长白山阔叶红松林采伐迹地土壤养分含量动态研究

采用对比实验 ,对不同采伐年限的长白山阔叶红松林采伐迹地土壤养分含量变化进行了分析与研究 .结果表明 ,不同采伐年限的采伐迹地土壤养分含量差异很大 .林地土壤 pH值随着伐后时间的推移而出现一个先下降后上升的过程 ,表层土壤在伐后 5年的酸性最强 ,10～ 2 0cm层土壤在伐后 10年酸性最强 ;土壤有机质含量、全量养分含量和速效养分含量均在采伐初期 2～ 5年增加 ,随后又迅速减少 ,尤其是表层土壤变化更为明显 ;土壤阳离子交换量 (CEC)及交换性Ca、Mg也都表现出相同的变化趋势 .因此 ,森林采伐后应及时人工造林、更新进行植被恢复 ,可将养分固定而减少和防止土壤养分的流失 .

管理措施对人工林土壤质量的影响

可持续性生产力是人工林发展的一个关键问题。然而,人工林培育过程中常出现土壤质量退化和人工林生产力下降等问题。管理措施是人工林发展过程中土壤质量变化的一个重要因素,正确的管理措施能够维护和提高林地的土壤质量。管理措施主要包括整地、施肥、林地收获与凋落物管理和营造混交林等。不同的整地方式、整地强度、整地时间等能改变土壤物理、化学和生物学性状,进而对其土壤质量产生一定的影响;施肥措施能改善土壤质量、提高人工林生产力,而过量施肥能够导致林地养分的流失和地下水质的恶化;木材收获和林地凋落物焚烧导致人工林系统养分的大量流失,加强对人工林系统有机物质的保护有利于林地土壤质量的改善;营造混交林在一定程度上有利于土壤质量维护,由于物种间存在复杂的相互关系,其对混交树种、混交方式和立地条件的选择等管理措施均能影响土壤质量。最后,文章对今后人工林管理措施对土壤质量影响的重点研究方向作了展望。

Mass resolved MPI spectra of methyl iodide in the 430-490 nm region

The mass resolved multiphoton ionization (MPI) spectra of methyl iodide were obtained in the 430-490 nm region using a time-of-flight (TOF) mass spectrometer. They have the same vibrational structure, which testifies that the fragment species, in the wavelength region under study, are from the photodissociation of multiphoton ionized molecular parent ions. Some features in the spectra are identified as three-photon excitations to 6p and 7s Rydberg states of methyl iodide. Two new vibrational structures of some Rydberg states are observed. The mechanism of ionization and dissociation is also discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

利用树木年轮宽度资料重建长白山地区240年来降水量的变化

根据长白山地区水曲柳年轮宽度资料,分析了树木年轮宽度与气候要素的关系,重建了1765年来该地区的降水变化。结果表明:长白山地区近240年降水波动明显,1850年以前降水波动幅度较大,1850—1900年波动比较平稳,并且降水量偏低,1900年以后降水的波动幅度明显增大,且湿润和干旱的持续时间增长,特别是1920年以后,降水波动剧烈;降水减少幅度最大的干旱期是1816—1820年,湿润期是1975—1979年;而1925—1936年和1947—1957年的2个干旱期在持续时间上最为显著。周期分析结果表明,长白山地区降水具有显著的2.64～3.03年、5.28～6.96年以及12.13～22.63年的周期。

植被与大气之间物质和能量交换过程的反演理论研究进展

介绍了研究植被与大气之间物质和能量交换过程的一个崭新理论———反演理论,主要包括拉格朗日方法、欧拉方法和欧拉-拉格朗日耦合方法.详细阐述了各种方法的理论框架,并简要说明了其应用范围,最后概述了反演理论的局限性和未来的发展方向.

Preparation of gold nanoparticles/functionalized multiwalled carbon nanotube nanocomposites and its glucose biosensing application

Gold nanoparticles stabilized by amino-terminated ionic liquid (Au-IL) have been in situ noncovalently deposited on poly(sodium 4-styrene-sulfonate) (PSS)-functionalized multiwalled carbon nanotubes (MWCNTs) to form a MWCNTs/PSS/Au-IL nanocomposite. PSS can interact with MWCNTs through hydrophobic interaction. Amino-terminated ionic liquid was applied to reduce aqueous HAuCl4, and the resulting gold nanoparticles were attached to the PSS-functionalized MWCNTs simultaneously. Most gold nanoparticles dispersed well on the functionalized MWCNTs. Transmission electron microscopy, Raman and X-ray photoelectron spectroscopy were used to confirm the composition and structure of the nanocomposites. The resulting MWCNTs/PSS/Au-IL composite exhibits good electrocatalysis toward oxygen and hydrogen peroxide reduction.

