.70‰, mostly in the range of +1.86‰~+3.20‰, and δ34Scp<δ34Spy. Therefore ore-forming fluid of porphyry comes from mantle and was contaminated by the earth’s crust. Sulfur isotope has reached balance in ore-forming process. 7. Sulfur isotope analyses show that δ34S values of sulfates vary in the range of +2.15‰~+6.73‰, with an average of +3.74‰, mostly equals as δ34S values of primary sulfides in Hongshan Cu-Au deposit. So supergene sulfates inherit sulfur of primary sulfide. δ34S values are mostly same in different sulfates. As well as pyrite and chalcopyrite, volcanic hot spring and associated native sulfur underground also provide water medium and sulfur during the formation process of sulfate. 8. According to the EPMA of sample chalcopyrite and pyrite in Hongshan Cu-Au, the value of Cu/Ni is 0.98-34.72, mostly close to the value of 5, which shows that Hongshan deposit is a typical volcanogenic magmaic hypothermal deposit. Au and Ag, Zn, Te and Bi are positive correlation, Cu and Hg, Se, Sb are positive correlation, indicates Au and Cu don’t locate in the factor of mineralization of same mineralization groups. The reasons of gold concentration in the oxidation zone are: 1). Change of redox potential (Eh) makes gold to deposit from the liquid of mineralization zone; 2). PH is one of the most factors of gold’s deposition; 3). Soluble complex and colloid of gold can be adsorbed easily. 9. The biotite and hornblende K-Ar isotopic ages from the wall rock－quartz diorite, biotite granite and monzonite granite are 231.99±3.45Ma, 237.97±2.36Ma and 296.53±6.69Ma respectively. The ore-bearing rhyolitic breccia lava contains breccia of the biotite granite which indicates the volcanism and related Cu-Au mineralization occurred later than the granite, possibly in Mesozoic. K-Ar ages of granitoids in Sanya, Baishiquan and Hongliugou area and Molybdenite Re-Os age of Baishan Mo deposit all are in Triassic. Besides late Paleozoic magmatism, igneous magmatic event of Mesozoic was widespread in eastern Tianshan. 10. The K-Ar age dating indicates that the K-Ar age of Voltaite occurred below surface 1m is 56.02±3.98Ma, K-Ar age of Ferricopiapite occurred below surface 1.5m is 8.62±1.12Ma, K-Ar age of Yavapaiite occurred below surface 14 m is 4.07±0.39Ma, and K-Ar age of Voltaite occurred below surface 10 m is 14.73±1.73Ma. So the age interval of oxidation zone of Hongshan copper-golden bed is between 60 -3.38Ma. Oxidization occurred at Caenozoic era (from 65Ma), which can be identified through comparing with different deposits oxidation zone in other countries. The coupling between global tectonic event and climatic change event which occur from Caenozoic era has some effect on epigeosphere system, which can act on the surface of bed oxidation zone similarly. It induces that the age mentioned above coincide with collision of India-Asia and multistage uplifting of Qinhai-Tibet Plateau happened subsequently. Bed oxidation zone is the effect and record of collision and uplifting of Tibet Plateau. The strong chemical weathering of surface accumulation to which was leaded by PETM event occurred Paleocene and Eocene is the reason of Voltaite sharply rises. On the contrary, Ferricopiapite formed due to the global cold weather. The predecessor did much research through biota, isotopes, susceptibility, but this paper try to use different sulfate mineral instead of climatic change. So the research of sulfate minerals not only indicates a great deal of oxidized zone feature, but also the intergrowth of sulfate minerals may be used to trace paleoenviroment and paleoclimate of oxidation zone. 11. Analysis of the information of alteration and mineralization features of four bore cores, induced activity polarization well logging and Eh-4 geophysical section, deep mineralization anomaly objects of Hongshan ore districts shows low resistance, middle and high polarization, measurements of Eh-4 consecutive conductance section show the existing of concealed porphyry ore body deeper than 450m, on the top of and around rock body there are low resistance body ranged from 100-300Ω•m, this area may be the ore-bearing part. In a word, Hongshan Cu-Au deposit deposit is a combine of upper HS-style epithermal Au deposit and deeper porphyry mineralization system. It has great potential to find large HS-style epithermal-porphyry Au-Cu deposits. This paper consists of seven chapters and twenty seven sections. The geological character of deposit is basic condition in this work. Constitute of oxidation zone, research of sulfate mineral, relation between oxidation and primary zone, K-Ar ages of potassic sulfate are key parts of thesis. Genesis of ore deposit is the further expansion of this research. Analysis of ore-controlling factors is the penetration above basic. Analysis of potential is application of exploration.

