硼对贮氢合金性能的影响

硼是贮氢合金中很有发展前景的一种元素,将硼及其化合物加入金属氢化物-镍电池的合金电极材料中,可有效改善贮氢合金电极的性能。本文主要评述了硼的添加对贮氢合金力学性能、热力学性能和动力学性能的影响。控制硼的含量对改善MH-Ni电池性能有极其重要的意义。

3{1-[2-(-3-羟基-1-甲基-2-亚丁烯氨基)-苯亚氨基]-乙基}4-甲硫基-2,4-戊二烯-2-醇的不对称Schiff碱镍(Ⅱ)配合物的合成、结构和性质

由 5-(2-乙酰基-1-甲硫基-3-羰基-亚丁基)-丙二酸亚异丙酯 (1)与邻苯二胺及乙酸镍()经一步反应合成了3{1-[2-( -3-羟基-1-甲基-2-亚丁烯氨基)-苯亚氨基 ]-乙基} 4-甲硫基-2,4-戊二烯-2-醇(3)的不对称四齿 Schiff碱镍()配合物(2),X射线衍射结果表明,配合物 2属单斜晶系,P21/C空间群.a=1.1476(2)nm,b=1.1782(2)nm,c=1.4810(3)nm;β=111.73(2)°,V=1.8602(7)nm3,Z=4,Rf=0.0535.电化学(循环伏安)测定结果表明,该配合物在测定条件下(阳极峰电位为1.1)发生了不可逆的氧化-还原反应.

Studies of methane reforming with carbon dioxide over LaNiAl11O19

A new type of the catalyst, LaNiAl11O19, for the methane reforming with carbon dioxide was synthesized and evaluated. LaNiAl11O19 has a hexaaluminate structure and can keep large surface and heat resistance against sintering at high reaction temperature. As compared with La2O3-Ni/SrAl12O19, in the CH4 + CO2 reaction, LaNiAl11O19 catalyst displays a higher catalytic activity, lower coking amount and excellent sintering resistance of Ni particle, due to its stable structure.

THE CLEAVAGE REACTION OF THE MO-MO TRIPLE BOND - THE CRYSTAL-STRUCTURES OF MOLYBDENUM COMPLEXES [CPMO(CO)(2)(C(5)H(4)NS)], [CPMO(CO)(2)(C(9)H(6)NS)]O=PPH(3) AND [CPMO(CO)(2)(S(2)CNME(2)]

The reactions of [Cp2Mo2(CO)4] (1) with 2,2'-dipyridyl disulphide (C5H4NS-)2, 8,8'-diquinolyl disulphide (C9H6NS-)2 and tetramethyl thiuram disulphide (Me2NC(S)S-)2 in toluene solution resulted in the cleavage of the Mo-Mo triple bond to yield molybdenum complexes [CpMo(CO)2(C5H4NS)] (2), [CpMo(CO)2(C9H6NS)] (3) and [CpMo(CO)2(S2CNMe2)] (4), respectively. The molecular structures of 2, 3 . O=PPh3 and 4 were determined by X-ray diffraction studies. Crystals of 2 are monoclinic, space group P2(1)/n, with Z = 4, in a unit cell of dimensions a = 6.448(1), b = 12.616(2), c = 14.772(2) angstrom, beta = 92.85(1)-degrees. The structure was refined to R = 0.028 and R(w) = 0.039 for 1357 observed reflections. Crystals of 3 . O=PPh3 are triclinic, space group P1BAR, with Z = 2, in a unit cell of dimensions a = 11.351(3), b = 13.409(3), c = 9.895(2) angstrom, alpha = 94.59(2), beta = 90.35(2), gamma = 78.07(2)-degrees. The structure was refined to R = 0.033 and R(w) = 0.037 for 3260 observed reflections. Crystals of 4 are monoclinic, space group P2(1)/a and Z = 4 with a = 12.468(5), b = 7.637(2), c = 13.135(4) angstrom, beta = 96.62(3). The structure was refined to R = 0.032 and R(w) = 0.042 for 1698 observed reflections. Each of complexes 2-4 contains a cyclopentadienyl ligand, a cis pair of carbonyls and a chelate ligand (S,N donor or S,S donor). All the compounds have distorted square-pyramid structures.

