激光拼焊生产线定位误差分析及其控制

对激光拼焊生产线板材定位精度进行了分析与研究。详细介绍了该系统定位装置的组成及定位原理。通过对板材自身直线度误差、定位销定位误差和对中运动误差的分析,建立了激光拼焊生产线板材定位误差模型。根据系统定位机构特点提出了过盈量作用机制来提高定位精度,通过对前后侧压紧力F1、F2以及过盈量I这3个主要参数的优化,在全自动激光拼焊生产线上实现良好的板材定位精度。对比试验验证了采用过盈量作用机制能有效减小板材定位误差,提高焊接质量。

激光拼焊错边产生与预测建模方法

错边是评定激光拼焊质量的一个非常重要的指标,薄板构件错边的控制是激光拼焊中一个难题。针对国内首条全自动激光拼焊设备,对错边的产生以及控制方法进行了深入研究,经过大量试验确定了影响错边大小的几个主要因素,板材自身物理变形、压紧力大小与均匀性、压紧横梁变形、支撑底板平面度误差以及焊接变形的影响。通过分析以上因素对错边的影响以及各个因素之间相互关系,建立了错边预测的数学模型。试验验证了模型的正确性,从而为确定错边产生原因,提高焊接质量提供了一个有效的理论指导。

PLC在长焊缝激光拼焊系统中的应用

介绍了长焊缝激光拼焊系统的工作原理和控制要求。针对长焊缝激光拼焊的难点,提出了焊缝塑性成形原理,采用碾压轮对板材焊缝进行碾压预处理提高定位精度。阐述了牵引电机同步控制原理和碾压轮力控制原理。详细介绍了该系统的组成和工作原理,确定了以三菱PLC为核心的长焊缝激光拼焊的控制系统,说明了其硬件组成、软件设计和控制系统的抗干扰措施。

基于PLC的激光拼焊生产线控制系统设计

本文介绍了基于PLC的激光拼焊生产线控制系统。分析了激光拼焊生产工艺过程,针对激光拼焊生产过程中多工作单元相互协调和工业过程复杂等特点,开发了基于三菱PLC的控制系统,介绍了系统的软硬件设计方法。该系统能够完成上料、定位、压紧、焊接、检测、下料以及废料处理功能,实现了激光拼焊生产线的全自动化,具有较高的安全性和稳定性。

基于三坐标测量机激光拼焊板材直线度研究

利用高精度三坐标测量机扫描功能,充分获得焊接板材端面线性三维数据坐标值,采用基于最小二乘法而建立的理想直线数学模型来评定直线度误差,并与实际采用塞尺法进行对比,结果发现采用三坐标测量更能详尽地反应整个焊接边缘直线度真实情况,节省大量的数据处理时间,且数据更加准确可靠,并在实际激光焊接中获得良好激光焊缝,同时直观地给出了焊接板材边缘线性特征,为剪板机刀具调整提供了方向与位置。

基于多智能体的制造系统生产控制建模研究

为提高制造系统生产控制的性能,建立了基于多智能体系统的混合控制模型。该模型把生产控制系统分为管理智能体层、单元智能体层和执行智能体层。管理智能体层负责调度和协调各单元智能体,并对所有智能体进行管理;单元智能体层中的各单元智能体间通过公用数据库相互协作;执行智能体对制造系统内的硬件负责,它们根据局部的本地资源信息及当前状态,接收发布的任务,并对其求解。同一层次的智能体之间是分布式结构。采用基于多智能体的混合控制模式,提高了制造系统生产控制的实时性和灵活性。通过激光拼焊生产系统中的试验,验证了该模型的有效性。

基于PMAC开放式数控系统软件开发

基于PC和多轴运动控制器的开放式数控系统是理想的开放式数控系统。介绍了基于PMAC的开放式数控系统结构形式,PMAC的差补、位置控制、伺服功能、以PMAC和PC机为硬件平台搭建了数控系统,并对其硬件构成和软件设计结构进行了分析。着重从软件设计的角度,介绍了PTALK控件的功能和作用,对数控系统软件构成进行了详细的阐述。并设计出了友好的用户界面,在实际应用中具有重要意义。

