Thermokinetic investigation of effect of temperature on optimum NaCl concentration for petroleum bacterial growth

The power-time curves of growth of three strains of petroleum bacteria at different NaCl concentrations at 40.0 and 50.0 degreesC have been determined by using a 2277 Thermometric Thermal Activity Analyser. An equation of a power-time curve, ln[alphaP(K)/P(t) - 1] = ln[(alphaK - N-0)/N-0] - alphakt, was established based on the generalized logistic equation, where P(t) is the thermal power at time t, K the carrying capacity, P-K = P0K, P-0 the thermal power of one cell, N-0 the bacterial population at time zero, alpha = (k - D)/k. The method of four observed points with the same time interval was used to calculate the value of P-K. The growth rate constant k and the death rate constant D were calculated. The NaCl concentration of optimum growth rate of petroleum bacteria at 40.0 and 50.0 degreesC, respectively, have been obtained according to the curves k - D versus NaCl concentration, which are 0.26, 0.54 and 0.57 mol l(-1) for B-1, B-2 and B-3, respectively, at 50.0 degreesC, 0.26, 0.55 and 0.56 mol l(-1) for B-1, B-2 and B-3, respectively, at 40.0 degreesC. The results indicated that the effect of temperature on NaCl concentration of optimum growth rate was small. (C) 2002 Elsevier Science B.V. All rights reserved.

On-line voltammetric monitoring of dissolved Cu and Ni in the Gulf of Cadiz, south-west Spain

Geochemical processes in estuarine and coastal waters often occur on temporally and spatially small scales, resulting in variability of metal speciation and dissolved concentrations. Thus, surveys, which are aimed to improve our understanding of metal behaviour in such systems, benefit from high-resolution, interactive sampling campaigns. The present paper discusses a high-resolution approach to coastal monitoring, with the application of an automated voltammetric metal analyser for on-line measurements of dissolved trace metals in the Gulf of Cadiz, south-west Spain. This coastal sea receives metal-rich inputs from a metalliferous mining area, mainly via the Huelva estuary. On-line measurements of dissolved Cu, Zn, Ni and Co were carried out on-board ship during an eight-day sampling campaign in the study area in June 1997. A pumping system operated continuously underway and provided sampled water from a depth of ca. 4 m. Total dissolved metal concentrations measured on-line in the Gulf of Cadiz ranged between <5 nM Cu (<3 nM Ni) ca. 50 km off-shore and 60–90 nM Cu (5–13 nM Ni) in the vicinity of the Huelva estuary. The survey revealed steep gradients and strong tidal variability in the dissolved metal plume extending from the Huelva estuary into the Gulf of Cadiz. Further on-line measurements were carried out with the automatic metal monitor from the bank of the Odiel estuary over a full tidal cycle, at dissolved metal concentrations in the μM range. The application confirmed the suitability of the automated metal monitor for coastal sampling, and demonstrated its adaptability to a wide range of environmental conditions in the dynamic waters of estuaries and coastal seas. The near-real time acquisition of dissolved metal concentrations at high resolution enabled an interactive sampling campaign and therefore the close investigation of tidal variability in the development of the Huelva estuary metal plume.

农药对土壤脲酶活性的影响

通过模拟方法,研究了豆磺隆和呋喃丹对草甸棕壤和黑土6个土样脲酶活性的影响.结果表明,在供试浓度范围内,两种农药对土壤脲酶均有不同程度的激活作用,其中豆磺隆对草甸棕壤和黑土脲酶活性的最大增幅分别为46.95%和39.36%,呋喃丹分别为21.08%和12.70%.豆磺隆和呋喃丹浓度与土壤脲酶活性之间用二元一次方程拟和效果较好,分别有5个和3个土样的方程达到了显著或极显著相关水平,且二次项系数为负,总体上表现为先增加后降低的规律性变化.从两种农药对土壤脲酶的增幅和方程系数来看,豆磺隆对土壤脲酶活性的影响比呋喃丹明显.

