黄土高原植物与不同粒级中土壤体系氮同位素组成变化及意义

IEECAS SKLLQG

额济纳绿洲沙尘暴沉积的物质特征

IEECAS SKLLQG

不同辅料对高塔熔体造粒工艺降氮共熔值的影响

目前高塔熔体造粒工艺限于仅能生产高氮复合肥料,要扩大生产线的生产范畴、增强市场竞争能力,就要解决降低尿素用量时熔融料的共熔值和黏度值上升的问题。以降低熔融料共熔值为主线,探明了共熔值随肥料营养比例中氮含量降低而升高的根本原因和解决方案。试验结果表明:肥料营养比例中氮含量的降低,CaCO3用量的增加,是促使共熔值升高的根本原因。解决问题的关键在于利用"相似相溶"原理,筛选和调整出相应比例的无毒无害、避免加入多余元素的无机盐类化合物且符合肥料生产的辅料和填加料。研究表明,辅料NH4HCO3的加入很大程度降低了熔融料的共熔值,可使氮的最低含量达18%,降低幅度最大为10.83℃,辅料与填加料的配比以7:3为最宜。

虎杖根提取物及分离组分对黄瓜白粉病的作用效果

在实验室内进行了虎杖(Polygonum cuspidatum Sieb.etZucc.)根提取物及其活性组分分离研究,并且对黄瓜白粉病进行了活性测定及温室小区试验。结果表明,无论提取率还是作用效果,乙醇较适合于做为虎杖根提取物的提取溶剂。虎杖根乙醇提取物和乙醚提取物对黄瓜白粉病的EC90值分别为537.85、35.38mg/L,而乙醚提取后残留物的活性很弱,说明乙醇提取物中具有杀菌作用的成分主要存在于乙醚提取物中。用pH梯度分离法对乙醚提取物进行分离,得到3个不同组分,其中以氢氧化钠分离得到的组分对黄瓜白粉病显示了极高的杀菌活性。在温室条件下虎杖乙醇提取物在800～1600mg/L下对黄瓜白粉病的防效相当或优于对照药剂三唑酮。

60年来的资源科学:从自然资源综合考察到资源科学综合研究

走过60年,资源科学研究已从最初的自然资源综合考察发展成了一门综合性的资源科学学科体系。期间,国家先后编制了7次科技发展规划,尤以《1956-1967年科学技术发展远景规划》和《1978-1985年全国科学技术发展规划纲要》对资源科学的形成与发展影响最大。前者推动了中国自然资源综合考察事业的形成与发展,后者促进了中国资源科学考察事业的发展与壮大,进而推动了资源科学的形成与发展。60年来的中国资源科学可以初步划分为大规模的自然资源综合考察时期(1950-1960年代)、区域资源综合科学考察与资源科学研究时期

Immobilization of dipyridyl complex to magnetic nanoparticle via click chemistry as a recyclable catalyst for Suzuki cross-coupling reactions

A magnetic nanoparticle (MNP)-supported di(2-pyridyl)methanol palladium dichloride complex was prepared via click chemistry. The MNP-supported catalyst was evaluated in Suzuki coupling reaction in term of activity and recyclability in DMF. It was found to be highly efficient for Suzuki coupling reaction using aryl bromides as substrates and could be easily separated by an external magnet and reused in five consecutive runs without obvious loss of activity.

Simultaneous determination of dopamine and ascorbic acid at an in-site functionalized self-assembled monolayer on gold electrode

The in-site functionalization of 4-aminothiophenol (4-ATP) self-assembled monolayer on gold electrode at physiological pH yields a redox active monolayer of 4'-mercapto-N-phenylquinone diimine (MNPD). The functionalized electrode exhibits excellent electrocatalytic responses towards dopamine (DA) and ascorbic acid (AA), reducing the overpotentials by about 0.22 V and 0.34 V, respectively, with greatly enhanced current responses. Due to its different catalytic activities toward DA and AA, the modified electrode resolves the overlapping voltammetric responses of DA and AA into two well-defined voltammetric peaks by differential pulse voltammetry (DPV), which can be used for the simultaneous determination of these species in a mixture. The catalytic peak current obtained from DPV was linearly related to DA and AA concentration in the ranges of 5.0 x 10-6 - 1.25 x 10-4 M and 8.0 x 10-6 - 1.3 x 10-4 M with correlation coefficient of 0.999 and 0.998, respectively. The detective limits (3sigma) for DA and AA were found to be 1.2 x 10-6 M and 2.4 x 10-6 M, respectively.