Preparation and properties of polyimide films codoped with barium and titanium oxides

Polyimide hybrid films containing bimetalic compounds were obtained by codoping poly(amic acid) with a barium and titanium precursor prepared from BaCO3, Ti(OBu)(4), and lactic acid followed by casting and thermal curing. FTIR, WAXD, and XPS measurements showed that barium and titanium precursor could be transformed to BaTiO3 at a temperature above 650 degreesC, while the mixed oxides were only found in hybrid films. The measurements of TEM and AFM indicated a homogeneous distribution of inorganic phase with particle sizes less than 50 nm. The hybrid films exhibited fairly high thermal stability, good optical transparency, and promising mechanical properties. The incorporation of 10 wt % barium and titanium oxide lowered surface and volume electrical resistivity by 2 and 5 orders, respectively, increasing dielectric constant from 3.5 to 4.2 and piezoelectric constant from 3.8 to 5.2 x 10(-12) c/N, relative to the nondoped polyimide film.

UNSTEADY DIFFUSION KINETICS OF ZIEGLER-NATTA HETEROGENEOUS CATALYST POLYMERIZATION .4. PREDICTION OF EXPERIMENTAL RESULTS OF PROPYLENE ETHYLENE 1-HEXADECENE TERPOLYMERIZATION

The prediction, based on unsteady diffusion kinetics, of the enhancement of reactivity and incorporation of 1-hexadecene in its copolymerization with propylene on adding a small amount of ethylene (increase from 5,2 mol-% to 10,8 mol-% when 2% of ethylene was added, and to 16,1 mol-% when 5% was added) was verified in the terpolymerization of propylene/1-hexadecene/ethylene on a commercial Solvay-type delta-TiCl3 catalyst. The catalyst efficiency was thus also increased. These augmentations originate from the increase in diffusion coefficient of 1-hexadecene at the catalyst surface when the PP crystallinity decreases on introduction of ethylene. Calculation based on unsteady diffusion kinetics showed that the order of diffusion coefficients ethylene > propylene > 1-hexadecene is reversed as the monomer concentration increases when the monomers are not at their equilibrium concentration. Sequence distribution as determined by means of C-13 NMR revealed a tendency of blocky structure rather than a Bernoullian one. The terpolymer compositions obtained by means of an IR method developed in this work conform rather well with the NMR results. Results in this work not only support the unsteady diffusion kinetics but also provide a new route to prepare olefinic copolymer rubbers with heterogeneous titanium catalysts.

EVALUATION OF THE EFFECT OF WAVELENGTH POSITIONING ERRORS ON KALMAN FILTERING RESULTS IN INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION-SPECTROMETRY

This work evaluates the effect of wavelength positioning errors in spectral scans on analytical results when the Kalman filtering technique is used for the correction of line interferences in inductively coupled plasma atomic emission spectrometry (ICP-AES). The results show that a positioning accuracy of 0.1 pm is required in order to obtain accurate and precise estimates for analyte concentrations. The positioning error in sample scans is more crucial than that in model scans. The relative bias in measured analyte concentration originating from a positioning error in a sample scan increases linearly with an increase in the magnitude of the error and the peak distance of the overlapping lines, but is inversely proportional to the signal-to-background ratio. By the use of an optimization procedure for the positions of scans with the innovations number as the criterion, the wavelength positioning error can be reduced and, correspondingly, the accuracy and precision of analytical results improved.

神经网络用于多模式分类

本文叙述一种改进型HAMMING网在印刷汉字文本识别实用系统中作为粗分类的应用.给出了以3755印刷汉字为多模式分类对象的神经网络分类器的结构及其相应的算法.该方法在微型机上用软件仿真得以实现.取得令人满意的结果.

岩石热开裂的实验研究

Micro-cracks appeared between the boundaries of different minerals of rocks during heating process, because of different thermal expansion coefficients of minerals, this phenomenon is referred as thermal cracking of rocks. The transport property of rocks was changed greatly due to the thermal cracking induced micro-cracks network, for example, the permeability of carbonate increases about 10 times when the temperature arise from room temperature to 110～120℃. Thermal cracking of rocks is a new research field of rock physics, which related closely to rock mechanics, mineralogy as well as experimental technology. The thermal cracking experiments of various rocks were performed, the rock macroscopic properties such as porosity, permeability, velocities of elastic waves in rocks were obtained as a function of temperature of heating process, and the microscopic structures of rocks were observed by using Scanning Electro-Microscope (SEM). The mechanism and the theoretical model of thermal cracking of rocks are given at present paper. Finally, the potential implication of rock thermal cracking to petroleum industry is discussed.