激光拼焊成套装备定位方法及焊接工艺研究

激光拼焊由于具有能量密度高，焊缝深宽比大，变形和热影响区小，焊接速度快，满足工件不同部位对材料各自性能的需求，焊接质量好，容易实现自动化等众多优点，使其广泛应用于工业中各个领域。激光拼焊生产线是利用高能激光作为焊接热源，将两块或多块汽车板材一次焊接成形，实现高效全自动化生产，年产可达百万片，以满足汽车行业的需求。而我国作为世界制造加工大国，目前尚不能完全独立自主开发激光拼焊成套装备。 针对自主开发激光拼焊成套装备的几个关键技术点，本文以中国科学院知识创新工程重要方向性项目“全自动激光拼焊成套装备关键技术研究与示范应用”为课题背景，结合项目实际开发中的具体要求，在对现有激光拼焊技术深入分析的基础上，对激光拼焊定位夹紧、最优化激光拼焊工艺和焊接接头机械性能、金相组织等方面进行了深入研究，得出了激光拼焊最优工艺规范和相应的焊接质量变化规律，为激光拼焊成套装备开发提供参考。 第一部分激光拼焊定位夹紧对中方法研究。重点分析了由于激光光束本身条件限制、激光拼焊生产线高速高效的要求、激光焊接热变形和目前国内汽车板材本身理化性能一致性差以及激光焊接过程中的诸多不确定因素，总结出了激光拼焊生产线工装夹具设计影响因素，并在此基础上指出了激光拼焊定位夹紧结构所应具备的功能特征。针对激光拼焊板材介于刚体和弹性体之间的柔性体特征，结合传统的定位原理“3-2-1”，提出了“N-2-1”的定位方式，给出了激光拼焊夹具定位原理及设计准则，初步建立了激光拼焊夹具参数化零件库和相应准则，并对激光拼焊夹紧机构进行了柔性分析，给出了拼焊夹具的柔性评价方案。 第二部分激光拼焊工艺研究。首先分析了激光拼焊工艺特征，重点研究了在大功率固态激光器条件下，激光拼焊焊接工艺参数主要包括激光功率、焊接速度、离焦量和侧吹保护气体的喷嘴高度、倾斜角度及气体流量等因素变化对焊接质量的影响，得出了变化规律曲线，为激光拼焊工艺规范微调方向提供参考依据;同时也为激光工艺库开发提供推理机制。最后系统全面地研究了目前汽车常用板材全厚度系列激光拼焊工艺，采用叠代寻优的方法获得到了适用于全自动激光拼焊生产线的最优化工艺规范。 第三部分激光拼焊工艺库开发。针对激光拼焊成套装备项目开发面临的问题：在中国市场中，激光拼焊成套装备销售必须附带汽车行业常用工艺规范库的现实问题。在大量试验的基础上，借助于VB6.0集成开发环境，建立了激光拼焊工艺库系统，主要包括激光拼焊示范应用模块、工艺参数查询模块、经济评估模块、数据库维护模块、管理查询模块等，初步实现了系统演示、查询、评估、管理等功能，基本满足激光拼焊生产线要求。 第四部分激光拼焊焊接接头金相组织性能研究。结合金属Fe3C相图，分析了在激光焊接快速冷却、大过冷度条件下，分别从合金性质、成分、固/液界面上的表面能、均相成核速度和固相生长速度等角度，探讨了金相组织结构变化特征。然后通过试验分别研究了汽车碳钢板和不锈钢板激光拼焊时，板材厚度、激光功率、焊接速度等工艺参数变化，对激光拼焊焊接接头的抗拉强度、显微组织硬度和金相组织结构影响。 第五部分针对激光拼焊钢板实际生产中，存在着焊接性能随焊接工艺变化差异大的问题，利用激光拼焊生产线实际得到的数据，建立了基于BP神经网络激光拼焊焊接性能预测模型，初步实现了根据工艺参数的改变，直接预测焊接力学性能的目的，克服了激光拼焊初期需大量试验性研究的缺点，为工艺参数优化研究提供了一种有效的手段。

