80 resultados para 502
Resumo:
空间生态规划着重于研究城乡土地和空间资源,达到城乡土地和空间资源合理配置。辽宁本溪市南芬区属山地资源型工矿城镇,由于空间用地类型配置不合理,中心城区环境污染严重,而广阔的乡村空间资源未尽其用。为此,有必要对南芬全区城乡空间进行生态规划,本文围绕生态优先、整体优化、经济优效和社会持续等方面探讨了南芬空间生态规划策略。
Resumo:
利用河南省气候中心编制的97个台站1961-2000年雷暴日数的资料,对该省境内雷暴发生的时空分布非均一性进行了分析。结果表明:全省平均雷暴日数有明显下降的趋势;雷暴日数站间偏度系数具有明显的年际变化特征,80%的年代表现为正偏;而其峰度系数则60%的年份为负值,且具有明显的年际变化特征。年平均雷暴日数及其均方差空间分布型态比较一致。豫北、豫西和豫东南分别出现3个雷暴高发区,其中豫东南强度最大,豫西强度与其相当,豫北相对较小。历年雷暴日数以正偏为主;峰度系数则以负值为主。河南省除信阳地区外,各站雷暴日数在0.05置信水平上服从正态分布。
Resumo:
提出了一套包括基础系统、协调系统与潜力系统在内的区域可持续发展评价体系,旨在以基础一过程一潜能为主线,资源、经济、社会、生态环境为基本要素单元,并结合外部介入因素对一个地区的可持续发展进行评价。利用这一指标体系,分析了世纪之交长江流域可持续发展的态势,并与沿海经济带及全国其它省区进行了比较。主要结论有:长江流域区域可持续发展总体水平不高,不符合其在国家经济开发中所处的地位;长江流域区域可持续发展状态的内部差异为流域开发带来困难与挑战,但优势互补的潜力也为实现流域资源综合开发与生态环境综合治理带来机遇。最后,针对以上存在的问题提出了建议与对策。
Resumo:
基于我国中部的样带基础上,采用陆面模式(CommonLandSurfaceModelCLM)和遥感结合技术,对研究的样带区域的地表温度利用CLM模式进行模拟和利用遥感分裂窗技术进行反演;以观测地表温度为真值,分别比较模拟地表温度和反演地表温度空间分布特征和误差大小,分析模拟方法和反演方法对计算地表温度的可适性和应用范围,为进行大面的地表温度计算提供选择和参考依据。通过研究发现,模式模拟地表温度同实测地表温度分布的大的格局吻合非常的好,但是因地貌类型及地表覆盖的影响,模拟地表温度对水域的模拟温度误差较大,大于3%以上,对耕地模拟误差偏小,在(-3)%以内,对裸地、草地和林地模拟温度吻合非常的好。反演地表温度同观测地表温度相差较大,分裂窗反演方法适合地表覆盖为草地和林地状态的地表温度的计算,裸露和农耕区域反演的地表温度误差特别的大。
Resumo:
The structure and electrochemical properties of TiV1.1Mn0.9Nix (x = 0.1-0.7) solid solution electrode alloys have been investigated. It is found that these alloys mainly consist of a solid solution phase with body centered cubic (bcc) structure and a C14 Laves secondary phase. The solid solution alloys show easy activation behavior, high temperature dischargeability, high discharge capacity and favorable high-rate dischargeability as a negative electrode material in Ni-MH battery. The maximum discharge capacity is 502 mAh g(-1) at 303 K when x = 0.4. Electrochemical impedance spectroscopy (EIS) test shows that the charge-transfer resistance at the surface of the alloy electrodes decreases obviously with increasing Ni content.
Resumo:
Two new light-emitting PPV-based copolymers bearing electron-withdrawing triazole unit in the main chain have been synthesized by Wittig reaction between triazole diphosphonium salt and the corresponding dialdehyde monomers, respectively. Their optical and physical properties are characterized by UV-vis, photoluminescence (PL), TGA and DSC. The resulting copolymers are highly soluble in common organic solvents and have high Tg and Td values. They show blue-greenish fluorescence in solution (lambda(max) 502 and 508 nm) and green fluorescence in the solid state (lambda(max) 520 and 526 nm), respectively.
Resumo:
A droplet of aqueous solution containing a certain molar ratio of redox couple is first attached onto a platinum electrode surface, then the resulting drop electrode is immersed into the organic solution containing very hydrophobic electrolyte. Combined with reference and counter electrodes, a classical three-electrode system has been constructed, Ion transfer (IT) and electron transfer (ET) are investigated systematically using three-electrode voltammetry. Potassium ion transfer and electron transfer between potassium ferricyanide in the aqueous phase and ferrocene in nitrobenzene are observed with potassium ferricyanide/potassium ferrocyanide as the redox couple. Meanwhile, the transfer reactions of lithium, sodium, potassium, proton and ammonium ions are obtained with ferric sulfate/ferrous sulfate as the redox couple. The formal transfer potentials and the standard Gibbs transfer energy of these ions are evaluated and consistent with the results obtained by a four-electrode system and other methods.
