黑土区县域生态工程建设对农业景观的调控

近年来,东北典型黑土区的水土流失问题得到了广泛的关注。该文运用景观生态学的空间分析方法,在地理信息系统GIS支持下,以1989年和2002年陆地资源卫星LandsatTM为主要信息源,结合测绘图件、统计数据及野外调查,分析黑土侵蚀区典型县域(拜泉县)生态恢复与重建的景观结构和水土保持效应。研究结果表明从1989到2002年,研究区耕地面积下降24731.01hm2,林草地面积增加了13567.53hm2,林网进一步完善,水库和塘坝数量由88座增加到1490座。全县55%的水蚀面积得到治理,82.2%的风蚀农田得到林网的防护,43.7%的景观地表超渗径流得到集蓄利用,大于1.5°坡耕地泥沙径流拦截面积增加1420.10hm2。大规模生态建设下,区域景观类型数量和空间配置发生了较大的变化,景观结构的调整对其水土保持功能起到了很好的调控作用。

沙地云杉生态型对干旱胁迫的生理生态响应

采用干旱胁迫处理不同生态型沙地云杉幼苗,对其主干高生长、丙二醛(MDA)、脯氨酸和叶绿素含量进行了测定。结果表明,沙地云杉幼苗高生长明显受到干旱胁迫的抑制,绿果型沙地云杉在水分条件良好的情况下,高生长迅速,明显高于紫果型沙地云杉。随着干旱胁迫强度的增强,其高生长受抑制的程度高于紫果型沙地云杉。红果型沙地云杉处于二者之间。同时干旱胁迫也影响沙地云杉生长进程,使得其封顶时间提前一个多月,MDA含量无论在叶还是根中呈上升趋势,只是在土壤含水量在10％左右出现轻度胁迫时略有下降;叶片中MDA含量明显高于根中;从不同生态型来看,紫果型沙地云杉体内MDA含量高,绿果型低且具有较大的变化幅度。脯氨酸含量随干旱胁迫强度增加而增加;绿果型沙地云杉根部脯氨酸含量在处理4之前高于另外两种生态型,叶绿素的变化规律,紫果型和红果型沙地云杉基本相同,只是红果型含量略微低于紫果型,其叶绿素a、叶绿素b和总叶绿素含量都是开始逐渐升高;随着胁迫强度增加,叶绿素含量下降;绿果型沙地云杉叶绿素含量总体上都呈下降趋势,只有叶绿素b含量在胁迫初期有所增加。从叶绿素a/b值出现下降趋势,但不同生态型表现不一样。绿果型沙地云杉由最高下降到最低,紫果型沙地云杉下降幅度较小,红果型介于二者之间。表明不同

试论生态分类系统在我国天然林保护与经营中的应用

我国林业的发展正面临前所未有的机遇和挑战。现有资料表明 ,一方面 ,我国林业的宏观政策以及森林的采伐更新过程缺乏基本生态学原理的支持 ;另一方面 ,仅研究生态学理论还不够 ,还要研究把生态学理论转化为生产力的工具。生态分类系统是确定、描述和绘制生态系统类型图的方法。应用这种多层次系统的目的是用图的形式把森林景观的生物和环境特征抽象化、综合化、标准化和整体化 ,以实现生态系统管理的目标。通过绘制各种景观特征 ,林业人员可以根据土地承载力及适应性确定森林的经营方向和经营措施。生态分类系统在吉林省东部针阔混交林区试验应用

21世纪初中国土地利用变化的空间格局与驱动力分析

在全球环境变化研究中,以土地利用与土地覆盖动态为核心的人类-环境耦合系统研究逐渐成为土地变化科学(LCS)研究的新动向。基于覆盖中国21世纪初5年间隔的遥感卫星数据获取的1km网格土地利用变化空间信息,依据近5年土地利用变化区域分异的显著特征,以及自然地理、经济发展与国家宏观政策因素综合考虑,设计针对21世纪初5年新的中国土地利用动态区划图,揭示土地利用变化的空间格局与驱动因素。总体上,21世纪初5年中国处于土地利用快速变化期,黄淮海平原、东南沿海地区与四川盆地城乡建设用地显著扩张,占用大规模优质农田,导致南方水田面积明显减少;西北绿洲农业发展与东北地区开垦导致北方旱地面积略有增加;受西部开发"生态退耕"政策的影响中西部地区林地面积显著增加,国家退耕还林还草政策成效明显,对区域土地覆盖状况的改善产生积极的影响;这一时段国土开发与区域发展战略的实施,包括"西部大开发"、"东北振兴"等国家重大政策,加之快速的经济发展是该阶段土地利用变化格局形成的主要驱动因素。

Screening and Structural Characterization of alpha-Glucosidase Inhibitors from Hawthorn Leaf Flavonoids Extract by Ultrafiltration LC-DAD-MSn and SORI-CID FTICR MS

In vitro a-glucosidase inhibition assays and ultrafiltration liquid chromatography with photodiode array detection coupled to electrospray ionization tandem mass spectrometry (ultrafiltration LC-DAD-ESI-MSn) were combined to screen a-glucosidase inhibitors from hawthorn leaf flavonoids extract (HLFE). As a result, four compounds were identified as alpha-glucosidase inhibitors in the HLFE, and their structures were confirmed to be quercetin-3-O-rha-(1-4)-glc-rha and C-glycosylflavones (vitexin-2 ''-O-glucoside, vitexin-2 ''-O-rhamnoside and vitexin) by high-resolution sustained off resonance irradiation collision-induced dissociation (SORI-CID) data obtained by Fourier transform ion cyclotron resonance mass spectrometry (FTICR MS).