激光拼焊焊缝质量在线检测技术研究

激光拼焊作为一种新的高质量焊接技术，已经广泛应用于汽车，航空、造船等领域，对提高我国装备制造水平有重要意义。激光拼焊过程中由于焊接装置与焊接工艺的一些时变因素，导致焊接质量存在一定波动，因此，必须对焊缝进行在线实时质量检测，这不仅可以保证焊接质量，而且有助于实现焊接的自动化。目前，国外成熟的激光拼焊系统中，焊缝质量实时检测技术已经成为实现激光拼焊自动化的关键部分。但该项技术国内目前仍处于研究阶段。因此，研制应用于激光拼焊的焊缝质量实时检测系统，实现焊接过程的自动化在学术理论性及工程应用性上具有重要研究意义。本文以激光拼焊为背景，针对激光焊接焊缝质量检测中存在的科学问题和实际应用需求，参考了国外先进的焊缝质量检测系统，应用机器视觉原理对焊缝质量检测方法进行了研究。 本文首先介绍了基于结构光视觉检测原理建立的焊缝质量检测系统。其次重点研究了焊缝质量检测系统的图像处理算法。图像处理算法是整个检测系统的核心内容，其处理的速度与精度直接影响到系统的实时性与准确性。本文依据ISO13919-1 B级焊缝质量标准设计了基于结构光的焊缝图像处理算法。算法主要分三步：首先准确提取结构光光纹中心线，其次提取光纹中心线特征点，最后，根据光纹的几何形状以及所提取的特征点，计算焊缝缺陷参数。第二部分系统介绍了结构光视觉传感器的标定原理及方法，针对激光拼焊焊缝质量检测应用需求，研究了焊缝质量检测视觉传感器直接标定方法。并设计了标定方法的具体实现，通过在局部区域建立光平面到像平面之间的线性函数关系，像平面中的任意一个像点对应的物理坐标，可以通过线性插值算出。实验结果表明，标定精度可以满足激光拼焊质量检测系统的精度要求，且便于工程实现。第三部分针对激光拼焊质量检测需求，进行了焊缝质量检测系统的软、硬件设计及实现。重点研究了软件实现中的一些关键问题，如Windows实现检测系统的方法，进程、线程的优先级，三维重建等。最后在该检测系统实验平台上进行了图像处理算法的精度与速度的验证，实验结果表明图像算法结果满足系统要求。最后，本文对所做的研究工作进行了总结，并对今后的工作进行了展望。

大洋有孔虫微量元素研究

The most novel aspect of this thesis is the combination analysis of the boron isotopes and trace elements. What’s more, it also provides a reliable analytical technique, which is suitable for both boron isotopes and trace elements. Al/Ca values can be used to monitor the clay removal during the sample preparation. It is found that when Al/Ca>100 mol/mol, the measured boron isotopic compositions are always several permil lower than those properly cleaned. B/Ca ratios can be used to calculate the exact boron loaded for each sample. Otherwise, too much loading will lead to too long time for the whole analytical sequence, and too less loading might incur serious blank problem. One other benefit besides those discussed above is that the combination analysis of boron isotopes and trace elements on the same sample allows reconstruction of the marine carbonate system and atmospheric pCO2 without assumption of the other parameter. In the marine carbonate system, with the seawater pH from the foraminiferal 11B, one has to make an assumption on the other variable to obtain the rest four variables. A series studies found that U/Ca and B/Ca are potential proxies for seawater [CO32-]and [HCO3-], respectively. Since they are measured on the same sample with boron isotopes, hence, there is no spatial or temporal ambiguity in the incorporation of the two controlling parameters. With 11B and U/Ca, the reconstructed atmospheric pCO2 variations match the atmospheric pCO2 record from the Vostok ice core within ±20 ppm. The incorporations of U and B into foraminiferal carbonates are controlled by the overall growth rate of individual foraminifers and other possible factors. The reliable application of these proxies still require further calibrations. In a similar fashion, the combination analysis of boron isotopes and Mg/Ca also has great advantages. Mg/Ca has been proved to be a reliable proxy for the surface seawater temperature. With the combination analysis, one can determine the phase between changes in atmospheric pCO2 and surface seawater temperature, thus explore the cause and mechanism of the changes in atmospheric pCO2. .

