Antioxidant capacity and lipophilic content of seaweeds collected from the Qingdao coastline

Lipophilic extracts from 16 species of seaweeds collected along the Qingdao coastline were screened and evaluated for their antioxidant activities (AA) using the beta-carotene-linoleate assay system. The diethyl ether soluble extracts of all selected seaweeds exhibited various degrees of antioxidative efficacy in each screen. The highest antioxidant capacities among the tested samples were observed for Rhodomela confervoides and Symphyocladia latiuscula and were comparable with that of the well-known antioxidant butylated hydroxytoluene and greater than that of propyl gallate. The lipophilic content of all 16 samples and the chemical composition of 4 selected seaweeds, R. confervoides and S. latiuscula, which had higher AA, Laminaria japonica, which had intermediate AA, and Plocamium telfairiae, which had lower AA, were analyzed by gas chromatography and gas chromatography-mass spectrometry, respectively. Fatty acids and alkanes were found. The present data indicated an increase in antioxidative property with increasing content of unsaturated fatty acid. The result of this study suggests that seaweeds can be considered as a potential source for the extraction of lipophilic antioxidants, which might be used as dietary supplements or in production in the food industry. This is the first report on the antioxidant activities of lipophilic extracts from seaweeds.

Sesquiterpenes from red alga Laurencia tristicha

Three naturally new sesquiterpenes named 10-hydroxyepiaplysin, 10-hydroxyaplysin and 10-hydroxybromoepiaplysin have been isolated from Laurencia tristicha. On the basis of the spectroscopic techniques their structures were elucidated as (3S, 3 alpha R, 8 beta S)-(-)-2, 3, 3 alpha, 8 beta-tetrahydro-7-bromo-3-hydroxy-3, 3 alpha, 6,8 beta-tetramethyl-1H-cyclopenta[b]benzofuran, (3R, 3 alpha R, 8 beta S)(-)-2,3,3 alpha, 8 beta-tetrahydro-7-bromo-3-hydroxy-3, 3 alpha,6,8 beta-tetratnethyl-1H-cyclopenta[b]benzofuran and (3S, 3 alpha R, 8 beta S)-(-)-2, 3,3 alpha,8 beta-tetrahydro-3-hydroxy-3,3 alpha,6,8 beta-tetrainethyl-1H-cyclopenta[blbenzofuran, respectively.

锦屏一级水电站高应力大断面地下洞室稳定性分析

According to the feature of high stress and large size underground tunnel , a method named DEFLAC is put forward in this paper. DEFLAC is such a method that use disturbing energy as criteria, and based on the simulating software of FLAC. Finally, the method is applied in the underground powerhouse project of Jin-Ping First-level Hydropower Station. The result is well. And some conclusions are got. (1) Based on the geological features of excavation unloading phenomena, they are concluded to three types, what’s more three corresponding mechanical modes are proposed to explain the unloading phenomena. (2) The relation of two standards , which is called GB50287-99 (T) and BQ ,is studied. And the main difference of them ,when they are applied in high stress zone ,is researched. (3) .A method named DEFLAC is put forward , which is combined disturbing energy method and FLAC simulating software. The two dimension and three dimension explicit finite difference expressions are deduced in this paper. (4) Compared the instability area achieved by FLAC and DEFLAC with the measured result, a conclusion is got. That is a more accurate result can be got by DEFLAC. (5) According to the main powerhouse first layer excavation project, the method to search and analyze the instability blocks is studied in this paper. Finally, the results got by FLAC and DEFLAC are compared .A conclusion is got that DEFLAC can judge the stability of blocks induced by intermittent joints, but Block Theory can’t. So more accurate block amount can be got by DEFLAC. It is an effective method to judge stability of blocks

贵州中、下寒武统界线层型候选剖面地球化学特征研究

在贵州台江八郎凯里组中，下寒武统界线层型候选剖面上，对中，下寒武统界线剖面沉积岩地球化学特征进行了研究，发现沉积岩中的微量元素含量和稀土元素分布模式沿剖面的变化均具有规律性，元素反映的沉积环境也具有类似特点，剖面微量元素及稀土元素地球化学特征在界线剖面12－13层之间变化明显，突变点主要分布在这两层样品中，因此，将八郎界线剖面上中，下寒武统界线置于剖面12－13层之间。