47 resultados para Carnot, Lazare, 1753-1823.
Resumo:
本发明涉及一种鱇白鱼的池塘人工驯养方法,属鱼产品养殖技术领域。鱇白鱼的池塘人工驯养方法为先用消毒剂对池塘进行清塘,随后放入清水,其水深为0.8米,此时将鱼苗放入池中,驯养期间水温在8-25℃,鱼苗投喂时间为每日二次,投喂的饲料分别为:一个月前喂蛋黄或轮虫,随后喂蛋黄、豆浆和混合饲料,5个月后投喂混合饲料,饲料的喂量为蛋黄每次5个,豆浆每天0.5公斤黄豆研磨成浆,混合饲料早期每次1公斤,随着鱼体长大酌情增量。采用本鱇白鱼的池塘人工驯养方法,具有操作简便,成本低廉,鱼苗成活率高,并将在自然状况下,生长到5厘米左右时便进入40-50米的深水区生长发育,直到性成熟后才洄游到浅水区的砾石砂滩和溶洞出水口处产卵的抚仙湖特有鱼类——鱇白鱼驯化成为一种池塘人工养殖品种等优点。
Resumo:
Carbon modified by the reduction of aromatic diazonium derivatives was first used as electrode for the electrochemical stripping analysis of heavy metals. As a model, the glassy carbon electrode was modified with benzoic acid by electrochemical reduction of diazobenzoic acid, and the resulting modified electrodes were used for determination of Cd2+ and Pb2+. The anodic peak currents of cadmium and lead at the benzoic acid-modified glassy carbon electrode are 7.2 and 6 times of that at the bare glassy carbon electrode. A linear response was observed for Pb2+ and Cd2+ in the range of 0.5-50 mu g/l.
Resumo:
Non-ionic surfactant Triton X-100 was used as a stabilizer to prepare PtRu/C catalysts for methanol oxidation reaction (MOR). The cyclic voltammogram was used to investigate the catalytic activity for MOR of different PtRu/C catalysts. TG-DTA, EDX, XRD, XPS and TEM were Used to characterize the composition, structure and morphology of the as-prepared PtRu/C catalysts. It is found that the heat treatment plays a crucial role in the particles size, particles distribution of the PtRu/C catalysts and the oxidation state of platinum. The results show that 350 degrees C is an optimum heat treatment temperature. The as-synthesized catalyst heat-treated at this temperature exhibits the best catalytic performance for MOR.
Resumo:
Facilitated proton transfer across the water/1,2-dichloroethane (DCE) interface supported on the tips of micro- and nano-pipets by o-phenanthroline (Phen) was studied by using cyclic voltammetry. The formed micro- and nano-liquid/liquid interfaces functioned as micro- and nano-electrodes under certain experimental conditions. The dependence of the half-wave potentials on the aqueous solutions acidities was studied and the ratio of association constants between Phen and proton in the aqueous and DCE phases was calculated by the method proposed by Matsuda et al.. The standard rate constant (k(0)) and the transfer coefficient (alpha) evaluated by using nano-pipets were equal to 0.183 +/- 0.054 cm/s and 0.70 +/- 0.09, respectively.
Resumo:
利用循环伏安法研究了玻璃微米 /纳米管支持的水 / 1 ,2 -二氯乙烷 ( DCE)界面上邻菲咯啉加速质子的转移过程 .将装有水溶液的微米 /纳米管插入到 DCE溶液中 ,可以形成微米 /纳米级 -液 /液界面 ,在选定的实验条件下 ,其作用类似于微米 /纳米电极 .用微米管考察了此加速转移过程的半波电位与 p H值 ( 1 .1~7.5 )的关系 ,利用 Matsuda等提出的理论公式计算了邻菲咯啉与质子在有机相和水相中的络合常数比 .并用纳米管计算得到邻菲咯啉加速质子在水 / DCE界面转移过程中的标准速率常数 ( k0 )和转移系数 (α)分别为( 0 .1 83± 0 .0 5 4 ) cm/ s和 0 .70± 0 .0
Resumo:
Macrocyclic arylene ether ketone dimer was isolated from a mixture of cyclic oligomers obtained by the nucleophilic substitution reaction of bisphenol A and 4,4'-difluorobenzophenone and easily polymerized to high molecular weight linear poly(ether ketone). The cyclic compound was characterized by FTIR, H-1- and C-13-NMR, and single-crystal x-ray diffraction. Analysis of the spectral and crystal structure reveals extreme distortions of he phenyl rings attached to the isopropylidene center and of the turning points of the molecular polygons. The release of the ring strain on ring-opening combined with entropical difference between the linear polymer chain and the more rigid macrocycle at temperatures of polymerization may be the proposed motivating factors in the polymerization of this precursor to high molecular weight poly(ether ketone). (C) 1997 John Wiley & Sons, Inc.
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合成了八-4-(四氢糠氧基)酞菁钕(Ⅲ)(A)、八-4-(β-萘氧基)酞菁钕(Ⅲ)(B)、八-4-(2,4-二叔戊基苯氧基)酞菁钕(Ⅲ)(C)和八-4-(2,4-二叔戊基苯氧基)酞菁镨(Ⅲ)(D)4种新的稀土(Nd、Pr)(Ⅲ)双酞菁衍生物,经元素分析、红外光谱、核磁共振谱表征.紫外可见光谱表明,它们在氯仿(10 ̄(-6)mol/L)溶液中以单分子形式存在.热重分析证明配合物的热稳定性:B>C~D>A.4种配合物成膜性好,Z型沉积形成的单层LB膜材料对氨气有响应,特别是八-4-(四氢糠氧基)酞菁钕(Ⅲ)的膜材料对氨气很敏感,可与铜酞菁LB膜气敏性相比.