Lu-Hf同位素的MC-ICP-MS实验方法及其在华北克拉通典型火山岩研究中的应用

Over past ten years, a great development has been made in the Lu-Hf isotopic system with the advent of MC-ICP-MS. Based on a comprehensive review of available references in the related field, a novel analytical protocol of three exchange chromatographies after one mixed acid attacking geological samples was developed in this work, which not only avoids common multiple sample treatments for natural inhomegeneous samples, but also is useful for Rb-Sr, Sm-Nd and Lu-Hf isotopic system simultaneously, especially for the garnet- and apatite-bearing rocks for the Sm-Nd and Lu-Hf geochronology. An analytical procedure for the Lu and Hf concentration in geological samples determined by by ID-MC-ICP-MS was detailedly investigated. The Hf yield is > 90 % and total procedural blank is less than. 50 pg for Hf and 10 pg for Lu, respectively. The developed method was successfully applied to the determination of Lu and Hf concentrations for USGS geological materials. A one-column procedure for Hf purification in geological samples using common anion exchange chromatography and its isotopic analyses by MC-ICP-MS were also established. Multiple analyses of Standard Reference Materials demonstrate that this method was simple, time-saving, cheap and efficient, especially suitable for the Hf isotopic compositions of young samples. Finally, the measurements of Sr and Nd isotopic compositions using Neptune MC-ICP-MS were described briefly, which indicates that Neptune MC-ICP-MS can precisely measure Sr and Nd isotopic compositions as the TIMS does, even more efficient and less time-consuming than the TIMS method. The Hf isotopic characteristics of typical volcanic rocks (Cenozoic Changle-Linqu basalts, Mesozoic Fangcheng basalts, Mesozoic Jianguo basalts, Mesozoic Wulahada high-Mg andesite, Cenozoic Fanshi, Zuoquan and Xiyang-Pingding basalts of the Taihang Mountains, Paleozoic diamondiferous Menyin and Fuxian Kimblites) from the North China Craton were firstly studied in this work. Coupled with Nd isotopic compositions, it shows that the Hf isotopes could be a better tracer for mantle sources than the Nd isotopes. Individual kimberlite fields from both the Mengyin and Fuxian regions have quite uniform Hf isotopic compositions, similar to the situation for the Nd isotopes.

