污泥构筑湿地——一种新型城市污泥处理技术

城市污泥的产量巨大且成分复杂,如何对城市污泥处置与利用已成为人们所关注的问题。通过对城市污泥的特性、国内外的常规处理技术现状进行综述,对污泥处理的一种新方法——污泥构筑湿地处理技术在国外的发展情况进行了全面分析,指出发展污泥构筑湿地处理技术在我国的迫切性和今后的研发重点。

污染生态学的研究前沿与展望

根据污染生态学国内外研究现状与发展趋势 ,对该领域的最新研究前沿进行了较为系统的分析和归纳。与此同时 ,从生态学发展战略的角度 ,对今后的研究重点进行了阐述。认为污染生态过程是污染生态学研究的中心议题 ,污染生态修复与污染生态工程是污染生态学应用研究的重点。通过研究 ,将会推动污染生态化学和污染生态毒理学等学科新的生长点和新的分支学科的形成和发展。

中国护蒴苔科Calypogiaceae的研究

对中国护蒴苔科Calypogiaceae进行了分类研究 .该科在我国有 2属 ,假护蒴苔属Metacalypogeia在我国有 2种 .护蒴苔属Calypogeia我国报道过 10种 ,本次研究仅见到 7种

近30年来青海三江源地区草地退化的时空特征

在20世纪70年代中后期MSS图像、90年代初期TM图像和2004年TM/ETM图像支持下,通过三期遥感影像的直接对比分析,获得了三江源地区草地退化空间数据集,并在此基础上分析了70年代以来青海三江源地区草地退化的主要时空特征。结果表明:三江源地区草地退化是一个在空间格局上影响范围大,在时间过程上持续时间长的连续变化过程。研究发现,三江源草地退化的格局在70年代中后期已基本形成,70年代中后期至今,草地的退化过程一直在继续发生,总体上不存在90年代至今的草地退化急剧加强现象。草地退化的过程在不同区域和地带有明显不同的表现,如在湿润半湿润地带的草甸类草地上,发生着草地破碎化先导,随后发生覆盖度持续降低,最后形成黑土滩的退化过程;在干旱、半干旱地带的草原类草地上,发生着覆盖度持续降低,最后形成沙地和荒漠化草地的退化过程。三江源地区草地退化具有明显的区域差异,草地退化可以分为7个区,各区草地退化在类型、程度、范围与时间过程方面具有明显不同的特点。

30年来青海三江源生态系统格局和空间结构动态变化

在多期遥感图像支持下,通过对生态系统类型进行辨识,获得了三江源地区生态系统类型空间分布数据集,并在此基础上分析了20世纪70年代中后期以来青海三江源地区生态系统格局和空间结构的动态变化。结果表明:30年来三江源地区生态系统格局稳定少动,生态系统类型变化相对缓慢,农田、森林、草地、水体与湿地和荒漠生态系统的年变化速率均小于0.5%,是长江、黄河流域乃至全国各区域生态系统转类变幅最小的稳定少动区。20世纪70年代中后期以来三江源地区生态系统类型的转变主要发生在草地和水体与湿地生态系统上,草地生态系统的变化主要发生在中部和东部地区,水体与湿地生态系统的变化主要发生在广大西部和北部地区。

