Modeling of a compact plate-fin reformer for methanol steam reforming in fuel cell systems

The characteristics of a compact plate-fin reformer (PFR) which integrates endothermic and exothermic reactions into one unit have been investigated by experiment as well as by numerical simulation. One reforming chamber was integrated with two vaporization chambers and two combustion chambers to constitute a single unit of PFR. In the PFR, which is based on a plate-fin beat exchanger, catalytic combustion of the reforming gas is used to simulate the fuel cell anode off gas (AOG) which supplies the necessary heat for the methanol steam reforming. Temperature distributions in all chambers and composition distribution in reforming chamber have been studied, and the effect of the ratio of H2O/CH3OH on the performance of the PFR has also been investigated. A model of the PFR was derived using a three-dimensional numerical model for a cross-current flow arrangement. Theoretical predictions of the temperature distributions in the PFR were in good agreement with experimental values. In addition, the numerical model was able to accurately predict the methanol conversion and the reformate composition in reforming chamber. © 2005 Elsevier B.V. All rights reserved.

Catalytic steam reforming of ethanol to produce hydrogen and acetone

Steam reforming of ethanol over CuO/CeO2 was studied. Acetaldehyde and hydrogen were mainly produced at 260degreesC. At 380degreesC, acetone was the main product, and 2 mol of hydrogen was produced from 1 mol of ethanol. The formation of hydrogen accompanied by the production of acetone was considered to proceed through the following, consecutive reactions: dehydrogenation of ethanol to acetaldehyde. aldol condensation of the acetaldehyde, and the reaction of the aldol with the lattice oxygen [O(s)] on the catalyst to form a surface intermediate, followed by its dehydrogenation and decarboxylation. The overall reaction was expressed by2C(2)H(5)OH + H2O --> CH3COCH3 + CO2 + 4H(2). Ceria played an important role as an oxygen supplier. The addition of MgO to CuO/CeO2 resulted in the production of hydrogen at lower temperatures by accelerating aldol condensation. (C) 2004 Elsevier B.V. All rights reserved.

Methanol steam reforming in a compact plate-fin reformer for fuel-cell systems

A compact plate-fin reformer (PFR) consisting of closely spaced plate-fins, in which endothermic and exothermic reactions take place in alternate chambers, has been studied. In the PFR, which was based on a plate-fin heat exchanger, catalytic combustion of the reforming gas, as a simulation of the fuel cell anode off gas (AOG), supplied the necessary heat for the reforming reaction. One reforming chamber, which was for hydrogen production, was integrated with two vaporization chambers and two combustion chambers to constitute a single unit of PFR. The PFR is very compact, easy to be placed and scaled up. The effect of the ratio of H2O/CH3OH on the performance of the PFR has been investigated, and temperature distributions in different chambers were studied. Besides, the stationary behavior of the PFR was also investigated. Heat transfer of the reformer was enhanced by internal plate-fins as well as by external catalytic combustion, which offer both high methanol conversion ratio and low CO concentration. In addition, the fully integrated reformer exhibited good test stability. Based on the PFR, a scale-up reformer was designed and operated continuously for 1000 h, with high methanol conversion ratio and low CO concentration. (c) 2004 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

Heat-Transfer Study of External Superheater of CFB Incinerator

The heat transfer coefficients for horizontally immersed tubes have been studied in model internally circulating fluidized bed (ICFB) and pilot ICFB incinerators. The characteristics in the ICFB were found to be significantly different from those in a bubbling bed. In ICFB, there is a flowing zone with high velocity, a heat exchange zone, and a moving zone with low velocity. The controllable heat transfer coefficients in ICFB strongly depend on the fluidized velocity in the flowing zone, and also the flow condition in the moving zone. The heat exchange process and suitable bed temperature can be well controlled according to this feature. Based on the results of experiments, a formulation for heat transfer coefficient has been developed. These results were applied to an external superheater of a CFB incinerator with a 450 degreesC steam outlet in a waste-to-energy pilot cogeneration plant of 12 MW in Jiaxing City, China.

