模拟酸雨对荔枝果园土壤磷素等温吸附与解吸特性的影响

采用等温吸附试验方法研究了模拟酸雨对荔枝果园土壤磷的吸附与解吸特性的影响。试验结果表明,不同处理间土壤对磷的最大吸附量(Xm)为pH2.5>pH4.5>CK=pH6.5,其中pH2.5的酸雨淋溶处理对磷的最大吸附量(Xm)与其它处理间差异显著;土壤吸附磷的解吸量(Xd)分别与相应的吸附量(X)和原平衡溶液浓度(C)呈显著的指数相关和线性相关,随着土壤对吸附量的增加,土壤磷的解吸量呈指数增长。

The Study of Electroactive Block Copolymer Containing Aniline Pentamer Isolated from Different Solvents

For the films and powder of polymers containing conductive oligomer are usually obtained from solution, the choice of better solvents for the regular arrangement of oligomers is very important for the higher conductivity. Because of the poor solubility of the oligomers, it is difficult to study the arrangement directly in most common solvents, so, we synthesized a triblock copolymer, mPEG2k-aniline pentamer-mPEG2k, as the model to investigate the arrangement-solvent relationship. For the poor solubility of the AP block in common solvents, the copolymer self-assembled into spheric micelles in toluene and into lamellar crystals in water and THF. The crystallinity (X-c) and crystallization temperature (T-c) values of mPEG blocks in powders prepared from different solvents differed obviously, which may be the effect of different self-assembled structures. From the two-phase model of one-dimensional electron density correlation function of SAXS, the long period of copolymer prepared from THF was presumably equal to the long period of pure mPEG plus the chain length of AP, which demonstrates that the AP blocks arrange regularly in the noncrystalline regions.

Conformational and orientational analyses of 2,2 '-bithiophene under interaction of external electric field constructed by point charges

The fully relaxed single-bond torsional potentials and orientation-related rotational potentials of 2,2'-bithiophene (BT) under the interaction of an external electric field (EF) constructed by point charges have been evaluated with semi-empirical AMI and PM3 calculations. The torsional potentials are sensitive to both EF strength and direction. While the EF is parallel to the molecular long axis, the torsional barrier around C-x-C-x' bond obviously rises with increasing the EF strength, whereas the relative energies of syn and anti minima show a slight change. The interaction between the EF and the induced dipole moment has been proposed to elucidate this observation. On the other hand, the relative energy difference between the syn and anti minima shows an obvious change, while the EF is perpendicular to the molecular long axis. This feature has been ascribed to the interaction between the EF and the permanent dipole moment of BT. Furthermore, conformational and orientational analyses in two dimensions have been carried out by changing the torsional and rotational angles in the different EF. The conformation and orientation of a gas-phase BT in the EF are governed by both the above factors.

MOLECULAR CHARACTERISTICS AND CRYSTALLINE-STRUCTURE OF ETHYLENE-DIMETHYLAMINOETHYL-METHACRYLATE COPOLYMERS

The relationship between molecular and crystalline structural characteristics of the ethylene -dimethylaminoethylmethacrylate copolymers (EDAM) was investigated and related to melt flow index MI and average gross content of DAM comonomer, in comparison with low density polyethylene (LDPE) produced by the common high-pressure radical polymerization process. Although the average molecular weight and its distribution are influenced predominantly by the polymerization conditions, DAM-content seems not to depend significantly on molecular weight according to the GPC-FT/IR measurement. Comonomer sequence distributions were determined quantitatively with the C-13-NMR spectra entirely assigned by DEPT and H-1-C-13 COSY techniques. The result suggests the alternating copolymerization tendency and surprisingly coincides with the simulation out-puts based on the assumption of continuous complete mixing reactor model, using Mayo-Lewis equation and the same Q-e values as previously reported on different types of copolymers such as EVA and St.DAM (VA;vinylacetate, St;styrene). It was confirmed by WAXD and SAXS analyses that the crystallinity X(c) and the thickness of lamellar crystal l(c) decreased with increasing DAM-content, whereas the a-lattice and b-lattice dimensions enlarged. X(c) and l(c) can definitely be correlated to the heats of fusion and crystallization measured by DSC. The average size of spherulites measured with light scattering photometry tends to be enlarged with decreasing molecular weight (increasing MI) and DAM-content.

乙烯基三甲基硅烷与苯、苯乙烯及六氟丙烯等离子体共聚物的结构表征

采用外部电极电容耦合的RF辉光放电装置研究了乙烯基三甲基硅烷(VTMS)与苯(Bz)、苯乙烯(St)以及六氟丙烯(HFP)的等离子体共聚合。用IR、ESCA、PGC/MS和X射线对聚合物结构进行表征,证明乙烯基三甲基硅烷与苯、苯乙烯以及六氟丙烯可进行共聚合。C/Si比的增加表明苯、苯乙烯和六氟丙烯的嵌入导致聚合物组成的变化,Si含量相对较低。共聚物中无Si-H键的形成。