(Ce_(0.9)Nd_(0.1))_(1-x)Mo_xO_(2-δ)(0.00≤x≤0.10)的合成、表征与电性能

采用溶胶-凝胶法合成(Ce0.9Nd0.1)1-xMoxO2-δ(x=0.00、0.02、0.05、0.10)氧化物,通过X射线衍射(XRD)、场发射扫描电镜(FESEM)等手段对氧化物进行结构表征,交流阻抗谱测试电性能.结果表明:所有样品均为单一萤石立方结构;少量MoO3的加入提高了材料的致密性,降低了材料的总电阻、晶界电阻和晶界电阻在总电阻中所占比例,提高了材料的电导率.1200℃烧结样品24h,测试温度700℃时,(Ce0.9Nd0.1)1-xMoxO2-δ(x=0.00)总电导率和晶界电导率分别为0.05和0.19S·m-1,掺Mo材料(Ce0.9Nd0.1)1-xMoxO2-δ(x=0.02)的总电导率和晶界电导率分别为2.42和3.96S·m-1.

Sintering of nanopowders of amorphous silicon nitride under ultrahigh pressure

Nanopowders of amorphous silicon nitride were densified and sintered without additives under ultrahigh pressure (1.0-5.0 GPa) between room temperature and 1600 degrees C. The powders had a mean diameter of 18 nm and contained similar to 5.0 wt% oxygen that came from air-exposure oxidation, Sintering results at different temperatures were characterized in terms of sintering density, hardness, phase structure, and grain size. It was observed that the nanopowders can be pressed to a high density (87%) even at room temperature under the high pressure. Bulk Si3N4 amorphous and crystalline ceramics (relative density: 95-98%) were obtained at temperatures slightly below the onset of crystallization (1000-1100 degrees C and above 1420 degrees C, respectively. Rapid grain growth occurred during the crystallization leading to a grain size (>160 nm) almost 1 order of magnitude greater than the starting particulate diameters, With the rise of sintering temperature, a final density was reached between 1350 and 1420 degrees C, which seemed to be independent of the pressure applied (1.0-5.0 GPa), The densification temperature observed under the high pressure is lower by 580 degrees C than that by hot isostatic pressing sintering, suggesting a significantly enhanced low-temperature sintering of the nanopowders under a high external pressure.

Enhanced crystallization and phase transformation of amorphous silicon nitride under high pressure

The crystallization and phase transformation of amorphous Si3N4 ceramics under high pressure (1.0-5.0 GPa) between 800 and 1700 degreesC were investigated. A greatly enhanced crystallization and alpha-beta transformation of the amorphous Si3N4 ceramics were evident under the high pressure, as characterized by that, at 5.0 GPa, the amorphous Si3N4, began to crystallize at a temperature as low as 1000 degreesC (to transform to alpha modification). The subsequent alpha-beta transformation occurred completed between 1350 and 1420 degreesC after only 20 min of pressing at 5.0 GPa. In contrast, under 0.1 MPa N-2, the identical amorphous materials were stable up to 1400 degreesC without detectable crystallization, and only a small amount of a phase was detected at 1500 degreesC. The crystallization temperature and the alpha-beta transformation temperatures are reduced by 200-350 degreesC compared to that at normal pressure. The enhanced phase transformations of the amorphous Si3N4, were discussed on the basis of thermodynamic and kinetic consideration of the effects of pressure on nucleation and growth.

Crystal Structure of [PrAl(CF3COO)(2)(CF3CHOO)(C2H5)(2)(C4H8O)(2)](2)

[PrAl (CF3COO)(2) (CF3CHOO) (C2H5)(2) (C4H8O)(2)](2) M-r = 1420. 56, monoclinic, P2(1)/n, a = 10. 651 (6) , b = 24. 276(9), c = 11. 110(5) Angstrom, beta = 107. 650 (4)degrees , V = 2737. 4(1) Angstrom (3) , Z = 2, D-c = 3. 45 g/cm(3) , F(000) = 2816 , T = 233K, MoK alpha radiation (lambda= 0. 71069 Angstrom), mu(MoK alpha) = 38. 017 cm(-1) , R = 0. 048 for 2847 observed reflections (I greater than or equal to 3 sigma(I)). It is isostructural with [LnAl (CF3COO)(2) (CF3CHOO) -R-2 (C4H8O)(2)](2) (Ln = Ho, R = Et; Ln = Ndt Y, R = Bu-1). Pr3+ is coordinated by eight oxygen atoms from five bridging ligands and two THF forming a distorted bicap-prism.

SYNTHESIS AND MOLECULAR-STRUCTURE OF (CH3CP)2YB.DME AND ITS CATALYTIC ACTIVITY FOR THE POLYMERIZATION OF METHYL-METHACRYLATE

The complex of (CH3Cp)2Yb . DME (DME = dimethoxyethane) has been synthesized by the reduction with metallic sodium of the corresponding chloride (CH3CP)2YbCl. (CH3CP)2Yb . DME crystallized from DME in the monoclinic space group Cm, with cell constants a = 11.068(3), b = 12.338(4), c = 12.479(4) angstrom; beta = 100.51(2)-degrees, V = 1675(l) angstrom3, and D0 = 1.66 g/cm3 for Z = 4. Least-squares refinement of 1420 unique observed reflections led to final R of 0.0487. This complex can be used as a catalyst for the polymerization of methyl methacrylate (MMA).

高分子科学研究和技术开发的重要基地

中国科学院长春应用化学研究所座落在吉林省长春市风景秀丽的南湖之畔,是国内大型综合性化学学科科研机构之一。它的前身是建于30年代的日伪大陆科学研究院,1948年10月长春解放,1948年12月正式建所。全所现有职工1420人,其中学部委员3人,高级科技人员300多人。中级科技人员600多人,全所设有24个研究