内蒙古龙头山Ag-Pb-Zn多金属矿床成矿模式及找矿模型

The recent years research indicated that middle-south section of Da Hinggan Mountains metallogenic belt has two periods(Hercynian and Yanshanian) characteristics of metallogenesis, as well as the most of ore deposits in the area closely relate to Permian strata. Longtoushan ore deposit discovered in 2004 is an Ag-Pb-Zn polymetallic ore deposit born in Permian and located in the east hillside of the metallogenic belt, which has considerable resources potentials. It has important research value for its good metallogenic location and blank research history. Base on the detail field geology studies, the geology characteristics of "two stages and three kinds of metallogensis" has established. According to further work through geochemistry research including trace element, REE, S, Pb and Sr isotope, as well as petrography, microtemperature measurement, Laser Raman analysis and thermodynamics calculation of fluid inclusion, origin and characteristic of the ore-forming material and fluid has been discussed. And a new technology of single pellet Rb-Sr isochrones has been tried for dating its born time. Bae on above work, study of ore deposit comparison has been carried out, and metallogesis controlling factor and geological prospecting symbol have been summarized. Finally, metallogenic model and prospecting model have been established. According to above, the next step work direction has been proposed. Main achievement of the paper are listed as follow: 1.Longtoushan ore deposit has experienced two metallogenic periods including hot-water sedimentation period and hydrothermal reformation period. There are three kinds of metallizing phase: bedded(or near-bedded) phase, vein-shaped phase and pipe-shaped phase. The mian metallogenic period is hot-water sedimentation period. 2.Ore deposit geochemistry research indicated that the metal sulfides have charcateristic of hot-water sedimentation metallogensis, but generally suffered later hydrothermal transformation. The barite mineral isotope content is homogenous, showing the seabed hot-water sedimentation origin characteristic. Wall rock, such as tuff is one of metallogenic material origins. Both of Pb model age and Rb-Sr isochrone research older age value than that of strata, possibly for been influenced by hydrothermal transformation, and interfusion of ancient basis material. 3.There are two kinds of main metallogenic fluid inclusion in barite of the Longtoushan ore deposit, which are rich gas phase( C type) and liquid phase (D type). Their size is 2～7um, and principal components is H2O. Both kinds of fluid inclusion have freezing point temperature -7.1～-2.4℃ and -5.5～-0.3℃, salinity 4.0～10.6wt% and 0.5～8.5wt%, homogeneous temperature 176.8～361.6℃ and 101.4～279.9℃, which peak value around 270℃ and 170℃, respectively. Density of the ore-forming fluid is 0.73～0.97g/cm3, and metallogenic pressure is 62.3×105～377.9×105Pa. Above characteristic of the fluid inclusion are well geared to that of ore deposit originated in seabed hot-water sedimentation. 4.Through the comparison research, that Longtoushan ore deposit has main characteristic of hot-water sedimentation ore deposit has been indicated. Ore-forming control factor and prospecting symbol of it has been summarized, as well as metallogenic model and prospecting model. Next step work direction about prospecting has also been proposed finally.

铂族元素分析方法研究及其在有关地质问题中的应用

Characterization of Platinum Group Elements (PGE) has been applied to earth, space and environmental sciences. However, all these applications are based on a basic prerequisite, i.e. their concentration or ratio in the research objects can be accurately and precisely determined. In fact, development in these related studies is a great challenge to the analytical chemistry of the PGE because their content in the geological sample (non-mineralized) is often extremely low, range from ppt (10~(-12)g/g) to ppt (10~(-9)g/g). Their distribution is highly heterogeneous, usually concentrating in single particle or phase. Therefore, the accurate determination of these elements remains a problem in analytical chemistry and it obstructs the research on geochemistry of PGE. A great effort has been made in scientific community to reliable determining of very low amounts of PGE, which has been focused on to reduce the level of background in used reagents and to solve probable heterogeneity of PGE in samples. Undoubtedly, the fire-assay method is one of the best ways for solving the heterogeneity, as a large amount of sample weight (10-50g) can be hold. This page is mainly aimed at development of the methodology on separation, concentration and determination of the ultra-trace PGE in the rock and peat samples, and then they are applied to study the trace of PGE in ophiolite suite, in Kudi, West Kunlun and Tunguska explosion in 1908. The achievements of the study are summarized as follows: 1. A PGE lab is established in the Laboratory of Lithosphere Tectonic Evolution, IGG, CAS. 2. A modified method of determination of PGE in geological samples using NiS Fire-Assay with inductively coupled plasma-mass spectrometry (ICP-MS) is set up. The technical improvements are made as following: (1) investigating the level of background in used reagents, and finding the contents of Au, Pt and Pd in carbonyl nickel powder are 30, 0.6 and 0.6ng/g, respectively and 0.35, 7.5 and 6.4ng, respectively in other flux, and the contents of Ru, Rh, Os in whole reagents used are very low (below or near the detection limits of ICP-MS); (2) measuring the recoveries of PGE using different collector (Ni+S) and finding 1.5g of carbonyl nickel is effective for recovering the PGE for 15g samples (recoveries are more than 90%), reducing the inherent blank value due to impurities reagents; (3) direct dissolving nickel button in Teflon bomb and using Te-precipitation, so reducing the loss of PGE during preconcentration process and improving the recoveries of PGE (above 60% for Os and 93.6-106.3% for other PGE, using 2g carbonyl nickel); (4) simplifying the procedure of analyzing Osmium; (5)method detection limits are 8.6, 4.8, 43, 2.4, 82pg/g for 15g sample size ofRu, Rh, Pd, Ir, Pt, respectively. 3. An analytical method is set up to determine the content of ultra-trace PGE in peat samples. The method detection limits are 0.06, 0.1, 0.001, 0.001 and 0.002ng/mL for Ru, Rh, Pd, Ir and Pt, respectively. 4. Distinct anomaly of Pd and Os are firstly found in the peat sampling near the Tunguska explosion site, using the analytical method. 5. Applying the method to the study on the origin of Tunguska explosion and making the following conclusions: (1) these excess elements were likely resulted from the Tunguska Cosmic Body (TCB) explosion of 1908. (2) The Tunguska explosive body was composed of materials (solid components) similar to C1 chondrite, and, most probably, a cometary object, which weighed more than 10~7 tons and had a radius of more than 126 m. 6. The analysis method about ultra-trace PGE in rock samples is successfully used in the study on the characteristic of PGE in Kudi ophiolite suite and the following conclusions are made: (1) The difference of the mantle normalization of PGE patterns between dunite, harzburgite and lherzolite in Kudi indicates that they are residual of multi-stage partial melt of the mantle. Their depletion of Ir at a similar degree probably indicates the existence of an upper mantle depleted Ir. (2) With the evolution of the magma produced by the partial melt of the mantle, strong differentiation has been shown between IPGE and PPGE; and the differentiation from pyroxenite to basalt would have been more and more distinct. (3) The magma forming ophiolite in Kudi probably suffered S-saturation process.

