Synthesis of novel cyclic aryl ether thioether ketone (Sulfone) oligomers

Two kinds of macrocyclic oligomers containing aromatic sulfide linkages have been synthesized by the solution polycondensation in high yield. The cyclic compounds were characterized by H-1 and C-13 NMR, by and MALDI - TOF MS.

Synthesis of cyclic aryl ether sulfone oligomers through interfacial polycondensation method

Novel cyclic aryl ether sulfone oligomers have been synthesized in high yield based on bisphenol A and 4-fluoro-3-nitrophenyl sulfone firstly through interfacial polycondensation reaction under a pseudo-high-dilution condition. Detailed structural characterization of the oligomers by MS, GPC, NMR and IR analyses confirmed the cyclic nature.

Use of lanthanide metal complexes for the hydrolysis of 3 ',5 '- and 2 ',3 ' cyclic nucleotides

Lutetium(III) and lanthanum(III) complexes of 2-carboxyethylgermanium sesquioxide (Ge-132) can hydrolyze the phosphodiester linkage of 3',5'-cyclic adenosine monophosphate (cAMP), 3',5'-cyclic deoxyadenosine monophosphate (dcAMP) and 2',3'-cyclic adenosine monophosphate (2',3'-cAMP). Both cAMP and dcAMP are hydrolyzed with high selectivity, yielding predominantly 3'-monophosphates. 2',3'-cAMP is converted to 3'-AMP and 2'-AMP, the ratio of 3'-AMP to 2'-AMP produced being 1.4.

Characterization of cyclic (aryletherketone)s by matrix-assisted laser desorption ionization time of flight mass spectrometry

Matrix-assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF MS) was used to identify cyclic(aryl ether ketone) oligomers, using 2,5-dihydroxybenzoic acid as a matrix, and Na+ and K+ as cationization agents, The existence of different ring-sized cyclic oligomers up to 9 and their distribution were determined and compared with GPC results, The results indicated that MALDI-TOF MS was a powerful and rapid analytical tool for the cyclic oligomers.

Cyclic voltammetry of dye-modified supported bilayer lipid membranes (s-BLMs)

The voltammetric behaviour of dye-modified supported bilayer lipid membranes is investigated. (C) 1997 Elsevier Science S.A.

Efficient synthesis and facile polymerization of some cyclic bisphenol o-phthalates

A series of new macrocyclic aromatic esters have been efficiently synthesized from o-phthaloyl dichloride and various bisphenols, and unambiguously characterized by a combination of GPC, MS(FAB), FTIR and NMR. These macrocyclic oligomers undergo facile ring-opening polymerization in the presence of anionic initiators to give high molecular weight polyarylates.

Lanthanide metal complexes for the hydrolysis of ribonucleoside 3',5'-cyclic phosphate and deoxyribonucleoside 3',5'-cyclic phosphate

Ytterbium(III) and praseodymium(III) complexes of 2-carboxyethylgermanium sesquioxide (Ge-132) can hydrolyze the phosphodiester linkage of 3',5'-cyclic adenosine monophosphate (cAMP) and 3',5'-cyclic deoxyadenosine monophosphate (dcAMP). Both cAMP and dcAMP are hydrolyzed with high selectivity, yielding predominantly 3'-monophosphates. The selectivity and activity for hydrolyzing cAMP and dcAMP by lanthanide metal(III) complexes and lanthanide metal ions are compared.

The chemistry of alpha-oxo ketene cyclic dithioacetal .36. Studies on silica G catalyzed decomposition of adducts of beta,beta-1,3-propylenedithio-alpha,beta-unsaturated arylketones with grignard reagents

beta, beta-1, 3-Piopylenedithio-alpha, beta-unsaturated arylketones 2 via chemoselective 1,2-addition with allyl or benzyl Grignard reagents afforded the corresponding carbinols 3 and 4. Catalysed by silica gel, the carbinols 3 and 4 were converted to the beta,gamma-unsaturated arylketones 5, 6. The mechanism and reaction condition were discussed.

