超临界压力下航空煤油流动与传热特性试验

本文针对超燃冲压发动机再生冷却系统运行条件,实验研究了大庆RP-3煤油在超临界压力下的流动和传热特性,目的在于研究煤油在各种工况下的流动参数变化以及对流传热规律. 煤油通过二级煤油加热/输运系统加热,试验的煤油压力约2.6M~5.0MPa,油温约300~800 K. 相应的壁面热流密度为10~300 kW/m2. 通过油温与壁温的同步测量,结合非定常传热分析,获得了超临界压力下、亚/超临界温度范围内煤油的流动和传热物理参量的变化曲线

超临界压力下航空煤油圆管流动和传热的数值研究

对超临界压力下大庆RP-3航空煤油在小管道内的流动、传热过程进行了数值研究. 湍流模拟采用了 RNG k-ε两方程模型和Wolfstein一方程模型结合的两层模型;同时, 采用煤油的10组分替代模型以及NIST Supertrapp程序库对大庆3号航空煤油的热物理和输运特性进行了确定. 圆管传热的计算条件为:入口压力4 MPa, 入口温度300 K, 质量流量范围:0.06~0.12 kg/s, 壁面热流密度范围:300~700 kW/m~2. 计算结果显示, 煤油的流动和传热特性比水、二氧化碳等简单化合物复杂得多. 在超临界压力下, 煤油的吸热升温导致其热物理特性以及流动特性均发生剧烈变化, 其中, 雷诺数沿管道方向上升了至少一个量级, 而普朗特数下降了一个量级. 在加热开始段, 煤油的对流传热系数迅速上升;当壁面温度超过其拟临界温度后, 对流传热系数略有所回落;随着煤油温度的进一步上升, 传热系数又得到明显增强. 计算表明, 煤油对流换热特性的变化与煤油复杂的高温热物理特性以及湍流流动在近壁区的增强和抑止有关

Extraction and separation of yttrium from the rare earths with sec-octylphenoxy acetic acid in chloride media

Extraction and separation of yttrium from the rare earths in chloride medium using sec-octylphenoxy acetic acid (CA-12), tri-n-butyl phosphate (TBP) as modifier, in kerosene has been investigated. The separation coefficients, beta, were obtained and the extraction selectivity has been enhanced when compared with that of naphthenic acid. The experimental results indicated that CA-12-TBP system could be employed to separate yttrium, from rare earths. Fractional extraction (15 stages for extraction and 10 stages for scrubbing) was studied, the raffinate of the first stage was abundant in purity yttrium of 99.5%, with a yield of > 95%, percentage of yttrium in the mixture rare earths was less than 5% in the loaded organic phase of the 25th stage and loaded capability was about 0.2 mol/L.

Interfacial activity of sec-nonylphenoxy acetic acid and kinetics of yttrium extraction

The interfacial behavior of sec-nonylphenoxy acetic acid (CA-100) at various diluents/(H, Na)Cl interfaces was examined using the Du Nouy ring method. Different adsorption isotherms such as the Gibbs and Szyszkowski were in good agreement with the experimental data. The values of interfacial excess at saturated interface increase in the following order: n-heptane > kerosene > cyclohexane > CCl4 > toluene > benzene > chloroform. The effects of temperature, acidity, and ionic strength of the aqueous phase on the interfacial activity of CA- 100 were also examined. The interfacial-activity data were used to discuss the mechanism and kinetics of yttrium (Y) extraction.

Study on transfer and interfacial kinetics of neodymium and samarium in membrane based extraction

Extraction and interfacial kinetics of Nd3+ and Sm3+ with HER/EHP-kerosene in a hollow fiber membrane extractor were studied. The results show that the extraction reactions in the hollow fiber membrane extractor are the same as those in the liquid-liquid extraction, which can be expressed as a quasi-first-order reaction. The effect of acidity in aqueous phase, concentrations of extractant, Nd3+ and Sm3+ on extraction rate were discussed and the corresponding reaction series were obtained. The reaction equations, reaction rate constants and the separation constant were obtained.

Studies on extraction and mass transfer of samarium and neodymium in hollow fiber membrane (HFM) with HEH/EHP

The membranes of polyvinylidene fluoride, which were synthesized by our laboratory, were used to study the transfer and extraction performances of Nd(III) and Sm(III) with the extraction system of HEH/EHP-kerosene. The results show that the membrane material was suitable to the study on membrane extraction, and could offer a good transfer performance in the membrane construction parameters selected, The extraction reaction in the membrane module was the same as that in liquid-liquid process, HEH/EHP ammoniated for increasing the mass transfer coefficient was almost the same with increasing the concentration of HEH/EHP, and H+ was still transferred first at higher pH range of feed solution when HEH/EHP was ammoniated, The controlling model of the membrane extraction process was the diffusion model accompanied by interfacial reaction, The controlling function of interfacial reaction would increase gradually with the increasing of the membrane pore size. The mass transfer coefficient increased when extraction and stripping were carried out simultaneously.

石油二次运移的物理与数值模拟实验及其应用

Facing the problems met in studies on predominant hydrocarbon migration pathways, experiments and numerical simulating were done in this thesis work to discuss the migration mechanisms. The aim is to analyze quantitatively the pathway pattern in basin scale and to estimate the hydrocarbon loss on the pathway that offer useful information for confirming the potential hydrocarbon accumulation. Based on our understandings on hydrocarbon migration and the fluid dynamic theory, a series of migration experiments were designed to observe the phenomena where kerosene is used as draining phase driven only by buoyancy force that expulses pore water. These experiments allow to study the formation of migration pathways, the distribution of non-wetting oil along these pathways, and the re-utilizing of previously existing pathways marked by residual traces etc. The types of pattern for migration pathways may be characterized by a phase diagram using two dimensionless numbers: the capillary number and the Bond number. The NMR technique is used to measure the average saturation of residual oil within the pathways. Based our experiment works and percolation concept, a numerical simulation model were proposed and realized. This model is therefore called as BP (Buoyancy Percolation) simulator, since buoyancy is taken as the main driving force in hydrocarbon migration. To make sure that BP model is applicable to simulate the process of oil secondary migration, the experimental phenomena are compared with those simulated with BP model by fractal method, and the result is positive. After then, we use BP simulator to simulate the process of migration of oil in the porous media saturated with water at different scale. And the results seem similar to those cited in literatures. In addition, our software is applied in Paris basin to predict the pathway of hydrocarbon migration happened in the Middle Jurassic reservoirs. It is found that the results obtained with our BP model are generally agree with Hindle (1997) and Bekeles'(1999), but our simulated migration pathway pattern and migration direction seem more reasonable than theirs.