碳黑预处理对Pt/C催化剂对甲醇氧化电催化活性的影响

直接甲醇燃料电池(DMFC)由于具有较多的优点而受到广泛的关注.但是碳载Pt(Pt/C)阳极催化剂电催化活性低是限制其应用的一个主要问题.为了提高Pt/C催化剂对甲醇氧化的电催化性能,分别用CO2,空气,H2O2或HNO3对常用作为载体的VulcanXC-72碳黑进行预处理.结果表明,在用CO2,空气,HNO3,H2O2处理的及未处理的碳黑作载体制得的Pt/C催化剂电极上,甲醇氧化峰的峰电流密度顺序为39,33,32,20和18mA?cm-2,表明用CO2处理的碳载体制备的Pt/C催化剂对甲醇氧化有最好的电催化活性和稳定性.其主要原因是用CO2处理能减少碳黑表面的含氧基团和增加石墨化程度,而使碳黑的电阻降低及Pt粒子在碳黑上的分散性变好.

Dynamic mechanical and thermal properties of plasticized poly(lactic acid)

The blends of low molecular weight triacetin (TAC) and oligomeric poly(1,3-butylene glycol adipate) (PBGA) were used as multiple plasticizers to lubricate poly(lactic acid) (PLA) in this study. The thermal and mechanical properties of plasticized polymers were investigated by means of dynamic mechanical analysis and differential scanning calorimetry. Atomic force microscopy (AFM) was used to analyze the morphologies of the blends. Multiple plasticizers were effective in lowering the glass transition temperature (T-g) and the melting temperature (T-m) of PLA. Moreover, crystallinity of PLA increased with increasing the con-tent of multiple plasticizers. Tensile strength of the blends decreased following the increasing of the plasticizers, but increased in elongation at break. AFM topographic images showed that the multiple plasticizers dispersed between interfibrillar regions. Moreover, the fibrillar crystallite formed the quasicrosslinkings, which is another cause for the increase in elongation at break.

Luminescence properties of rare-earth (Eu3+ and Tb3+) complexes with paraaminobenzoic acid and 1,10-phenanthroline incorporated into a silica matrix by sol-gel method

Ternary complexes of europium and terbium with paraaminobenzoic acid and 1,10-phenanthroline (Eu(p-ABA)(3). phen . 2H(2)O and Tb(p-ABA)(3). phen . 2H(2)O, where p-HABA = paraaminobenzoic acid and phen = 1,10-phenanthroline) were introduced into a silica matrix by sol-gel method. The luminescence behavior of the complexes in silica gels was studied in comparison with the. corresponding solid-state complexes by means of emission, excitation spectra, and Lifetimes. Within the range of effective dopant concentrations, the luminescence intensities of rare-earth complexes in silica gel increase with the increasing of their dopant concentration. The lifetimes of rare-earth ions (Eu3+ and-Tb3+) in silica gel doped with europium and terbium complexes become longer than those in pure complexes. Very small amounts of rare-earth complexes doped in silica gel matrix can exhibit excellent luminescence properties, (C) 1998 Elsevier Science Ltd.

规范化管理高科技高效益企业

规范化管理高科技高效益企业中国科学院成都生物研究所王海燕中共成都市委组织部张松中科院成都生物研究所于１９８８年开始创办药厂，药厂产值六年翻了六番，原始投资增值数百倍。如今，药厂已更名为地奥制药公司，成为拥有净资产２亿多元、年利税１亿元的集高科技、新产...