Variations in morphology and PSII photosynthetic capabilities during the early development of tetraspores of Gracilaria vermiculophylla (Ohmi) Papenfuss (Gracilariales, Rhodophyta)

Background: Red algae are primitive photosynthetic eukaryotes, whose spores are ideal subjects for studies of photosynthesis and development. Although the development of red alga spores has received considerable research attention, few studies have focused on the detailed morphological and photosynthetic changes that occur during the early development of tetraspores of Gracilaria vermiculophylla (Ohmi) Papenfuss (Gracilariales, Rhodophyta). Herein, we documented these changes in this species of red algae. Results: In the tetraspores, we observed two types of division, cruciate and zonate, and both could develop into multicellular bodies (disks). During the first 84 hours, tetraspores divided several times, but the diameter of the disks changed very little; thereafter, the diameter increased significantly. Scanning electron microscopy observations and analysis of histological sections revealed that the natural shape of the disk remains tapered over time, and the erect frond grows from the central protrusion of the disk. Cultivation of tissue from excised disks demonstrated that the central protrusion of the disk is essential for initiation of the erect frond. Photosynthetic (i.e., PSII) activities were measured using chlorophyll fluorescence analysis. The results indicated that freshly released tetraspores retained limited PSII photosynthetic capabilities; when the tetraspores attached to a substrate, those capabilities increased significantly. In the disk, the PSII activity of both marginal and central cells was similar, although some degree of morphological polarity was present; the PSII photosynthetic capabilities in young germling exhibited an apico-basal gradient. Conclusions: Attachment of tetraspores to a substrate significantly enhanced their PSII photosynthetic capabilities, and triggered further development. The central protrusion of the disk is the growth point, may have transfer of nutritive material with the marginal cells. Within the young germling, the hetero-distribution of PSII photosynthetic capabilities might be due to the differences in cell functions.

Validation of RADARSAT-2 fully polarimetric SAR measurements of ocean surface waves

C band RADARSAT-2 fully polarimetric (fine quad-polarization mode, HH+VV+HV+VH) synthetic aperture radar (SAR) images are used to validate ocean surface waves measurements using the polarimetric SAR wave retrieval algorithm, without estimating the complex hydrodynamic modulation transfer function, even under large radar incidence angles. The linearly polarized radar backscatter cross sections (RBCS) are first calculated with the copolarization (HH, VV) and cross-polarization (HV, VH) RBCS and the polarization orientation angle. Subsequently, in the azimuth direction, the vertically and linearly polarized RBCS are used to measure the wave slopes. In the range direction, we combine horizontally and vertically polarized RBCS to estimate wave slopes. Taken together, wave slope spectra can be derived using estimated wave slopes in azimuth and range directions. Wave parameters extracted from the resultant wave slope spectra are validated with colocated National Data Buoy Center (NDBC) buoy measurements (wave periods, wavelengths, wave directions, and significant wave heights) and are shown to be in good agreement.

藏药麻花秦艽的研究进展

麻花秦艽（Gentiana straminea Maxim．）具有清热利胆、舒筋止痛之功效，是一种治疗风湿性关节炎、肺结核、低热盗汗、黄疸型肝炎等的珍稀藏药草本植物。笔者系统阐述了近年来该植物的研究进展，并对其研究方向进行了展望，为该物种资源的进一步有效开发利用提供参考。