三峡库区巴东组泥灰岩溶蚀作用与岩体力学性质弱化研究

Abstract The karsrt erosion engineering geology became a highlight problem in recent years, in particularly, the karst erosion of marlite of Badong formation made the rock mechanics weaken in Three Gorges Reservoir area, which reduces the safety of slope. During the immigrant construction, many high slopes have been formed, whose instabilities problems pose serious threats to the safety of the people and properties. The accidents of the slope failure take place now and then. By testing, it has been found that the karst erosion pattern and dissolution rate of marlite are not weaker than that of the pure limestone. Furthermore, owning to the weathering and unloading, the karst erosion of the marlite will reach certain depth of the slope, which is named infiltrated karst erosion. The karst erosion made the rock mass quality of slope or foundation worse in a large scale. The karst erosion geological disasters, taken place or not, has become the main restrictive factors to the social stability and economic development. Thus the karst erosion process and mechanism of marlite of Badong formation are studied as the main content of this dissertation. The weakening characteristic of rock mass mechanics parameters are studied along with the rock mass structure deformation and failure processes in the course of the karst erosion. At first, the conditions and influencing factors of the karst erosion are analyzed in the investigative region, on the basis of different karst erosion phenomenon of the marlite and different failure modes of slope. Then via indoor the karst erosion tests, it is analyzed that the karst erosion will change the rock mass composition and its structure. Through test, the different karst erosion phenomena between micro and macro have been observed, and the karst erosion mechanism of the marlite has been summarized. Damage theory is introduced to explain the feature of dissolution pore and the law of crack propagation in the marlite. By microscope and the references data, it can be concluded that the karst erosion process can be divided into rock minerals damage and rock structural damage. And the percent of karst erosion volume is named damage factor, which can be used to describe the quantify karst erosion degree of marlite. Through test, the rock mechanical properties in the different period of karst erosion are studied. Based on the damage mechanics theory and the test result, the relation between the karst erosion degree of marlite and weakening degree of mechanical properties is summarized. By numerical simulations, the karst erosive rock mass mechanics is verified. The conclusion is drawn as below: to the rock mass of marlite, the karst erosion damage made mechanics parameters variation, the deformation modulus, cohesion, and inter friction angle reduce as the negative exponent with the increasing of the karst erosion volume, however, the Poisson ratio increases as the positive exponent with the karst erosion volume increasing. It should be noticed that the deduced formulations are limited to the test data and certain conditions. It is suitable to the rock mass parametric weakening process after the karst erosion of marlite in Three Gorges Reservoir area. Based on the failure types of marlite slope in the field, the karst erosion and weathering process of rock mass are analyzed. And the evolution law of deformation and failure of the marlite mass is studied. The main failure feature of the marlite slope is the karst erosive structure subsidence mode in Three Gorges Reservoir area. The karst erosive structure subsidence mode is explained as follows: the rock mass undergoes the synthetic influence, such as weathering, unloading, corrosion, and so on, many pores and cavities have been formed in the rock mass interior, the rock mass quality is worsen and the rock mass structure is changed, and then the inherent structure of rock mass is collapsed under its gravity, therefore, the failure mode of compaction and subsidence take place. Finally, two examples are used to verify the rock mass parameters in Three Gorges Reservoir area, and the relationship between the marlite slope stability and the time of karst erosion is proposed.

