Synthesis, Structural Characterization, and Olefin Polymerization Behavior of Vanadium(III) Complexes Bearing Tridentate Schiff Base Ligands

Vanadium(III) complexes bearing tridentate salicylaldiminato ligands (2a-f) [OC6H4CH=NL]VCl2(THF) (L = CH2CH2OMe, 2a; CH2CH2NMe2, 2b; CH2C5H4N, 2c; 8-C9H6N (quinoline), 2d; 2-MeSC6H4, 2e; 2-Ph2PC6H4, 2f) and tridentate beta-enaminoketonato ligands [OC6H8CH=N-2-Ph2PC6H4]VCl2(THF) (2g) and [O(Ph)C=CHCH=N-2-Ph2PC6H4]VCl2(THF) (2h) were prepared from VCl3(THF)(3) by treating with 1.0 equiv of the deprotonated ligands in tetrahydrofuran (THF). These complexes were characterized by FTIR and mass spectrometry as well as elemental analysis. Structures of complexes 2e, 2f, and 2h were further confirmed by X-ray crystallographic analysis. These complexes were investigated as catalysts for olefin polymerization in the presence of organoaluminum compounds. On activation with Et2AlCl, complexes 2a-h exhibited high catalytic activities toward ethylene polymerization (up to 20.64 kg PE/mmol(v) center dot h center dot bar) even at high temperature, suggesting these catalysts possess high thermal stability.

M(EGTA)配合物的NMR研究

乙二醇-双-(α-氨基乙基醚)四乙酸(EGTA)是一种Ca~(2+)高选择性螯合剂,结合Ca~(2+)能力比Mg~(2+)强10~6倍,被认为是钙结合蛋白钙结合位的理想配位模型。Ca(EGTA)的晶体结构虽已确定,但其溶液结构仍不清楚。考虑Ca~(2+)离子半径(0.99

Neural network retrieval of ocean surface parameters from SSM/I data

A new algorithm based on the multiparameter neural network is proposed to retrieve wind speed (WS), sea surface temperature (SST), sea surface air temperature, and relative humidity ( RH) simultaneously over the global oceans from Special Sensor Microwave Imager (SSM/I) observations. The retrieved geophysical parameters are used to estimate the surface latent heat flux and sensible heat flux using a bulk method over the global oceans. The neural network is trained and validated with the matchups of SSM/I overpasses and National Data Buoy Center buoys under both clear and cloudy weather conditions. In addition, the data acquired by the 85.5-GHz channels of SSM/I are used as the input variables of the neural network to improve its performance. The root-mean-square (rms) errors between the estimated WS, SST, sea surface air temperature, and RH from SSM/I observations and the buoy measurements are 1.48 m s(-1), 1.54 degrees C, 1.47 degrees C, and 7.85, respectively. The rms errors between the estimated latent and sensible heat fluxes from SSM/I observations and the Xisha Island ( in the South China Sea) measurements are 3.21 and 30.54 W m(-2), whereas those between the SSM/ I estimates and the buoy data are 4.9 and 37.85 W m(-2), respectively. Both of these errors ( those for WS, SST, and sea surface air temperature, in particular) are smaller than those by previous retrieval algorithms of SSM/ I observations over the global oceans. Unlike previous methods, the present algorithm is capable of producing near-real-time estimates of surface latent and sensible heat fluxes for the global oceans from SSM/I data.

Summer reproduction of the planktonic copepod Calanus sinicus in the Yellow Sea: influences of high surface temperature and cold bottom water

We have observed that Calanus sinicus retreated from neritic areas in the Yellow Sea and concentrated in the Yellow Sea Cold Bottom Water (YSCBW) area in summer. To investigate the summer reproductive strategy of C. sinicus in this situation, effects of high temperature on reproduction and hatching, as well as geographical variation of in situ egg production rate, were studied by onboard incubation in August 2001. Diel vertical migration (DVM) of females was investigated within and outside the YSCBW, respectively. Onboard incubation at 27 degrees C (i.e. surface temperature) resulted in lower fecundities than that at 9.8 and 12 degrees C (i.e. bottom temperature inside and outside the YSCBW) together with decreased hatching rates and increased naupliar malformation. Egg production was more active at stations outside the YSCBW than inside, where chlorophyll-a concentration was also relatively low. Females inside the YSCBW underwent DVM although they rarely entered the surface layer, but DVM was not observed outside the YSCBW. We conclude that surface temperature in summer has deleterious effects on C. sinicus egg production and hatching, and that it cannot reproduce successfully over the whole area. Inside the YSCBW, egg production is depressed by low food availability, while females outside suffer from high temperatures because of strong vertical mixing.