Resumo:
In this paper, we present a new method of fabricating metal nanoparticles on carbon substrates through molecular design. Scanning tunneling microscopy measurements show that the electrochemically synthesized Ag nanoparticles are homogeneously dispersed on the modified highly oriented pyrolytic graphite (HOPG) surface with a narrow particle size distribution. Moreover, the size and number density of Ag nanoparticles on the grafted HOPG surface can be easily changed through control of the experimental conditions. (C) 2001 Elsevier Science B.V. All rights reserved.
Resumo:
Through the reaction of Co-2(CO)(8) with four thiuram [R2NC(S)S](2), four new sulfur-capped trinuclear cobalt carbonyl clusters Co-3 (CO)(7) (mu(3)-S) (mu, eta(2)-S* C* NR2) ( I : R = Me; I : R = Et; II : R = i-Pr; IV : NR= -N [GRAPHICS] were prepared and characterized by elementary analysis, IR,H-1 NMR and MS spectroscopy. The crystal structure of the cluster Co-3(CO)(7)(mu(3)-S)[mu, eta(2)-S*C*N (i-Pr)(2)]( III) was determined by X-ray single crystal diffraction method. The crystal of m is monoclinic, belonging to space group P2(1)/n, and the cell parameters are as follows: a = 1, 145 2(2) nm, b = 1. 502 8(3) nm, c = 1, 214 4(2) nmj alpha = 90 degrees, beta = 92, 15(3)degrees, gamma = 90 degrees; V = 2. 088 5(7) nm(3) , Z = 4, F (000) = 1 096, D-c = 1. 747 mg . m(-3), mu = 2. 588 mm(-1), R=0. 040 7, R-w=0. 062 4, The structural analysis shows that cluster II has a pyrimidal Co3S framework and contains a heterocylic bridging bidentate ligand [mu, eta(2)-S* C* N (i-Pr)(2)] linked to the Co2 and Co3 atoms of the cluster by a cobalt-carbon and a cobalt-sulfur bond respectively.
Resumo:
Four typical LB monolayer film materials, Ru(phen)(3)(2+) complexes with one ligand attached to different long chain alkyl amides, were designed and synthesized. Their chemical structures were identified by the techniques of FT-IR, H-1 NMR and ESI-MS. Also, UV-Vis, electrochemistry and fluorescence of these complexes are reported.
Resumo:
采用1HNMR方法研究了镧离子对酵母tRNAPhe分子结构和构象变化的影响 .结果表明位于扩大二氢尿嘧啶螺旋 (D 螺旋 )的端梢三级碱基对 (G_15) (C_4 8)明显受加入La3+ 的影响 ,向低场位移 0 33;与三级相互作用相关 ,连接D 茎和接受茎起固定L结构转折的 (U_8) (A_14)碱基对向高场位移 0 2 0 ;另一可能受La3+影响的亚胺质子碱基对为 (G_19) (C_56 ) ,由于该碱基对位于高度叠加的 12 6和 12 2之间 ,其归属仅供参考 ,该碱基对有助于D 环对TΨC环的连接.
Resumo:
A series of macrocyclic arylate dimers have been selectively synthesized by an interfacial polycondensation of o-phthaloyldichloride with bisphenols. A combination of GPC, FAB-MS, H-1 and C-13 NMR unambiguously confirmed the cyclic nature. Although single-crystal X-ray analysis of two such macrocycles reveals no severe strain on the cyclic structures, these macrocycles can undergo facile melt polymerization to give high molecular weight polyarylates.
Resumo:
2,2'-Bis(3,4-dicarboxyphenoxy)-1,1'-binaphthyl dianhydride was used as a new monomer with various aromatic diamines to obtain polyimides by the usual two-step method. The bis(ether anhydride) was prepared by a nucleophilic substitution of I,1'-bi-2-naphthol with N-phenyl-4-chlorophthalimide, N-methyl-4-nitrophthalimide or 4-nitrophthalonitrile in aprotic polar solvent, and subsequent hydrolysis of the resulting bis(ether imide)s or bis(ether dinitrile), and then dehydration of the corresponding tetracarboxylic acid to afford the dianhydride. Most of the obtained polyimides were soluble in chloroform, pyridine, DMF, etc. The polyimide prepared from p-phenylene diamine was partial crystalline, whereas the others showed amorphous patterns in a WAXD study. These polymers have glass transition temperatures between 255-294 degrees C and 5% weight loss temperatures in the range of 502-541 degrees C in nitrogen and 473-537 degrees C in air. (C) 1997 Elsevier Science Ltd.