纵波方位属性裂缝检测技术综合研究

Fractured oil and gas reservoir is an important type of oil and gas reservoir, which is taking a growing part of current oil and gas production in the whole world. Thus these technologies targeted at exploration of fractured oil and gas reservoirs are drawing vast attentions. It is difficult to accurately predict the fracture development orientation and intensity in oil and gas exploration. Focused on this problem, this paper systematically conducted series study of seismic data processing and P-wave attributes fracture detection based on the structure of ZX buried mountain, and obtained good results. This paper firstly stimulated the propagation of P-wave in weak anisotropic media caused by vertical aligned cracks, and analyzed the rule of P-wave attributes’ variation associated with observed azimuth, such as travel-time, amplitude and AVO gradient and so on, and quantitatively described the sensitive degree of these attributes to anisotropy of fracture medium. In order to further study the sensitive degree of these attributes to anisotropy of fractures, meanwhile, this paper stimulated P-wave propagation through different types and different intensity anisotropic medium respectively and summarized the rule of these attributes’ variation associated with observed azimuth in different anisotropic medium. The results of these studies provided reliable references for predicting orientation, extensity and size of actual complicated cracked medium by P-wave azimuth attributes responses. In the paper, amounts of seismic data processing methods are used to keep and recover all kinds of attributes applied for fracture detection, which guarantee the high accurate of these attributes, thus then improve the accurate of fracture detection. During seismic data processing, the paper adopted the three dimensional F-Kx-Ky field cone filter technique to attenuate ground roll waves and multiple waves, then enhances the S/N ratio of pre-stack seismic data; comprehensively applying geometrical spread compensation, surface consistent amplitude compensation, residual amplitude compensation to recover amplitude; common azimuth processing method effectively preserves the azimuthal characteristics of P-wave attributes; the technique of bend ray adaptive aperture pre-stack time migration insures to obtain the best image in each azimuth. Application of these processing methods guaranteed these attributes’ accuracy, and then improved the accuracy of fracture detection. After comparing and analyzing a variety of attributes, relative wave impedance (relative amplitude) attribute is selected to inverse the orientation of fracture medium; attenuation gradient and corresponding frequency of 85% energy are selected to inverse the intensity of fracture medium; then obtained the fracture distribution characteristics of lower Paleozoic and Precambrian in ZX ancient buried mountains. The results are good accord with the characteristics of faults system and well information in this area.

新第三纪红河盆地特征及红河断裂活动对其形成与发育的控制

Based on geodynamic analysis of sedimentary basins, combined sedimentology with structural geology and other methods, the author studied the Honghe basin located in Yunnan province of Southwestern China. Sandstone slice grain size analysis, combined with field geology and indoors study indicate that a set of inland alluvial fan diposits, fluvial deposites, delta deposits and some lacustrine sediments are in Honghe basin. Studying on shape of the Honghe basin, sedimentary and structural characteristic and distribution of different kinds of conglomerate and its structural significance, we hold the idea that the formation and evolution of Honghe basin are controlled by the activity of Red River faut. Correlation of lithostratic cross section in Honghe basin and studying on activity of Red River fault indicate that Honghe basin was formed in two stages. It is a complex basin constitutes of the first-stage trans-releasing basin and the second-stage trans-downfaulted basin. Due to the uplift of Qinghai-Xizang plateau and deformation of orogeny, the western Yunnan and adjacent area move to SE direction as a result of Tectonic Escape. Right lateral strike slip occurred along Red River fault, trans-releasing basin formed at the bend part of the fault due to stress relexation. As the block escaping, it moves away from the other block of the Red River fault, the upper block move down obliquely and trans-downfaulted basin formed. Combined the age of phytolite and regional structural events, we think the first-stage transreleasing basin was formed in late Miocene, on the other words, the dextral strike slip of Red River fault may began in late Miocene (10-7Ma). The second-stage trans-downfaulted basin may be formed in early stage of Pliocene (about 4.7Ma). Subsequently, the bilateral faults dipping to the inside of the plateau and thrusting outwards occurred in the marginal region of Qinghai-Xizang plateau during its uplifting as a fan-shaped mountain body, this results in the uplift of the strata to the east of Red River fault and supply large quantity of provenance for the Honghe basin. In last Pliocene (about 3Ma), strong uplift of Qinghai-Xizang plateau leads to massive clastic sediment entered Honghe basin and causes its closure. As a kind of trans-tentional basin, trans-releasing basin is different to pull-apart basin. The author compared the Mosha trans-releasing basin with Jinggu pull-apart basin in SW Yunan, China, and described their character correspondingly. Otherwise, the author combined the predecessors' studding with conclusion of own study, discussed the kinematics of Ailaoshan-Red River belt in Cenozoic, and the relationship between the formation of Honghe basin and uplifting of Qinghai-Xizang plateau.