柔性制造单元的智能调度系统

本文基于递阶控制原理提出了柔性制造单元的一种新的计划与调度方法,并综合采用了理论分析、专家系统技术和仿真技术,建立了一个智能调度系统原型.另外,在制造单元调度问题的描述上采用了状态方程形式,从系统的观点来研究调度问题.并在此基础上建立了仿真模块,对单元的加工过程进行了仿真实验.

孤东油田馆陶组河流相储层流动单元模型与剩余油分布规律研究

Since C.L. Hearn presented the concept of flow unit in 1984, its generation mechanisms and controlling factors have been studied in many aspects using different methods by researchers. There are some basic methods to do the research, and there are several concepts and classification standards about flow unit. Based on previous achievements and using methodologies from sedimentary geology, geophysics, seismic stratigraphy, and reservoir engineering, the author systemically studies the factors controlling flow unit, puts forward a series of methods for recognition, classification and evaluation of flow unit. The results obtained in this paper have important significance not only for understanding the flow unit, but also for revealing the distribution of remaining oil. As a case, this paper deals with the reservoir rocks in Guantao Group of Gudong Oilfield. Zhanhua Sag, Jiyang Depression in Bohaiwan Basin. Based on the study of stratigraphic, depositional and structural characteristics, the author establishes reservoir geological models, reveals the geological characteristics of oil-bearing reservoir of fluvial facies, points out the factors controlling flow unit and geological parameters for classification of flow unit. and summarizes methods and technologies for flow unit study when geological, well-logging and mathematical methods are used. It is the first attempt in literatures to evaluate reservoir by well-logging data constrained by geological conditions, then a well-logging evaluation model can be built. This kind of model is more precise than ever for calculating physical parameters in flow unit. In a well bore, there are six methods to recognize a flow unit. Among them, the activity function and intra-layer difference methods are the most effective. Along a section, the composition type of flow unit can be located according amplitude and impedance on seismic section. Slice method and other methods are used to distinguish flow unit. In order to reveal the distribution laws of flow unit in space, the author create a new method, named combination and composition of flow unit. Based on microscopic pore structure research, the classification methods of flow unit are developed. There are three types of flow unit in the reservoir of fluvial facies. They have their own lithology, petrophysics and pore structure character. Using judgement method, standard functions are built to determine the class of flow unit of fluvial facies. Combining reservoir engineering methods, the distribution laws of remaining oil in different types, or in different part of a flow unit are studied. It is evident that the remaining oil is controlled by the type of flow unit. The author reveals the relationship between flow unit and remaining oil distribution, builds the flowing models, predicts the variation of reservoir parameters in space, put forward different methods developing remaining oil in different flow unit. Especially, based on the results obtained in this paper, some suggestions for the adjustment of the developing flow units have been applied in Districts No.4 and No.7, and good results have been yielded. So, the results of this paper can guide oil field development. They are useful and significant for developing the remaining oil and enhancing the oil recovery efficiency.

小兴安岭过去5000年的泥炭δ^13C记录

小兴安岭植物体中δ13C 不仅受区域湿度变化控制,也受温度变化控制。泥炭纤维素的δ13C 曲线,较好地响应了小兴安岭地区过去5000 年来气候,特别是温度和湿度的演变过程。5. 1～3. 0 ka BP、3. 0 ～1. 8 ka BP、1. 8 kaBP 迄今,小兴安岭经历了3 个千年尺度的气候波动,气候演变过程为温暖湿润→温凉较湿→冷凉较湿。在千年尺度的气候波动上,又叠加着百年尺度的气候变化,在3. 0 kaBP 以来更为显著。相应的,泥炭发育也经历了从富营养、中营养到贫营养阶段。

自然硒矿物的形貌特征及其成因研究

元素硒早在1817年就被发现，但因产出稀少，百年来只有十几篇文章报道了自然硒矿物。Thompson等于1956年在砂岩型铀矿中发现了自然硒矿物，呈毡状展布，紫灰色针状晶体。Sun于1959年在粘土岩块的表面擦痕上发现了薄膜状灰硒。Menshikov于1990年在U-Se-Re多金属矿床的氧化带发现了球状和管状形态的自然硒，并把自然硒的形态变化作为矿体形成的温度指示器。

首次发现多形态多成因自然硒

元素硒早在1817年就被发现，但因产出稀少，数百年来只有几篇文章报导了自然硒矿物。易爽庭等手1988年在新疆伊犁雅马渡地区发现了自然硒矿物，其产出环境是低变质烟煤中含硒黄铁矿于封闭缺氧条件下，在煤自燃过程中形成硒蒸汽经冷凝结晶而成。这是我国首次发现自然硒矿物。