美国长期生态学研究网络第三次全体学者大会及国际长期生态学研究负责人会议介绍

美国长期生态学研究网络第三次全体学者大会及国际长期生态学研究负责人会议介绍赵士洞（中国科学院沈阳应用生态研究所，沈阳１１００１５）美国长期生态学研究网络（Ｕ．Ｓ．ＬＴＥＲＮｅｔ－ｗｏｒｋ）第Ｈ次全体学者大会（１９９３ＬＴＥＲＡｌｌＳｅｔ－ｅｎｔｉｓｔ...

模拟不同森林可燃物处理对大兴安岭潜在林火状况的影响

大兴安岭林区50年来实施的森林防火政策导致森林火烧轮回期延长,可燃物累积,所以需要将森林可燃物的管理纳入到森林防火政策中。本研究构建10种可燃物处理预案,5种为计划火烧预案(PB02,PB04,PB06,PB08,PB10),另5种为机械清除+计划火烧预案(PR02,PR04,PRP6,PR08,PR10,用无处理预案(notreat)作对照。采用空间直观森林景观模型LANDIS,从火烧面积、不同强度火烧面积和林火强度动态特征来说明不同可燃物处理预案的长期效果(300年)。结果表明,计划火烧虽然可以减少总火烧面积,但随着处理面积的增加,减少幅度不大,对于降低高强度火烧面积效果不显著;机械清除+计划火烧可以有效地减少火烧面积,降低火烧强度[将高强度火(4、5级)降低为低强度火(1、2级)]。建议森林可燃物处理必须长期进行,以达到降低林火强度、减少灾难性火灾发生的机率的目的。

文冠果的食用和药用价值

<正> 文冠果属无患子科文冠果属植物,别名文官果、文光果、木瓜等,是我国特有的一种优良木本食用油料树种。其适应性极强,根深、耐旱、耐寒、耐盐碱、耐脊薄,且综合价值高。分布于我国13个省(市、自治区)。1、文冠果的食用价值文冠果的果实含有高油脂及多种生物活性成分:

环境地理与人类健康研究成果与展望

中国科学院地理科学与资源研究所倡导和建立了化学地理研究机构,是我国最早从事环境科学研究的单位之一,推动了环境质量调查、环境质量评价、环境背景、环境容量和环境治理等理论和技术的建立和发展;长期进行克山病、大骨节病等地方病的调查及其环境病因与防治的研究,为上述疾病的控制做出了重大贡献;创立和发展了中国的医学地理学研究体系。2000年以后,在持续开展西部地方病地理流行规律和稀土元素生物地球化学循环研究基础上,重点开展了重金属等污染物及全球环境变化的健康风险评价研究,拓展了区域碳、氮、磷等生命元素的生物地球化学循环与温室气体排放的关系研究,强化了环境污染治理和健康保护的技术研究。实现了从化学地理到环境地理、从医学地理到健康地理的转变。未来的环境地理与人类健康研究将以地理环境的化学属性为重点,以人口健康保护为核心,探讨环境保护、社会经济发展和人类健康安全在整体上协调的机制与途径。

Enhanced luminescence of gadolinium niobates by Bi3+ doping for field emission displays

Blue emitting GdNbO4: Bi3+ powder phosphors for field emission displays were prepared by a solid state reaction. Both photoluminescence and cathodoluminescence properties of the materials were investigated. GdNbO4 itself shows only a very weak luminescence in the blue spectral region. By doping Bi3+ in GdNbO4, the luminescence intensity was improved greatly. The emission spectrum of the GdNbO4: Bi3+ consists of a broad band with maximum at 445 nm (lifetime = 0.74 mu s; CIE chromaticity coordinates: x = 0.1519 and y = 0. 1196) for both UV and low voltage (1-7 kV) cathode ray excitation. In GdNbO4:Bi3+ phosphors, the energy transfer from NbO43- to activator Bi3+ occurred.

Preparation and luminescent properties of rare earth ions in M2B5O9Cl : Re(M = Ca, Sr, Ba; Re=Eu, Tb)

M2B5O9X: Re(M = Ca, Sr, Ba; X = Cl, Br; Re = Eu, Th) phosphors were synthesized via solid state method. The products were characterized with X-ray powder diffraction and luminescence spectrometer. The luminescent properties as well. as the influences of the matrix composition and other doping ions on the luminescence of the rare earth ions of the co-doped phosphors were investigated. The coexistence of Eu3+, Eu2+ and Th3+ were observed in these matrices. The phenomenon may be explained by the electron transfer theory. The sensitization of Ce3+ ion improves the intensity of emission of Eu2+, and Tb3+. The competition between electron transfer among conjugate rare earth ions and energy migration might be the reasons for the observation. We predict a novel trichromatic phosphor co-doped with Eu3+ Tb3+ in M2B5O9X.

