煤油-氢双燃料超音速燃烧研究

本课题进行了“煤油一氢”双燃料超音速燃烧的实验研究，采用一维近似计算程序对实验数据进行处理，对此一维程序所用模型也作了说明。实验采用“煤油一氢”双燃料超音速燃烧方案，即利用少量的氢与来流空气自然形成引导火焰与煤油进行混合燃烧。实验是在超单速燃烧实验台上进行的，实验空气总温1800K左右、总压17atm左右，燃烧室进口M为2.5，可以模拟飞行M数为7的超燃冲压发动机中的燃烧工况。在没有附加点火的情况下，能实现煤油一氢双燃料自点火并维持稳定燃烧的条件包括：氢的最小当量比、燃料的喷注方式与燃烧室几何形状等。因此，本实验进行了四方面的研究内容：（1）氢气当量比对点火极限的影响；（2）煤油驱动气压力对点火极限的影响；（3）不同凹槽形火焰稳定器对燃烧的影响，包括改变凹槽形状和改变喷油孔的位置；（4）实验空气总温对燃烧的影响。用一维超音速燃烧程序对实验数据进行了处理，实验结果表明，通过合理地控制氢气当量比、煤油当量比，在一定的总温总压条件下，利用合适的火焰稳定器，采用煤油一氢双燃料超音速燃烧方案实施煤油的超单速燃烧是可行的，其中凹槽形火焰稳定器对点火与燃烧有重要的作用。本实验研究表明，氢气当量比的最低极限为0.09左右，来流总温最低生在1710K时煤油仍能点燃。实验结果说明，煤油一氢双燃料超音速燃料超烯冲压发动机来说，煤油一氢双燃料超音速燃烧的氢量可以控制在较低的范围，并且来流温度要求不是很高，因此对于碳氢燃料超燃冲压发动机来说，煤油一氢双燃料超音速燃烧方案具有较为实用的价值。

A load simulation method of piezoelectric actuator in FEM for smart structures

More and more piezoelectric materials and structures have been used for structure control in aviation and aerospace industry. More efficient and convenient computation method for large complex structure with piezoelectric actuation devices is required. A load simulation method of piezoelectric actuation is presented in this paper. By this method, the freedom degree of finite element simulation is significantly reduced, the difficulty in defining in-plane voltage for multi-layers piezoelectric composite is overcome and the transfer computation between material main direction and the element main direction is simplified. The concept of simulation load is comprehensible and suitable for engineers of structure strength in shape and vibration control, thereby is valuable for promoting the application of piezoelectric material and structures in practical aviation and aerospace fields.

超临界压力下航空煤油水平管内对流换热特性数值研究

采用RNG(renormalization group)k-ε湍流模型和近壁区的Wolfstein一方程模型对超临界压力下大庆RP-3航空煤油在水平圆管内的流动和换热特性进行了数值研究.超临界压力下,由于航空煤油在拟临界点附近热物性的剧烈变化,浮升力将引起显著的二次流动.二次流动使得水平圆管的下表面湍流强度和对流换热增强,而上表面的湍流强度和对流换热减弱.最后分析了两种水平管内对流换热受浮升力影响判别标准在超临界流体中的适用性

Extraction and separation of yttrium from the rare earths with sec-octylphenoxy acetic acid in chloride media

Extraction and separation of yttrium from the rare earths in chloride medium using sec-octylphenoxy acetic acid (CA-12), tri-n-butyl phosphate (TBP) as modifier, in kerosene has been investigated. The separation coefficients, beta, were obtained and the extraction selectivity has been enhanced when compared with that of naphthenic acid. The experimental results indicated that CA-12-TBP system could be employed to separate yttrium, from rare earths. Fractional extraction (15 stages for extraction and 10 stages for scrubbing) was studied, the raffinate of the first stage was abundant in purity yttrium of 99.5%, with a yield of > 95%, percentage of yttrium in the mixture rare earths was less than 5% in the loaded organic phase of the 25th stage and loaded capability was about 0.2 mol/L.

Interfacial activity of sec-nonylphenoxy acetic acid and kinetics of yttrium extraction

The interfacial behavior of sec-nonylphenoxy acetic acid (CA-100) at various diluents/(H, Na)Cl interfaces was examined using the Du Nouy ring method. Different adsorption isotherms such as the Gibbs and Szyszkowski were in good agreement with the experimental data. The values of interfacial excess at saturated interface increase in the following order: n-heptane > kerosene > cyclohexane > CCl4 > toluene > benzene > chloroform. The effects of temperature, acidity, and ionic strength of the aqueous phase on the interfacial activity of CA- 100 were also examined. The interfacial-activity data were used to discuss the mechanism and kinetics of yttrium (Y) extraction.

Study on transfer and interfacial kinetics of neodymium and samarium in membrane based extraction

Extraction and interfacial kinetics of Nd3+ and Sm3+ with HER/EHP-kerosene in a hollow fiber membrane extractor were studied. The results show that the extraction reactions in the hollow fiber membrane extractor are the same as those in the liquid-liquid extraction, which can be expressed as a quasi-first-order reaction. The effect of acidity in aqueous phase, concentrations of extractant, Nd3+ and Sm3+ on extraction rate were discussed and the corresponding reaction series were obtained. The reaction equations, reaction rate constants and the separation constant were obtained.