中国大中型气田天然气成藏物理化学模拟研究

Natural gas pays more important role in the society as clean fuel. Natural gas exploration has been enhanced in recent years in many countries. It also has prospective future in our country through "85" and "95" national research. Many big size gas fields have been discovered in different formations in different basins such as lower and upper Paleozoic in Erdos basin, Tertiary system in Kuche depression in Tarim basin, Triassic system in east of Sichuan basin. Because gas bearing basins had been experienced multiple tectogenesis. The characteristics of natural gases usually in one gas field are that they have multiple source rocks and are multiple maturities and formed in different ages. There has most difficult to research on the gas-rock correlation and mechanism of gas formation. Develop advanced techniques and methods and apply them to solve above problems is necessary. The research is focused on the critical techniques of geochemistry and physical simulation of gas-rock correlation and gas formation. The lists in the following are conclusions through research and lots of experiments. I 8 advanced techniques have been developed or improved about gas-rock correlation and gas migration, accumulation and formation. A series of geochemistry techniques has been developed about analyzing inclusion enclave. They are analyzing gas and liquid composition and biomarker and on-line individual carbon isotope composition in inclusion enclave. These techniques combing the inclusion homogeneous temperature can be applied to study on gas-rock correlation directly and gas migration, filling and formation ages. Technique of on-line determination individual gas carbon isotope composition in kerogen and bitumen thermal pyrolysis is developed. It is applied to determine the source of natural is kerogen thermal degradation or oil pyrolysis. Method of on-line determination individual gas carbon isotope composition in rock thermal simulation has being improved. Based on the "95"former research, on-line determination individual gas carbon isotope composition in different type of maceral and rocks thermal pyrolys is has been determined. The conclusion is that carbon isotope composition of benzene and toluene in homogenous texture kerogen thermal degradation is almost same at different maturity. By comparison, that in mixture type kerogen thermal pyrolysis jumps from step to step with the changes of maturity. This conclusion is a good proof of gas-rock dynamic correlation. 3. Biomarker of rock can be determined directly through research. It solves the problems such as long period preparing sample, light composition losing and sample contamination etc. It can be applied to research the character of source rock and mechanism of source rock expulsion and the path of hydrocarbon migration etc. 4. The process of hydrocarbon dynamic generation in source rock can be seen at every stage applying locating observation and thermal simulation of ESEM. The mechanism of hydrocarbon generation and expulsion in source rock is discussed according to the experiments. This technique is advanced in the world. 5. A sample injection system whose character is higher vacuum, lower leaks and lower blank has been built up to analyze inert gas. He,Ar,Kr and Xe can be determined continuously on one instrument and one injection. This is advanced in domestic. 7. Quality and quantity analysis of benzene ring compounds and phenolic compounds and determination of organic acid and aqueous gas analysis are applied to research the relationship between compounds in formation water and gas formation. This is another new idea to study the gas-rock correlation and gas formation. 8. Inclusion analysis data can be used to calculate the Paleo-fluid density, Paleo-geothermal gradient and Paleo-geopressure gradient and then to calculate the Paleo-fluid potential. It's also a new method to research the direction of hydrocarbon migration and accumulation. 9. Equipment of natural gas formation simulation is produced during the research to probe how the physical properties of rock affect the gas migration and accumulation and what efficiency of gas migrate and factors of gas formation and the models of different type of migration are. II study is focused on that if the source rocks of lower Paleozoic generated hydrocarbon and what the source rocks of weathered formation gas pool and the mechanism of gas formation are though many advanced techniques application. There are four conclusions. 1.The maturity of Majiagou formation source rocks is higher in south than that in north. There also have parts of the higher maturity in middle and east. Anomalous thermal pays important role in big size field formation in middle of basin. 