环渤海花岗岩体地下油库建设的工程地质力学研究

As a kind of strategic resource，petroleum play an very important role in current social stability, economic development and state safety. Since 1993 China has turned from a net oil exporter into a net oil importer, the figure of imported oil increased from then on. In 2004 China's total energy consumption exceeded Japan’s, and ranked in the second place, just inferior to America. Today China is the world’s third-largest importing nation, accounting for 6% of world imports and 8% of world consumption. Comparing with other strategic petroleum reserve schemes, underground oil storage possess many advantages, such as security, economy, less pollution, save land, suited for strategic reserve and so on, so it is the most ideal form for strategic petroleum reserve. In the background of China Strategic Petroleum Reserve Program started just now, this paper choose Circum-Bo sea region as a study area, and do some system study on the underground oil storage caverns constructed in inter-large granite rock masses in Circum-Bo sea region. On the foundation of a great amount of information come from both home and abroad, firstly this paper analysed the principle, economy, cavern shape, profile dimension, and gain some cognizances and logos, as follows: ①Hard rock mass such as granite is the major rock, in which underground oil storage are constructed; ②Unlined underground oil storage caverns had been wide spread used as a sort of oil storage form abroad, there already exist a suit of skilled experience and technologies to prevent oil product from leaking; ③Compared with surface tanks, underground oil storage cavern possess predominance in economy clearly. In general, it will be more economical when the storage capacity exceed 50000m3. The quality of rock mass is the most important factor for underground storage cost, however such as hydrogeology, storage capacity, the number of storage galleries, the length, storage product, mechanical equipments, geographic location also influent the cost. In designed depth of the underground storage, the rock mass of Jinzhou mainly belong to class Ⅱ, but parts with dykes, clayization alteration, and dense joints are Ⅲ, Ⅳ; ④Now, there are few underground oil storages span more than 25m in both abroad and home. The examples of some ancient underground works and modern underground excavation with wide span surely give us many precious elicitations to construct more great unlined storage caverns, when the rock mass quality is good, cavern shape and construction method also are proper, it is quite possible to construct underground oil storage cavern with span more than 30m . The main axis orientation of Jinzhou underground oil storage cavern is NW direction, the cavern's elevation locate between -53msl and -76msl. The storage's total volume is about 3×106m3, composed of 8 parallel galleries with 950m length, the pillars between them are 45m, and every two of galleries form one unit, which can deposit 75×104m3 for each unit. The product will be stored are Saudi light and Saudi medium crude oil, the main cavern's section is 411.5m2, with 23m height and 19m width. According to the principle and technique of engineering geomechanics, this study supply a sort of system scientific thinking and method for sitting location of underground oil storage in granite region: ① On the foundation of the earth crust stability sub-zone appraise of Circum-Bo sea region, farther research concerning granite distribution, genesis, geological period and fault structure are conducted in stable areas, generally, this paper select Liaoxi, east shore of Liaotung peninsula and Jiaotung peninsula as target areas for underground oil storage regions, where Mesozoic granite is magnitude; ②After roundly comparison in facts of geologic structure, engineering geology, hydrogeology, topography, transportation and so on of three granite distributed areas, at last, selecting Jingzhou granite zone in Liaoxi out as an ideal construction area; ③ Detailed investigation is conducted in the southeast of Baimashi in Jingzhou development district, the final field. Ultrasonic Borehole Television, as a major way to collect original information of borehole rock mass were used, which is very effective to appraise the quality of deep rock mass; ④ According to the field data of tectonic stress, rock mass quality, the spatial distribution of fracture water, some optimum designs in cross section, axial direction and cavern span have been designed for the underground oil storage cavern layout in Jinzhou. To understand the characteristics of swelling alteration rock in Jinzhou granite mass, collected abundant swelling alteration rock engineering examples in granite, which study them in detail, concluded the swelling alteration rock distribute nearly everywhere in China, intruded medium-basic dykes alteration, along discontinuities and mineral hydrothermal alteration with genesis of granite are three main forms clayization alteration rock in granite rock mass. In Jinzhou field, from macro to micro studied the swelling rock which induced by mid-basic dyke intrusion, with weak swelling. In conclusion, this paper conclude the distribution rule and features of expansion alteration rock in filed, and advise some technical suggestions for excavation at swelling alteration rock part. The main features of this paper: ①In the process of site selection, investigation and design, a suit of technique and method of engineering geomechanics metasynthesis were formed, which is significative to guide the large scale underground oil storage cavern sitting location, investigation and design in granite rock mass; ②The detailed discussion on the engineering geology problems in granite mass, such as weathering crust, faults, dykes and clayization alteration rock, are useful for other projects in aspects of site selection, engineering geology evaluation and stability estimation; ③The summary and integration of the genesis, type, countermeasure relate to swelling alteration rock, also is likely to be used for other underground oil storage caverns constructed in swelling alteration granite. In conclusion, this study is meaningful for guiding the large scale underground oil storage for site selection, investigation and design in granite rock mass.