Studies on extraction and mass transfer of samarium and neodymium in hollow fiber membrane (HFM) with HEH/EHP

The membranes of polyvinylidene fluoride, which were synthesized by our laboratory, were used to study the transfer and extraction performances of Nd(III) and Sm(III) with the extraction system of HEH/EHP-kerosene. The results show that the membrane material was suitable to the study on membrane extraction, and could offer a good transfer performance in the membrane construction parameters selected, The extraction reaction in the membrane module was the same as that in liquid-liquid process, HEH/EHP ammoniated for increasing the mass transfer coefficient was almost the same with increasing the concentration of HEH/EHP, and H+ was still transferred first at higher pH range of feed solution when HEH/EHP was ammoniated, The controlling model of the membrane extraction process was the diffusion model accompanied by interfacial reaction, The controlling function of interfacial reaction would increase gradually with the increasing of the membrane pore size. The mass transfer coefficient increased when extraction and stripping were carried out simultaneously.

激光焊接技术与航空制造

激光焊接能够实现多种类型材料的连接,而且具有许多其他熔焊工艺无法比拟的优越性,未来航空工业将是激光焊接技术应用的一个重要领域。

石油二次运移的物理与数值模拟实验及其应用

Facing the problems met in studies on predominant hydrocarbon migration pathways, experiments and numerical simulating were done in this thesis work to discuss the migration mechanisms. The aim is to analyze quantitatively the pathway pattern in basin scale and to estimate the hydrocarbon loss on the pathway that offer useful information for confirming the potential hydrocarbon accumulation. Based on our understandings on hydrocarbon migration and the fluid dynamic theory, a series of migration experiments were designed to observe the phenomena where kerosene is used as draining phase driven only by buoyancy force that expulses pore water. These experiments allow to study the formation of migration pathways, the distribution of non-wetting oil along these pathways, and the re-utilizing of previously existing pathways marked by residual traces etc. The types of pattern for migration pathways may be characterized by a phase diagram using two dimensionless numbers: the capillary number and the Bond number. The NMR technique is used to measure the average saturation of residual oil within the pathways. Based our experiment works and percolation concept, a numerical simulation model were proposed and realized. This model is therefore called as BP (Buoyancy Percolation) simulator, since buoyancy is taken as the main driving force in hydrocarbon migration. To make sure that BP model is applicable to simulate the process of oil secondary migration, the experimental phenomena are compared with those simulated with BP model by fractal method, and the result is positive. After then, we use BP simulator to simulate the process of migration of oil in the porous media saturated with water at different scale. And the results seem similar to those cited in literatures. In addition, our software is applied in Paris basin to predict the pathway of hydrocarbon migration happened in the Middle Jurassic reservoirs. It is found that the results obtained with our BP model are generally agree with Hindle (1997) and Bekeles'(1999), but our simulated migration pathway pattern and migration direction seem more reasonable than theirs.

员工的组织支持感和工作压力对工作结果变量的作用——中国民航管制员研究

Both perceived organizational support and job stresses have impact on employees’ work outcomes. Great progresses have been made in past researches. However, there are many disputes about the impact of perceived organizational support (POS) on job performance (especially, safety performance), the impact of job stresses on job performance (especially, safety performance) and job attitudes, as well as the interaction of subordinates’ POS and job stresses, and the impact of supervisor on subordinates’ POS et al.. Thus, the aim of the study is to explore the impact of supervisors’ POS, leader-member exchange(LMX) on subordinates’ POS, the direct impact of subordinates’ POS and job stressors from task and rewards on work attitudes(job satisfaction, turnover intention) and safety behaviors(safety compliance and safety participation), and the interaction of subordinates’ POS and job stresses. Analyses are based on the data from interviewing of 20 staff, posts of a Chinese civil aviation Bulletin Board System (BBS) and surveys of 216 subordinates and 42 supervisors from two Chinese civil aviation Air traffic control centers (ATC). The major findings are listed as follows: Firstly, the exchange relationship between supervisors and members has impact on subordinates’ POS by the fully mediating role of subordinates’ perceived supervisor support (PSS). But supervisors’ POS have no impact on subordinates’ POS. Secondly, subordinates’ POS has a direct and positive impact on their job satisfaction and safety behaviors, and a negative impact on turnover intention. Specifically, the higher the employees’ perceived organizational support, the higher job satisfaction and safety behaviors, as well as the lower turnover intention they have. Moreover, POS has stronger relationship with safety participation behaviors than that of safety compliance behaviors. Thirdly, task-related stressor has no significant impact on job satisfaction, turnover intention and safety behaviors. And compensation-related stressor has significant and positive impact on turnover intention and safety behaviors, which means that with the compensation-related stress increases, turnover intention increases, safety behaviors including safety compliance and safety participation also increases. Fourthly, POS and task-related stressor, POS and compensation-related stressor have significant interaction, respectively. Specifically, POS moderates the relationship between task-related stressor and job satisfaction, and between task-related stressor and turnover intention. Moreover, POS also moderates the relationship between compensation-related stressor and safety compliance behaviors.