Cardo polyarylethersulfones and polyaryletherketones bearing alkyl substituents on the phenylene unit

A series of cardo polyaryletherketones and polyaryletersulfones containing alkyl substituents of a different kind, number and volume were synthesized from bis(4-nitrophenyl)ketone or bis(4-fluorophenyl)sulfone with various alkyl substituted phenolphthaleins by polycondensation using K2CO3 as catalyst. Their chemical and aggregation structures were confirmed by FT-IR, H-1-NMR and WAXD. The resulting polymers were soluble in a variety of common polar solvents and, transparent, colorless, and tough films could be easily cast from 1,1,2-trichluoroethane solution. Their tensile strength, elongation at break and tensile modulis were in the range of 70.5 similar to 97.1MPa, 4.49%similar to7.81%, and 1.69 similar to2.27GPa, respectively. The prepared polymers had reasonably high glass transition temperatures at 207 to 269 degreesC, and showed fairly good thermal stability with 5% thermal decomposition loss above 410 degreesC.

Crosslinking of polyimides via spirodilactone unit in polymer backbone

A new approach for the crosslinking of polyimides via the lactamization of spirodilactone unit in polyimide backbone was studied by two means: model reaction and the comparison of the properties of the polyimide precursors to those of the crosslinking polymers. Polyimides 4 and 5 were soluble in N,N'dimethylacetamide (DMAc), dimethylformamide (DMF), dimethylsulfoxide (DMSO), N'-methylpyrrolidone (NMP), and other common organic solvents, whereas their corresponding crosslinking polymers were insoluble in these solvents. The glass transition temperatures for polyimide 5 and its crosslinking polymer were 262 degrees C and 291 degrees C, whereas those for polyimide 4 and its crosslinking polymer were 265 degrees C and 360 degrees C. The weight-loss rate of the crosslinling polymers was apparently slower than that of the precursors when the temperature was >400 degrees C. The 10% weight-loss temperature for the polyimides 4 and 5 was <500 degrees C, whereas that for the crosslinking polymers was close to or above 600 degrees C. The results indicate that this type of crosslinking polymer has good thermal properties. The temperature for the formation of lactam was above 180 degrees C. (C) 1999 John Wiley & Sons, Inc.

Using triazine as coupling unit for intramolecular ferromagnetic coupling of multiradicals

Novel high spin tri-, tetra-, pentaradicals, composed of triazine coupling units and cationic amino radical spin centers (+ . NH) under various configurations and linkages, are predicted from AM1-CI calculations. It is found that for charged planar multiradicals the stability of high spin ground states depends on both the molecular configuration and the number of end groups. Generally, cyclic 1,3-bridged charged multiradicals (S less than or equal to 5/2) possess more stable high spin ground states than their isomers under the branched 1,3,5,-bridged configuration. Therefore, it is suggested that in the design of planar high spin molecules with stable high spin ground states, less end groups and all the supposed spin centers and/or the coupling units should be under the same structural situation. (C) 1999 Elsevier Science B.V. All rights reserved.

Characterization of cyclic arylether ketone (sulfone) containing hexafluoroisopropylidene unit by matrix-assisted laser desorption ionization time-of-flight mass spectrometry

The cyclic aryletherketone( sulfone) oligomers containing hexafluoroisopropylidene unit were characterized by matrix-assisted laser desorption ionization time-of-night mass spectrometry(MALDI-TOF-MS) using Na+ and Ag+ as cationization agents. The affinities of cyclic oligomers to the cation were studied. The analysis result showed that 1,8,9-dithranol, in the presence of silver trifluoroacetate, was very effective for the characterization of cyclic arylether ketone ( sulfone) containing hexafluoroisopropylidene unit.

Synthesis, structure and ring-opening polymerization of macrocyclic arylates containing phthalic unit

A series of macrocyclic arylate dimers have been selectively synthesized by an interfacial polycondensation of o-phthaloyldichloride with bisphenols. A combination of GPC, FAB-MS, H-1 and C-13 NMR unambiguously confirmed the cyclic nature. Although single-crystal X-ray analysis of two such macrocycles reveals no severe strain on the cyclic structures, these macrocycles can undergo facile melt polymerization to give high molecular weight polyarylates.

地理信息系统支持下的滑坡灾害空间分析预测-以云南小江流域为例

As a typical geological and environmental hazard, landslide has been causing more and more property and life losses. However, to predict its accurate occurring time is very difficult or even impossible due to landslide's complex nature. It has been realized that it is not a good solution to spend a lot of money to treat with and prevent landslide. The research trend is to study landslide's spatial distribution and predict its potential hazard zone under certain region and certain conditions. GIS(Geographical Information System) is a power tools for data management, spatial analysis based on reasonable spatial models and visualization. It is new and potential study field to do landslide hazard analysis and prediction based on GIS. This paper systematically studies the theory and methods for GIS based landslide hazard analysis. On the basis of project "Mountainous hazard study-landslide and debris flows" supported by Chinese Academy of Sciences and the former study foundation, this paper carries out model research, application, verification and model result analysis. The occurrence of landslide has its triggering factors. Landslide has its special landform and topographical feature which can be identify from field work and remote sensing image (aerial photo). Historical record of landslide is the key to predict the future behaviors of landslide. These are bases for landslide spatial data base construction. Based on the plenty of literatures reviews, the concept framework of model integration and unit combinations is formed. Two types of model, CF multiple regression model and landslide stability and hydrological distribution coupled model are bought forward. CF multiple regression model comes form statistics and possibility theory based on data. Data itself contains the uncertainty and random nature of landslide hazard, so it can be seen as a good method to study and understand landslide's complex feature and mechanics. CF multiple regression model integrates CF (landslide Certainty Factor) and multiple regression prediction model. CF can easily treat with the problems of data quantifying and combination of heteroecious data types. The combination of CF can assist to determine key landslide triggering factors which are then inputted into multiple regression model. CF regression model can provide better prediction results than traditional model. The process of landslide can be described and modeled by suitable physical and mechanical model. Landslide stability and hydrological distribution coupled model is such a physical deterministic model that can be easily used for landslide hazard analysis and prediction. It couples the general limit equilibrium method and hydrological distribution model based on DEM, and can be used as a effective approach to predict the occurrence of landslide under different precipitation conditions as well as landslide mechanics research. It can not only explain pre-existed landslides, but also predict the potential hazard region with environmental conditions changes. Finally, this paper carries out landslide hazard analysis and prediction in Yunnan Xiaojiang watershed, including landslide hazard sensitivity analysis and regression prediction model based on selected key factors, determining the relationship between landslide occurrence possibility and triggering factors. The result of landslide hazard analysis and prediction by coupled model is discussed in details. On the basis of model verification and validation, the modeling results are showing high accuracy and good applying potential in landslide research.