Probe beam deflection combined with cyclic voltammetry studies of C-60-modified electrode film

C-60 films, prepared by solution casting, were studied by means of in situ probe beam deflection (PBD) combined with cyclic voltammetry (CV). PBD is a powerful technique for investigation of phenomena at the electrode/electrolyte interface in acetonitrile with quaternary ammonium and alkali metal salts as supporting electrolytes. In tetra-n-butylammonium (TBA(+)) salt solution, a stable CV can be obtained during the first two reduction/reoxidation waves. On reduction, injection of cations to maintain charge balance and dissolution of small amount of C-60(-) (TEA(+)) and/or C-60(2-) (TBA(+))(2) are detected. During the reoxidation process ejection of cations and injection of anions occur simultaneously, especially for the second reoxidation wave. In the case where TBABr is the supporting electrolyte, the accompanied behavior is more complicated than in TBABF(4), TBAClO(4), and TBAPF(6) solutions. A small pair of prewaves in CV are proposed due to oxidation/reduction of C-60 domains but not dissolution/redeposition of C-60 film. Extending the potential scan range to the third reduction wave, no apparent corresponding reoxidation wave is related to the third reduction wave, the electroactivity of the film disappears rapidly and dissolution of C-60 film is observed. In tetraethylammonium (TEA(+)) and NAClO(4) solutions, the electrochemistry of the C-60 films is unstable, and potential scans lead to dissolution of flaking of the film.

Efficient cleavage of ribonucleoside 3',5'-cyclic phosphates and deoxyribonucleoside 3',5'-cyclic phosphate by lanthanides

The cleavage of 3',5'-cAMP, 3',5'-cGMP and 3',5'-dcAMP by lanthanides has been investigated by HPLC and H-1 NMR. Rapid cleavage of cAMP, cGMP and dcAMP by Ce(III) under air at pH 8 and 37 degrees C has been observed. Regioselective cleavage of P-O(5') bond in cAMP, cGMP and dc;aMP tu give the corresponding 3'-AMP, 3'-GMP and 3'-dAMP by lanthanide chlorides has been achieved, and 3'-AMP and 3'-GMP are cleaved to adenosine(A) and guanosine(CT) more slowly, respectively, The notable difference in reactivity between Ce(III) and the other lanthanide ions under air has also been studied. The cleavage is enhanced with the increase in the molar fraction of Ce(IV). The fast cleavage of cAMP by Ce(III) under air at pH 8 is ascribed to the resultant Ce(IV) in the reaction mixture.

Isolation and X-ray crystallographic structure of cyclic tetramer based on bisphenol A and o-phthaloyl dichloride

The polycrystalline powder of the cyclic tetramer based on bisphenol A and o-phthaloyldichloride has been prepared by recrystallization from nitrobenzene and its crystal structure has been determined by Wide-Angle X-ray Diffraction (WAXD). The unit cell is orthorhombic and its dimensions a = 0.967 6 nm, b = 0.869 9 nm, c = 2.085 9 nm, Space group belongs to Pmmm, With two tetramers per unit cell,the crystal density is 1.36 g . cm(-3), Indices of crystal diffraction peaks are also detailed in the present work.

X-ray crystallographic structure of cyclic tetramer ester based on bisphenol-A and o-phthaloyldichloride

The polycrystalline powder of the cyclic tetramer ester based on bisphenol-A and o-phthaloyldichloride has been prepared by recrystallization from nitrobenzene and its crystal structure determined by wide-angle X-ray diffraction. The unit cell is orthorhombic and has dimensions a=0.967 nm, b=0.8699 nm, c = 2.0859 nm. With two tetramers per unit cell, the crystal density is 1.36 g cm(-3). Indices of crystal diffraction peaks are also detailed in the present work. Copyright (C) 1996 Elsevier Science Ltd.

CYCLIC VOLTAMMETRIC STUDY OF QUININE DERIVATIVES TRANSFER ACROSS THE WATER NITROBENZENE INTERFACE

Quinine derivatives, quinine hydrochloride and 8-hydroxyquinoline, transfer across the water/nitrobenzene interface was studied by cyclic voltammetry. The effect of solution acidity on the transfer behaviour was observed. Transfer mechanism was discussed

EFFECTS OF DOPANT AND SOLVENT ON THE PROPERTIES OF POLYPYRROLE - INVESTIGATIONS WITH CYCLIC VOLTAMMETRY AND ELECTROCHEMICALLY INSITU CONDUCTIVITY

A new method for electrochemically in situ conductivity measurements based on a reusable glassy carbon disc carbon fibre array double electrode is described. Using this technique and cyclic voltammetry, we have investigated the effects of the doping anion and solvent on the electrochemical properties of polypyrrole film. The electroactivity and potential dependent conductivity of polypyrrole film are strongly affected by solvent and the doping anion's solubility in the solvent, and also by the history of electrochemical treatments in different electrolyte solutions. It is very interesting that NO3-doped polypyrrole can completely keep its conducting state (doped state) at a reasonably negative potential (eg -0.8 V vs. sce) in acetonitrile solutions.