近30年来长江源头高寒草地生态系统退化的遥感分析:以青海省治多县为例

为了对长江源头高寒草地退化的时空过程规律取得全面客观的科学认识,本文利用20世纪70年代末、90年代初和2004年的陆地卫星遥感影像为信息源,结合气象数据、DEM、草地分布图及社会统计数据等辅助资料,以青海省治多县为例分析了近30年来长江源头的高寒草地生态系统退化的时空格局与过程及其驱动因素,从新的视角阐释高寒草地退化的过程与机理,为退化高寒草地的恢复、治理与区域可持续发展提供了科学依据。结果表明,研究区高寒草地生态系统的退化呈现自东南向西北,退化面积减少、退化程度降低、退化类型由复合型向单一型过渡的总体趋势。研究区东部是草地退化最严重的区域,主要表现为沿着原退化草地斑块的扩张,而西部即唐古拉山以北的广大地区由于下垫面起伏较低则以草地覆盖度的轻度下降退化为主。草地退化时间过程特征的总体趋势是持续退化、后期加剧,前后两个时段对比可以看出草地退化比重和程度皆呈逐渐加剧的趋势,退化面积比重净增9.86%。地形因素的影响分析亦发现,研究区高寒草地退化主要发生在海拔4500～4900m、坡度5～15°范围内的阴坡。研究区草地退化格局在20世纪70年代以前就已经形成,气候变化对高寒草地退化的影响是长期、缓慢的,而研究区人口和家畜数量变化的分析可以得出人类活动特别是过度放牧是草地退化发生的最重要诱因。

近30年来中国气候湿润程度变化的空间差异及其对生态系统脆弱性的影响

论文利用近30a中国756个气象站点日观测数据计算中国陆地表层潜在蒸散和湿润指数现状及变化趋势,然后划分湿润程度变化对不同自然地带生态系统脆弱性影响的等级,并应用于农田、林地和草地三大生态系统脆弱性变化分析,结果显示:近30a中国陆地表层平均年潜在蒸散为754mm,平均湿润指数为-5.6,湿润指数平均变化率为-4.4/10a,反映中国陆地表层湿润程度总体具有下降趋势。近30a中国陆地表层气候湿润程度变化导致生态系统脆弱性增加的面积约占中国陆地面积的43.7%,主要集中在东北地区西南部、华北地区、西北地区东部,以及青藏高原的西部、北部和东部。总体上,近30a中国陆地表层气候湿润程度变化对农田、林地和草地生态系统脆弱性具有不利影响。其中草地生态系统脆弱性增加的面积最大,约占草地生态系统总面积的63.2%;其次为农田生态系统,约占31.6%;林地生态系统脆弱性受影响面积最小,约占17.7%。

The characteristics of land cover and macroscopical ecology changes in the source region of three rivers in Qinghai-Tibet plateau during last 30 years

We obtained four phases of land cover spatial data sets by interpreting MSS images of middle and late 1970s and three phases of TM images of late 1980s, 2004 and 2008 based on field investigation in Three Rivers' Source Region. We analyzed the temporal and spatial characteristics of land cover and macro ecological changes in Three Rivers' Source Region in Qinghai-Tibet plateau since middle and late 1970s. Indicated by land cover condition index change rate and land cover change index, land cover and macroscopical ecological condition degenerated (7090 period Zc -0.63, LCCI -0.58)-obviously degenerated (9004 period, Zc -0.94, LCCI -1.76)-slightly meliorated (0408 period, Zc 0.06, LCCI 0.33). This course was jointly driven by climate change, grassland stocking pressure and implement of ecological construction project.

Structure and electrochemical characteristics of melted composite Ti0.10Zr0.15V0.35Cr0.10Ni0.30-LaNi5 hydrogen storage alloys

The structure and electrochemical characteristics of melted composite Ti0.10Zr0.15V0.35Cr0.10Ni0.30+x% LaNi5 (x=0, 1, 5 and 10) hydrogen storage alloys have been investigated systematically. XRD shows that the matrix phase structure of V-based solid solution phase with a BCC structure and C14 Laves phase with hexagonal structure is not changed after adding LaNi5 alloy. However, the amount of the secondary phase increases with increasing LaNi5 content. Field emission scanning electron microscopy-energy dispersive spectroscopy (FESEM-EDS) shows that the C14 Laves phase contains more Zr and the white lard phase has a composition close to (Zr, Ti)(V, Cr, Ni, La)(2).