2. The amount of gas generation in high-over maturity source rocks in lower Paleozoic is lager than that of most absorption of source rocks. Lower Paleozoic source rocks are effective source rocks. Universal bitumen exists in Ordovician source rocks to prove that Ordovician source rocks had generated hydrocarbon. Bitumen has some attribution to the middle gas pool formation. 3. Comprehensive gas-rock correlation says that natural gases of north, west, south of middle gas field of basin mainly come from lower Paleozoic source rocks. The attribution ratio of lower Paleozoic source rocks is 60%-70%. Natural gases of other areas mainly come from upper Paleozoic. The attribution ratio of upper Paleozoic source rocks is 70%. 4. Paleozoic gases migration phase of Erdos basin are also interesting. The relative abundance of gasoline aromatic is quite low especially toluene that of which is divided by that of methyl-cyclohexane is less than 0.2 in upper Paleozoic gas pool. The migration phase of upper Paleozoic gas may be aqueous phase. By comparison, the relative abundance of gasoline aromatic is higher in lower Paleozoic gas. The distribution character of gasoline gas is similar with that in source rock thermal simulation. The migration phase of it may be free phase. IH Comprehensive gas-rock correlation is also processed in Kuche depression Tarim basin. The mechanism of gas formation is probed and the gas formation model has been built up. Four conclusions list below. 1. Gases in Kuche depression come from Triassic-Jurassic coal-measure source rocks. They are high-over maturity. Comparatively, the highest maturity area is Kelasu, next is Dabei area, Yinan area. 2. Kerogen thermal degradation is main reason of the dry gas in Kuche depression. Small part of dry gas comes from oil pyrolysis. VI 3.The K12 natural gas lays out some of hydro-gas character. Oil dissolved in the gas. Hydro-gas is also a factor making the gas drier and carbon isotope composition heavier. 4. The mechanism and genesis of KL2 gas pool list as below. Overpressure has being existed in Triassic-Jurassic source rocks since Keche period. Natural gases were expulsed by episode style from overpressure source rocks. Hetero-face was main migration style of gas, oil and water at that time. The fluids transferred the pressure of source rocks when they migrated and then separated when they got in reservoir. After that, natural gas migrated up and accumulated and formed with the techno-genesis. Tectonic extrusion made the natural gas overpressure continuously. When the pressure was up to the critical pressure, the C6-C7 composition in natural gas changed. The results were that relative abundance of alkane and aromatic decreased while cycloalkane and isoparaffin increased. There was lots of natural gas filling during every tectonic. The main factors of overpressure of natural gas were tectonic extrusion and fluid transferring pressure of source rocks. Well preservation was also important in the KL2 gas pool formation. The reserves of gas can satisfy the need of pipeline where is from west to east. IV A good idea of natural gas migration and accumulation modeling whose apparent character is real core and formation condition is suggested to model the physical process of gas formation. Following is the modeling results. 1. Modeling results prove that the gas accumulation rule under cap layer and gas fraction on migration path. 2. Natural gas migration as free phase is difficult in dense rock. 3. Natural gases accumulated easily in good physical properties reservoirs where are under the plugging layer. Under the condition of that permeability of rock is more than 1 * 10~(-3)μm~(-1), the more better the physical properties and the more bigger pore of rock, the more easier the gas accumulation in there. On the contrary, natural gas canonly migrate further to accumulate in good physical properties of rock. 4. Natural gas migrate up is different from that down. Under the same situation, the amount of gas migration up is lager than that of gas migration down and the distance of migration up is 3 times as that of migration down. 5. After gas leaks from dense confining layer, the ability of its dynamic plug-back decreased apparently. Gas lost from these arils easily. These confining layer can confine again only after geology condition changes. 6. Water-wetted and capillary-blocking rocks can't block water but gases generally. The result is that water can migrate continuously through blocking rocks but the gases stay under the blocking rocks then form in there. The experiments have proved the formation model of deep basin gas.