Y_2O_3∶Eu~(3+)纳米线阵列的制备与表征

Y2 O3∶ Eu3+红色荧光粉由于色纯度高、化学性质稳定和量子效率接近 1 0 0 %而广泛用于荧光灯和投影电视等方面 .近年来 ,Y2 O3∶Eu3+的大量研究工作主要集中于纳米粉末的制备方法及其与体相材料不同的发光特性 [1～ 3] .最近 ,有关 Y2 O3∶ Eu3+及其稀土化合物的纳米管、纳米线和纳米带一维材料的制备成为研究热点 . Wu Changfeng等[4 ,5] 利用表面活性剂合成了 Y2 O3∶ Eu3+纳米管 .激光格位选择激发测试结果表明 ,Eu3+在纳米管中占据 3个不同的格位 ,其 61 1 nm处的红色发光峰出现了宽化 .HeYu等 [6 ] 采用水热法及退火处理制备出了 Y2 O3∶ Eu3+纳米带 ,发现 Eu3+的发射峰不仅宽化 ,而且出现了 62 5 nm的新峰 .Li Yadong等 [7～ 9]采用水热法制备了稀土氧化物、硫氧化物和氢氧化物等的纳米线和纳米管 ,并探索了其形成机理 ,同时发现 Y2 O3S∶ Yb3+,Er3+具有上转换的性质 .制备各种类型的一维纳米材料的目的之一是为了进一步组装出如纳米阵列材料等功能结构 ,最终实现纳米器件的制作 ,但上述制备方...

Isothermal melt and cold crystallization kinetics of poly(aryl ether ether ketone ketone) (PEEKK)

Isothermal melt and cold crystallization kinetics of PEEKK have been investigated by differential scanning calorimetry in two temperature regions. During the primary crystallization process, the relative crystallinity develops with a time dependence described by the Avrami equation, with exponent n = 2 for both melt and cold crystallization. The activation energies are -544.5 and 466.7 kJ/mol for crystallization from the melt and amorphous glassy state, respectively. The equilibrium melting point T-m(o) is estimated to be 371 degrees C by using the Hoffman-Weeks approach. The lateral and end surface free energies derived from the Lauritzen-Hoffman spherulitic growth rate equation are sigma=10 erg/cm(2) and sigma(e) = 60 erg/cm(2), respectively. The work of chain folding q is determined as 3.98 kcal/mol. These observed crystallization kinetic characteristics of PEEKK are compared with those of PEEK. (C) 1997 Elsevier Science Ltd.

[Cp_2ErCl(THF)]_2的晶体结构

本文报导了(Cp_2ErCl(THF)]_2的晶体结构,晶体属单斜晶系,P2_1/c空间群。晶胞参数为a=8.141(2),b=21.218(6),c=8.597(2),β=107.77(2)°;V=1414.1(6) ~3;Z=2,D_c=1.90g/cm~3,F(000)=780,μ_c=66.3cm~(-1)(MoK_a)。最终的偏离因子R=0.047,R_(to)=0.048。结构分析表明,该配合物是以两个氯离子与金属离子桥联的二聚体形式存在。四氢呋喃中的氧原子同金属离子键合,Er—O键长为2.490(6),两个环戊二烯中的所有碳原子同金属离子间的平均键长为2.649,Er-Cl=2.666(3),Er—Cl-a=2.797(3),Er-Er_a=4.42,Cl-Er-Cl_a键角为72.2°。