岩石中地震波速度和衰减的应力变化响应研究

Stress change is one of key factors in seismic nucleating and triggering; therefore for understanding and forecasting earthquakes, it is necessary to research on stress status and its changes in rocks. Propagating in underground structures, wave velocity and attenuation contain information on stress changes of the Earth’s interior. For a better understanding of relationship between seismic data and stress changes, modeling and ultrasonic test supply significant references. In this article, acoustoelastic theory is introduced to explain nonlinear elastic characteristics of rocks. Based on the acoustoelastic theory, a solid-fluid coupled model is given to calculate velocity under different stress for porous and liquid fulfilled rocks. Except for the stress-velocity relationship, effects of pore pressure induced stress changes on ultrasonic coda attenuation are also studied. Intrinsic attenuation quality factors are calculated for a comparison purpose. Finally, the relationship between elastic constants and stress changes is thoroughly investigated, a mixture model from two phases of Hooke media is introduced to explain the differences between dynamic and static moduli, a relation among wave length, wave velocities and elastic moduli considering dimension of microstructure, dimension and state of surface between phases is presented. The most important aspect of this work is exploring and establishing relationships between the seismic properties of rocks and changes of their stress conditions, which will have its application in earthquake forecast and seismic hazard.

Ultrasonic synthesis of silica-alumina nanomaterials with controlled mesopore distribution without using surfactants

A novel sol-gel process has been developed for the synthesis of amorphous silica-aluminas with controlled mesopore distribution without the use of organic templating agents, e.g., surfactant molecules. Ultrasonic treatment during the synthesis enables production of precursor sols with narrow particle size distribution. Atomic force microscopy analysis shows that these sol particles are spherical in shape with a narrow size distribution (i.e., 13-25 nm) and their aggregation during the gelation creates clusters containing similar sized interparticle mesopores. A nitrogen physiadsorption study indicates that the mesoporous materials containing different Si/Al ratios prepared by the new synthesis method has a large specific surface area (i.e., 587-692 m(2)/g) and similar pore sizes of 2-11 nm. Solid-state Al-27 magic angle spinning (MAS) NMR shows that most of the aluminum is located in the tetrahedral position. A transmission electron microscopy (TEM) image shows that the mesoporous silica-alumina consists of 12-25 nm spheres. Additionally, high-resolution TEM and electron diffraction indicate that some nanoparticles are characteristic of a crystal, although X-ray diffraction and Si-29 MAS NMR analysis show an amorphous material.