职业倦怠与自我和谐、人际信任的关系研究：中学校长与一般教师的对比

Job Burnout has been a focus of the Occupational Stress Research. As a typical,helping occupation, teacher has attracted widely attention and researches in the areas of pedagogy and psychology. The special subgroup of teacher, headmasters who are the elites of the Basic Education, is ignored. The research about principals’ Job Burnout is nearly blank after analyzing related documents and information. With the development of the society, people pay more and more attention to the education and put more demands on the headmasters, especially middle-school principals. They are required not only to be good educators, who are equipped with all the inner qualities as a teacher, but also good managers. So the main purpose of this research was to compare the principal group with ordinary teacher group, and reveal underling factors, such as background variables and psychological protection variables. A representative sample of Wenzhou middle school principals sized 192 and a sample of middle school teacher sized 302 were sampled from various schools. The educational version of burnout inventory, self consistency scale, and interpersonal trust scale were administrated to the two samples, together with some demographic variables of interest. The applicability and equivalence of the three instruments used in this study were checked. Based on well-established reliability and cross-sample congruence of measures, the difference between principals and teachers was test. Then the contributing factors were analysis gradually. The five background variables were examined one by one in the two samples separately. A multiple covariance analysis was conducted to test whether there remained any difference between these two samples on the variables of interest. Regression analysis was used to further control the effect of self harmony and interpersonal trust to test the difference between two samples. Mediating analysis was conducted to build the relationship among the three constructs. The main results of the research were stated as following: 1. The internal consistency coefficients of all the scales were good, and no difference exited between the two groups. The measurement equivalence of three instruments was established well. The measures could be applied to and comparing the two samples. 2. The self-harmony, and interpersonal trust of principals were better than the ordinary middle-school teachers. Job Burnout of principals was significant lower than teachers. 3. Demographic variables like the gender, age groups, income levels, disricts, and the type of school, were important influencing factors. The difference patterns of the variables on these five variables in two samples had similarity and distinction. 4. After controlling the background variables, there remained significant difference between principals and teachers on the variables of interest. 5. Job Burnout negatively correlated with self-harmony and interpersonal trust. That is to say，the lower the degree of self-harmony and interpersonal are, the serious of the Job Burnout is, The correlation between the self-harmony and the interpersonal trust was positive. 6. After statistically controlling the background variables and psychological variables, there still exited significant difference between two groups of this study. Also, self harmony and interpersonal trust were significant protection predictors to different aspect of job burnout. 7. Mediating analysis was conducted to the residual score of the three constructs after controlling the five variables and group membership. Self harmony partially mediated the relationship between interpersonal trust and job burnout. That is, interpersonal trust had indirect effect to burnout mediated by self harmony, also had direct effect to burnout.