The characteristics of BSRs and their derived heat flow on the profile 973 in the northeastern South China Sea

Processing of a recently acquired seismic line in the northeastern South China Sea by Project 973 has been conducted to study the character and the distribution of gas hydrate Bottom-Simulating Reflectors (BSRs) in the Hengchun ridge. Analysis of different-type seismic profiles shows that the distribution of BSRs can be revealed to some extents by single-channel profile in this area, but seismic data processing plays an important role to resolve the full distribution of BSRs in this area. BSR' s in the northeastern South China Sea have the typical characteristics of BSRs on worldwide continental margins: they cross sediment bed reflections, they are generally parallel to the seafloor and the associated reflections have strong amplitude and a negative polarity. The characteristics of BSRs in this area are obvious and the BSRs indicate the occurrence of gas hydrate-bearing sediments in the northeastern South China Sea. The depth of the base of the gas-hydrate stability zone was calculated using the phase stability boundary curve of methane hydrate and gas hydrate with mixture gas composition and compared with the observed BSR depth. If a single gradient geothermal curve is used for the calculation, the base of the stability zone for methane hydrate or gas hydrate with a gas mixture composition does not correspond to the depth of the BSRs observed along the whole seismic profile. The geothermal gradient therefore changes significantly along the profile. The geothermal gradient and heat flow were estimated from the BSR data and the calculations show that the geothermal gradient and heat flow decrease from west to east, with the increase of the distance from the trench and the decrease of the distance to the island arc. The calculated 2 heat flow changes from 28 to 64 mW/m(2), which is basically consistent with the measured heat flow in southwestern offshore Taiwan.

柔性机械臂运动轨迹的鲁棒自适应控制

本文针对多连杆柔性机械臂的运动轨迹控制问题，讨论了动力学建模、控制系统结构设计以及鲁棒自适应控制算法，运用假设模态方法得到了柔性机械臂动力学近似方程，通过对柔性机械臂动力学特性分析，建立了等价动力学模型，依此提出了一种鲁棒自适应控制算法，并给出了仿真研究结果。

柔性制造系统中死锁避免的充要条件第二部分：资源的动态分配规则

本文根据在第一部分中推导出来的描述资源竞争的着色ＲＯＰＮ给出在柔性制造系统中无死锁运行的充分必要条件，从而得出相应的控制规律。它是一种资源动态分配的策略，它决定当一个资源空闲时，是否可以分配给一个任务，可以的话先分配给谁，以保证系统无死锁，并使得资源利用率最大。

水水环境中腐殖质—金属离子键合作用研究进展

腐殖质(主要指腐殖酸和富里酸)普遍存在于各种水体中，它对金属离子的形态、迁移转化、生物可利用性等地球化学行为起着重要作用。本文概述了水环境中腐殖质的一些基本性质，以及腐殖质一金属离子之间的键合作用机理、研究方法和影响因素。并且对各种金属离子键合到腐殖质上的现代物理化学模型，尤其对Model Ⅵ及NICA—Donnan模型进行了简要回顾和评述。它们在许多条件下模拟腐殖质—金属离子键合作用可以得到令人欣喜的结果。还简述了腐殖质对水环境中金属离子各种水环境地球化学行为的影响。但是，若要更深入了解和阐述金属离子在水环境中的各种行为，还需考虑腐殖质与颗粒物质、胶体物质以及微生物等的相互作用。

全新世青藏高原东部西南季风的演变

本研究报道一组新的西南季风代用指标,即泥炭中单一种属植物-木里苔草残体纤维素和泥炭混合植物残体纤维素的δ13C 时间序列,所记录的青藏高原东部全新世气候变化。两记录表明,该区全新世的下限年龄约11 200 aBP (14C 年龄约9 900 aBP) ;从约11 200 aBP 起该区迅速进入湿暖的全新世阶段,季风活动迅速增强;在约10800～5 500 aBP 期间,季风总体保持在强盛状态,但其间有4 次突然减弱,气候变干冷;约从5 500 aBP 起季风活动在波动中逐渐减弱,其中有4 次减弱最明显。所有这8 次气候的突然变化都与北大西洋浮冰事件一一对应。这种密切的相关关系表明,西南季风强度的波动可能是对全球变化,特别是对海洋热盐环流引起的地球南北方气候波动的所谓“跷跷板效应”的响应。