蒸汽引射稠油输送新技术

摘要：管线输送是稠油输运的一种主要手段。由于我国一些油田原油粘度高，常温下流动性差，管输需采用特殊工艺。根据粘度随温度沿指数下降的规律，与其它工艺比较，加热输送工艺有更大的潜力。该文提出了一种蒸汽引射直接加热稠油输送的新技术。为研究其有效性，进行了性能分析，并在辽河油田φ80mm，300m输油管线上进行了现场实验，测量了三种工况下该方法对稠油的温度、压降和含水串的影响。实验结果表明该文提出的方法是可行的。

用于稠油输送的新蒸汽引射器

介绍一种自行研制的蒸汽引射器，蒸汽以自由射流形式注入到输油管中，利用蒸汽释放的热量提高稠油温度以降低黏度，从而达到低输送压降的目的。该引器具有加热效率高，防止稠油堵塞管线等优点，引射器已在辽河油田输油管线上进行了现场实验，取得了很好的效果。

Coflow jets with large velocity difference - a new aerodynamic principle of flame stabilization and combustion intensification

A new aerodynamic principle of flame stabilization and combustion intensification, the coflow jets with large velocity difference, is described. One or more small high-velocity jets of air or steam, injected off the axis and in the same direction as the low-velocity main fuel-air flow into the combustor, create a large recirculation zone of high turbulence intensity in which the combustibles and high temperature gases are effectively mixed, so that stable and intensive combustion can be maintained even for fuels with poor ignition. A pulverized coal combustor based on the principle mentioned above is shown to be characteristic of excellent combustoom and a simple structure. A number of precombustors of this type are in operation at some power stations and industrial boilers of China. Using such precombustor, successtul startups and part-load operation of the boilers have become available under conditions of unpreheated air and low-grade coal with volatiles as low as 15% and ash content as high as 30%. This principle shows good promise as an attractive new technology of combustion.

柴油、甲醇和水三组元乳化液滴微爆过程的研究

分别采用激光全息摄影技术和高速数字摄影技术观察了柴油、甲醇和水乳化液喷雾在高温高压(773K,3.1MPa)环境中发生微爆现象的瞬间和全过程,证实了微爆现象的存在.由于微爆机理的复杂性,尚难以用数学方法准确描述该过程.实验分析表明:若环境温度处于"最佳温度"范围内,乳化液滴表面首先形成"无水层",液滴内部形成一个水滴的概率很小,可能形成几个相对较大的水滴,只要其中一个较大水滴的蒸汽压力大于液滴的表面张力和环境压力之和,液滴就有可能发生微爆,微爆不仅与液滴直径、组分的质量分数和组分间的沸点差等乳化液的本身特性有关,而且环境温度和压力的影响也不容忽视.该研究可以为乳化液喷雾微爆过程的数学模拟提供参考.

岩石爆炸增渗模型实验及DEM数值模拟研究

岩体中爆炸提高矿石的渗透性可以极大地提高采矿效率，是碎裂岩型矿床预裂浸出法的关键技术。混凝土与岩体都具有脆性材料的特性，因此用浇筑于铁桶中的混凝土试件进行模型实验研究岩体的爆炸增渗效果。铁桶可以提高实验效率，使边界条件更为简单和易于操作，但是，实验和原型的差异需要论证。用自主开发的基于连续介质力学模型的离散元方法，模拟了有铁桶边界的模型实验，验证了数值模拟方法的可行性及有效性，给出了有弹性侧限边界约束的混凝土和较大尺度无反射边界条件的岩石中的爆炸差别。在此基础上，分析了岩石中爆炸造成的岩石破坏规律。计算结果表明：岩石破坏面总面积和破坏区的最大裂缝宽度受药量和岩石的抗拉强度影响，破坏面总面积和裂缝宽度随药量增加而增大，随抗拉强度增大而减小；在药量相同的条件下，实际岩石环境下的岩块破坏程度比铁桶约束的大。模型实验和数值模拟相结合的办法可以对混凝土和岩石的爆炸破坏给出较为合理的结果。

注蒸汽井套管应力的数值计算与工业应用

在注蒸汽吞吐井的井筒应力模型中引入井筒温度场，利用ANSYS软件对不同约束条件下井简的应力场进行了计算．结果表明，最大热应力发生在套管内壁，超过了N80套管的弹性屈服极限，最大热膨胀发生在温度过渡区．当套管周围掏空时，热应变远大于材料的弹性极限应变，是诱发热采井套管变形损坏的主要原因．为此提出了相应的套管损坏防治措施，在油田现场采用厚壁合金钢TP120TH套管完井，试验结果验证了防治措施的有效性．