干涉合成孔径雷达海浪遥感理论与应用研究

干涉合成孔径雷达 (Interferometric Synthetic Aperture Radar，InSAR) 是以合成孔径雷达复数据提取的相位为信息源获取地表三维信息和海表散射体运动信息的新型微波成像雷达。 InSAR通过两幅天线同时观测 (单轨模式)，或两次近平行的观测 (重复轨道模式)，获取地面或海面同一景观的复图像对。20世纪90年代以来，InSAR陆地和海洋研究成为微波遥感的热点，广泛应用于地表变形监测、南极冰流测量、地面或海面慢速运动目标检测等领域。 近年来，国际上逐渐应用机载顺轨或交轨干涉合成孔径雷达进行海表面流速测量以及海面波成像机制研究。相对于传统单天线合成孔径雷达 (Synthetic Aperture Radar, SAR)，双天线干涉合成孔径雷达 (InSAR) 测量海表面波有着独特的优势： (1) InSAR复图像的相位近似正比于海面散射体的径向速度，这种内在的成像机制提供了直接测量海表面动态运动的机会。 (2) 真实孔径雷达调制传递函数几乎对InSAR相位图像没有影响，而对传统SAR图像影响较大。 基于干涉合成孔径雷达测量海浪的优势，本文做了一些干涉合成孔径雷达海浪遥感理论与应用研究工作，主要内容大致可归纳如下： (1)基于新建立的顺轨干涉合成孔径雷达 (Along-Track Interferometric Synthetic Aperture Radar，ATI-SAR) 相位谱与海浪谱之间的非线性映射关系，通过数值模拟研究了不同雷达参数和海况参数对应的ATI-SAR相位谱。数值模拟结果表明：距离速度比率、雷达入射角、天线间距和有效波高和波长比率是影响ATI-SAR海浪成像的重要因素。进一步，利用机载X波段水平极化相位图像和机载C���段水平极化相位图像谱结合方向波骑士浮标测量的海浪方向谱验证了ATI-SAR相位谱与海浪谱之间的非线性映射关系。结果显示用前向映射关系计算的相位谱与实际观测的相位谱较为一致，二者相关系数总体大于0.6，而且对成像非线性不敏感. (2)建立了包含海表面高度和速度聚束的交轨干涉合成孔径雷达 (Across-Track Interferometric Synthetic Aperture Radar，XTI-SAR) 涌浪干涉相位模型，得到了涌浪成像的解析表达式，进一步研究了XTI-SAR沿方位向传播的涌浪成像机制。定义二次谐波振幅与基波振幅比率来表征成像非线性，通过比较XTI-SAR和ATI-SAR相位的二阶调和分量，分析不同海况和干涉SAR参数情况下的数值模拟，结果表明：当速度聚束弱时，XTI-SAR相位比ATI-SAR相位具有较强的非线性，ATI-SAR比XTI-SAR更适合测量海浪。当速度聚束强时，XTI-SAR相位比ATI-SAR相位具有较弱的非线性，XTI-SAR比ATI-SAR更适合测量海浪。 (3)基于包含海表面高度和速度聚束的交轨干涉合成孔径雷达 (XTI-SAR) 涌浪干涉相位模型，结合多维高斯变量的特征函数方法建立了新的XTI-SAR相位谱与海浪谱非线性积分变换。新积分变换不同于Bao (1999) 建立的积分变换，两者形式上区别在于新积分变换中包含了长波径向轨道速度一阶倒数项。数值模拟显示：通常情况下，长波径向轨道速度一阶倒数项不能忽略。进一步，我们针对不同雷达参数和海况结合新非线积分变换对XTI-SAR海浪成像进行了数值模拟，结果表明：同顺轨干涉合成孔径雷达 (ATI-SAR) 海浪成像一致，距离速度比率 和有效波高与波长比率 是影响XTI-SAR海浪成像的重要因子。 (4)基于新的ATI-SAR相位谱与海浪谱之间的非线性映射关系，发展了利用ATI-SAR相位图像反演海浪方向谱的参数化反演模式，并由此得到海浪波长、波向和有效波高。反演结果与现场浮标观测结果比较一致。相对于其它反演模式，参数化反演模式的优点在于：(1) 不需要任何附加信息如初猜海浪谱、散射计提供的风速风向等信息。 (2) 不需要对相位图像进行辐射定标，可以由反演的海浪谱直接计算有效波高。(3) 反演结束后还可以得到成像区域的局地风速信息。因此，参数化反演模式可以实现风、浪信息的联合反演。

土壤中碳水化合物的分布特征与环境意义

本文选择了贵州喀斯森土壤，对土壤中的碳水化合物从分析测试、分布特征及其环境意义等方面进行了初步的研究，并结合了有机碳、元素氮对碳水化合物作为有机质进期变化的指示剂的可行性进了探讨。碳水化合物与有机碳、总氮之间存在着明显的相关性，而M／X比值却与前两者成反相关。在耕作土壤中，碳水化合物、有机碳、总氮均明显减少。并且由于缺乏绿肥回田，使耕作土壤中，C���N比值下降，M／X比值上升，用糖／有机碳比C���N比值更能反映有机质的生物有效性和成熟度。因此我们认为碳水化合物不仅能灵敏指示有机碳的变化，同样了能反映总氮的变化。

Characterization of aluminosilicate zeolites by UV Raman spectroscopy

A series of aluminosilicate zeolites are characterized by UV Raman spectroscopy for the first time, and UV Raman spectra of various zeolites give strong and clear bands with high resolution, while conventional Raman spectra of these zeolites are difficult to obtain because of a strong background fluorescence. Additionally, these zeolites show several new bands in UV Raman spectroscopy. A summary of these UV Raman spectra over various zeolites suggests that the bands at 470-530, 370-430, 290-410, and 220-280 cm(-1) can be assigned to the bending modes of 4-, 5-, 6-, and 8-membered rings of aluminosilicate zeolites, respectively. Furthermore, it is found that the band intensity of zeolites in UV Raman spectroscopy is dependent on the Si/Al ratio. Moreover, the UV Raman spectra of crystallization, for zeolite X at various times show that, in the initial stage of crystallization, the 4-membered rings (510 cm(-1)) interconnect each other to form beta -cages with 6-membered rings (390 cm(-1)), which further crystallize to zeolite X. (C) 2001 Elsevier Science B.V. All rights reserved.