Effect of pretreatment of black carbon on electrocatalytic activity of Pt/C catalyst for methanol oxidation

Direct methanol fuel cell (DMFC) has attracted wide attention due to its many advantages. However, its practical application is limited by the low electrocatalytic activity of the anodic Pt/C catalyst usually used for the methanol oxidation. In this paper, in order to increase the electrocatalytic performance of the Pt/C catalyst for the methanol oxidation, the black carbon, usually used as the supporter, was pretreated with CO2, air, HNO3 or H2O2. The cyclic voltarnmetric results indicated that the current densities of the anodic peak of methanol oxidation at the Pt/C catalysts with the black carbon pretreated with CO2,air, HN03, H202 and untreated black carbon were 39, 33, 32, 20 and 18 mA center dot cm(-2), respectively, illustrating that among the above five kinds of the Pt/C catalysts, the Pt/C catalyst with the black carbon pretreated with CO2 shows the best electrocatalytic activity and stability for the methanol oxidation. Its main reason is that the CO2 pretreatment could reduce the content of the oxygen-containing groups on the surface of the black carbon and increase the content of graphite in the black carbon, leading to the low resistance of the black carbon and the increase in the dispersion extent of the Pt particles in the Pt/C catalyst.

碳黑预处理对Pt/C催化剂对甲醇氧化电催化活性的影响

直接甲醇燃料电池(DMFC)由于具有较多的优点而受到广泛的关注.但是碳载Pt(Pt/C)阳极催化剂电催化活性低是限制其应用的一个主要问题.为了提高Pt/C催化剂对甲醇氧化的电催化性能,分别用CO2,空气,H2O2或HNO3对常用作为载体的VulcanXC-72碳黑进行预处理.结果表明,在用CO2,空气,HNO3,H2O2处理的及未处理的碳黑作载体制得的Pt/C催化剂电极上,甲醇氧化峰的峰电流密度顺序为39,33,32,20和18mA?cm-2,表明用CO2处理的碳载体制备的Pt/C催化剂对甲醇氧化有最好的电催化活性和稳定性.其主要原因是用CO2处理能减少碳黑表面的含氧基团和增加石墨化程度,而使碳黑的电阻降低及Pt粒子在碳黑上的分散性变好.

Dynamic mechanical and thermal properties of plasticized poly(lactic acid)

The blends of low molecular weight triacetin (TAC) and oligomeric poly(1,3-butylene glycol adipate) (PBGA) were used as multiple plasticizers to lubricate poly(lactic acid) (PLA) in this study. The thermal and mechanical properties of plasticized polymers were investigated by means of dynamic mechanical analysis and differential scanning calorimetry. Atomic force microscopy (AFM) was used to analyze the morphologies of the blends. Multiple plasticizers were effective in lowering the glass transition temperature (T-g) and the melting temperature (T-m) of PLA. Moreover, crystallinity of PLA increased with increasing the con-tent of multiple plasticizers. Tensile strength of the blends decreased following the increasing of the plasticizers, but increased in elongation at break. AFM topographic images showed that the multiple plasticizers dispersed between interfibrillar regions. Moreover, the fibrillar crystallite formed the quasicrosslinkings, which is another cause for the increase in elongation at break.

不同结构可生物降解聚酯的组织相容性

目的采用共聚的方法改变聚酯的结构，探讨材料结构与生物相容性的关系，为临床选用适宜性质的该类材料提供实验依据。方法将自行合成的聚己内酯（ＰＣＬ）、聚丙交酯（ＰＬＡ）、以及它们不同摩尔比的共聚物（ＰＣＬＡ２／１、ＰＣＬＡＩ／２）植入兔背部肌肉中２４周，观察动物生活和整体情况；组织学和组织计量学方法观察材料周围肌肉的组织学情况，比较不同结构材料的组织相容性。结果材料在整个植入周期所呈现的组织反应是一种无菌性非特异炎症反应；周围纤维包膜厚度依次增厚，肌肉中的炎细胞数量依次增加。结论不同结构材料的生物相容性存在差异。

Lanthanide coordination polymers with dicarboxylate-like ligands: crystal structures of polymeric lanthanum(III) and terbium(III) complexes with flexible double betaines

Four novel polymeric lanthanide(III) complexes of two new double betaine derivatives have been synthesized and structurally determined. In [{La-2(L-1)(2)(H2O)(9)}(n)]Cl-6n. 2nH(2)O (1) and [{Tb(L-1)(H2O)(4)}(n)]Cl-3n. nH(2)O (2) (L-1 =4,4'-trimethylenedipyridinio-N,N'-diacetate), the lanthanide(III) ions form a two-dimensional layer in which each pair of lanthanide(III) ions is bridged by two syn-anti mu-carboxylato-O,O' groups. Adjacent layers are cross-linked through hydrogen bonds among aqua ligands, lattice water molecules and chloride ions, to form a three-dimensional network. Isomorphous [{Ln(L-1)(H2O)(4)}(n)]Cl-3n. 5nH(2)O (Ln=La, 3; Ln=Tb, 4; L-2=1,3 bis(pyridinio-4-carboxylato)-propane) each contain a centrosymmetric paddle-wheel-like dimeric unit in which each pair of adjacent metal atoms is bridged by four syn-syn mu-carboxylato-O,O' groups that are oriented nearly perpendicular to each other about the metal-metal axis. Neighboring dimeric subunits are bridged by a pair of flexible LL ligands into a polymeric chain. Adjacent chains are inter-linked by hydrogen bonds among aqua ligands, lattice water molecules and chloride ions into a three-dimensional network. (C) 1999 Elsevier Science Ltd. All rights reserved.

规范化管理高科技高效益企业

规范化管理高科技高效益企业中国科学院成都生物研究所王海燕中共成都市委组织部张松中科院成都生物研究所于１９８８年开始创办药厂，药厂产值六年翻了六番，原始投资增值数百倍。如今，药厂已更名为地奥制药公司，成为拥有净资产２亿多元、年利税１亿元的集高科技、新产...