Effect of La-Mg-based alloy addition on structure and electrochemical characteristics of Ti0.10Zr0.15V0.35Cr0.10Ni0.30 hydrogen storage alloy

Effect of La-Mg-based alloy (AB(5)) addition on Structure and electrochemical characteristics of Ti0.10Zr0.15V0.35Cr0.10Ni0.30 hydrogen storage alloy has been investigated systematically. XRD shows that the matrix phase structure is not changed after adding AB(5) alloy, however, the amount of the secondary phase increases with increasing AB(5) alloy content. The electrochemical measurements show that the plateau pressure Ti0.10Zr0.15V0.35Cr0.10Ni0.30 + x% La0.85Mg0.25Ni4.5Co0.35Al0.15 (X = 0, 1, 5, 10, 20) hydrogen storage alloys increase with increasing x, and the width of the pressure plateau first increases when x increases from 0 to 5 and then decreases as x increases further, and the maximum discharge capacity changes in the same trend.

Effect of AB(5) alloy on Ti0.10Zr0.15V0.35Cr0.10Ni0.30 hydrogen storage alloy

The structure and electrochemical characteristics of melted composite Ti0.10Zr0.15V0.35Cr0.10Ni0.30 + x% LaNi4Al0.4Mn0.3Co0.3 (x = 0, 1, 5) hydrogen storage alloys have been investigated systematically. XRD shows that though the main phase of the matrix alloy remains unchanged after LaNi4Al0.4Mn0.3Co0.3 alloy is added, a new specimen is formed. The amount of the new specimen increases with increasing x. SEM-EDS analysis indicates that the V-based solid solution phase is mainly composed of V, Cr and Ni; C14 Laves phase is mainly composed of Ni, Zr and V; the new specimen containing La is mainly composed of Zr, V and Ni. The electrochemical measurements suggest that the activation performance, the low temperature discharge ability, the high rate discharge ability and the cyclic stability of composite alloy electrodes increase greatly with the growth of x.

Electrochemical properties of Ti0.17Zr0.08V0.35Cr0.10Ni0.30 alloy electrode

The electrochemical properties of the Ti0.17Zr0.08V0.35Cr0.10Ni0.30 alloy electrode were investigated. This alloy has good cycle life at 303 K, 313 K, and even at 323 K, but the discharge capacity decreases gradually at 333 K with increasing cycle number. Both the charge-discharge efficiency and the charge-discharge voltage reduce. The electrochemical impendence spectra indicate that the charge-transfer resistance decreases while the exchange current density increases as temperature increases. The apparent activation energy of the charge-transfer reaction is about 50 kJ mol(-1), which is higher than that on the AB(5) type alloy electrode.

Phase transition and transition kinetics of a thermotropic poly(amide-imide) derived from 70% pyromellitic dianhydride, 30% terephthaloyl chloride, and 1,3-bis[4-(4 '-aminophenoxy)cumyl]benzene

The phase transition and transition kinetics of a liquid crystalline copoly(amide-imide) (PAI37), which was synthesized from 70 mol% pyromellitic dianhydride, 30 mol% terephthaloyl chloride, and 1,3-bis[4-(4'-aminophenoxy)cumyl]benzene, was characterized by differential scanning calorimetry, polarized light microscopy, X-ray diffraction, and rheology. PAI37 exhibits a glass transition temperature at 182 degreesC followed by multiple phase transitions. The crystalline phase starts to melt at similar to 220 degreesC and forms smectic C (S-C) phase. The Sc phase transforms into smectic A (S-A) phase when the temperature is above 237 degreesC. The S-C to S-A transition spans a broad temperature range in which the S-A phase vanishes and forms isotropic melt. The WARD fiber pattern of PAI37 pulled from the anisotropic melt revealed an anomalous chain orientation, which was characterized by its layer normal perpendicular to the fiber direction. The transition kinetics for the mesophase and crystalline phase formation was also studied.

聚醚酰亚胺（YS－30）链结构的1D和2DNMR谱分析

聚醚酰亚胺（ＹＳ－３０）是一种可溶性的聚酰亚胺，本文对它的￣（１３）ＣＮＭＲ谱，￣１ＮＮＭＲ谱和ＣＯＳＹ谱进行了研究．经过分析，对￣（１３）ＣＮＭＲ和￣１ＨＮＭＲ谱作出了归属，确认了聚醚酰亚胺的链结构．