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The ecological characteristics of the deep-sea amoA-encoding archaea (AEA) are largely unsolved. Our aim was to study the diversity, structure and distribution of the AEA community in the sediments of the tropical West Pacific Continental Margin, to develop a general view of the AEA biogeography in the deep-sea extreme environment. Archaeal amoA clone libraries were constructed. Diverse and novel amoA sequences were identified, with the Bohol Sea, Bashi Strait and Sibuyan Sea harbouring the highest and the Bicol Shelf the lowest AEA diversity. Phylogenetic and statistical analyses illustrate a heterogeneous distribution of the AEA community, probably caused by the differential distribution of the terrestrial or estuarine AEA in the various sampling sites. The deep-sea sedimentary environments potentially harbour diverse and novel AEA in the tropical West Pacific Continental Margin. The stations in the Philippine inland seas (including station 3043) may represent AEA assemblages with various terrestrial influences and the stations connected directly to the open Philippine Sea may represent marine environment-dominant AEA assemblages. Our study indicates the potential importance of geological and climatic events in the transport of terrestrial micro-organisms to the deep-sea sedimentary environments, almost totally neglected previously.
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Analyses of rare earth and trace element concentrations of native sulfur samples from the Kueishantao hydrothermal field were performed at the Seafloor Hydrothermal Activity Laboratory of the Key Laboratory of Marine Geology and Environment, Institute of Oceanology, Chinese Academy of Sciences. Using an Elan DRC II ICP-MS, and combining the sulfur isotopic compositions of native sulfur samples, we studied the sources and formation of a native sulfur chimney. The results show, when comparing them with native sulfur from crater lakes and other volcanic areas, that the native sulfur content of this chimney is very high (99.96%), the rare earth element (REE) and trace element constituents of the chimney are very low (Sigma REE < 21x10(-9)), and the chondrite-normalized REE patterns of the native sulfur samples are similar to those of the Kueishantao andesite, implying that the interaction of subseafloor fluid-andesite at the Kueishantao hydrothermal field was of short duration. The sulfur isotopic compositions of the native sulfur samples reveal that the sulfur of the chimney, from H2S and SO2, originated by magmatic degassing and that the REEs and trace elements are mostly from the Kueishantao andesite and partly from seawater. Combining these results with an analysis of the thermodynamics, it is clear that from the relatively low temperature (< 116 degrees C), the oxygenated and acidic environment is favorable for formation of this native sulfur chimney in the Kueishantao hydrothermal field.
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企业管理信息系统 (EMIS) 是 CIMS 的重要组成部分.随着企业环境的演变,不仅应研究各种批量生产方式的管理方法,更应注意一样一件 (OKP) 生产方式.企业对 CIMS 环境中 EMIS 的需求不断增长,它比普通的 EMIS 更复杂.本文首先对 MRPⅡ的应用开发进行分析,认为应吸取 MRPⅡ的核心部分开发适合国情的 EMIS 产品;然后提出了 EMIS 的通用概念结构及子系统的划分.这一通用概念结构已用于沈阳鼓风机厂的 CIMS 初步设计中.
Resumo:
尽管西南岩溶地区石漠化趋势严重,但真正做到生态、经济、社会三效益统一的岩溶石漠化生态重建模式的实践工作却做得很少。且对于这些实践活动还缺乏理论的总结和思考。花江峡谷顶坛片区,充分利用当地的适生植物资源和干热资源优势在石漠化土地上种植花椒、砂仁等喜热耐旱的经济作物,在恢复和治理生态的前提下成功调整了农业内部结构,形成以花椒规模种植为核心心的特色产业,利用雨水、坡面水、岩溶裂隙水,实行参与式社区管理,使环境、经济与社区文化得以可持续发展。“顶坛”模式是充分利用岩溶环境资源优势,高山地保护于特色农业开发之中的一个成功例子。它启示我们,岩溶石漠化土地恢复重建必须重新认识岩溶环境优势。因地制宜,对过去侧重于水土保持的传统治理模式进行创新。
Resumo:
对安徽省冬瓜山层控夕卡岩型铜(金)矿床中穿层方向上不同蚀变程度的大理岩,顺层方向上距岩体远近不同但垂向深度的块状石榴子石夕卡岩及其主矿物石榴子石,不同演化阶段的石英及矿石等到的REE特征进行了系统研究,结果显示,在穿层方向上,大理岩被交代的程度愈深其稀土总量(∑REE)愈高,Eu负异常愈显著,尽管,夕卡岩全岩的RE分布模式与原岩(大理岩)相似,但前者的稀土总量(∑REE)远高于后者,且Eu异常更为显著,显然不是继续承原岩的REE特征所致,而是受控于其主矿物石榴子石的REE特征,后者又由参与交代作用的岩浆热液REE所决定,热液中的REE具有缓和右倾型分布模式,LREE富集,较显著的Eu负异常等基本特征,石榴子石晶体基本承袭了热液的REE特征,REE的空间变化特征结果地层的构造特征可以揭示夕卡岩及相关矿体形成过程中流体的输运径及输运方式,REE的研究有助于深化对层控夕卡岩及其相关矿床形成过程的认识。