A method for quantitative analysis of nitrogen oxides and N2 by means of mass spectrometry with the assistance of a catalytic technique for the reduction of NO with CO or hydrocarbons

Mass spectrometry is not able to differentiate NOx and N2 from other interferences (e.g. CO and C2H4) in the deNOx reactions. In the present study, a quantitative method for analysis of NOx and N2 simultaneously in these reactions with an assisted converter operated at higher temperature under O2-rich condition, which eliminates the interferences, is developed. The NOx conversion from this method is comparable to the one from an Automotive Emission Analyser equipped with NOx electrochemical sensor. Two types of deNOx reactions are tested in terms of selectivity of N2 production. The application of this method is discussed.

Miscibility and crystallization behavior of PBT/epoxy blends

The miscibility and the isothermal crystallization kinetics for PBT/Epoxy blends have been studied by using differential scanning calorimetry, and several kinetic analyses have been used to describe the crystallization process. The Avrami exponents n were obtained for PBT/Epoxy blends. An addition of small amount of epoxy resin (3%) leads to an increase in the number of effective nuclei, thus resulting in an increase in crystallization rate and a stronger trend of instantaneous three-dimensional growth. For isothermal crystallization, crystallization parameter analysis showed that epoxy particles could act as effective nucleating agents, accelerating the crystallization of PBT component in the PBT/Epoxy blends. The Lauritzen-Hoffman equation for DSC isothermal crystallization data revealed that PBT/Epoxy 97/3 had lower nucleation constant K, than 100/0, 93/7, and 90/10 PBT/Epoxy blends. Analysis of the crystallization data of PBT/Epoxy blends showed that crystallization occurs in regime II. The fold surface free energy, sigma(e) = 101.7-58.0 x 10(-3) J/m(2), and work of chain folding, q = 5.79-3.30 kcal/mol, were determined. The equilibrium melting point depressions of PBT/Epoxy blends were observed and the Flory-Huggins interaction parameters were obtained.

Infrared spectrum of 2-octadecyl-7,7,8,8-tetracyanoquinodimethane

Infrared spectrum of 2-octadecyl-7,7,8,8-tetracyanoquinodimethane was dealt with 2nd-derivative and deconvolution methods. It was first discovered that the band near 2849 cm(-1) assigned to the CH2 Symmetric stretching mode splited into two bands and this splitting might result from the coexistence of two kinds of conformations of CH2 in the hydrocarbon chain.

2-十八烷基四氰代二甲基苯醌的红外光谱

采用二次微分和解卷积法 ,对 2 十八烷基TCNQ的红外光谱数据进行处理 ,首次发现长碳链中CH2对称伸缩振动的分峰现象 ,并将CH2 对称和反对称伸缩振动的分裂归结为是由十八烷基TCNQ分子中碳氢链的不同构象所产生的

A study of the crystallographic equivalence of ether and ketone groups in poly(aryl ether ketone)s

Crystallographic equivalence of ether and ketone in all para-substituted PAEKs crystallized in form I was discussed in this paper. In a word, crystallographic equivalence between ether and ketone groups is tenable when polymer contains only phenyl rings in the repeat unit. If a polymer contains a diphenyl group in the repeat unit, two cases should be distinguished. In the case of PEDEKK and PEEKDK, crystallographic equivalence between ether and ketone linkages is untenable, However, in the case of PEDK and PEDEKDK, crystallographic equivalence between ether and ketone linkages is still tenable.

Studies on morphology and crystallization of polypropylene/polyamide 12 blends

Scanning electron microscopy (SEM) and an image analyser are used to study morphologies of the fractured surface, etched by hot phenol, of polypropylene/maleated polypropylene/polyamide 12 PP/PP-MA/PA12) = 65/10/25 blend and PP-MA/PA12 = 75/25 blend. The particle dimension and its distribution of PA12 dispersed phase in these blends are much lower and narrower than that of the PP/PA12. blends. Especially, most of the particles in the PP-MA/PA12 = 75/25 blend are smaller than 0.1 mu m. The effect of the morphology of PP/PA12 blends on their crystallization behaviour is studied using differential scanning calorimetry and SEM. PA12 dispersed phase coarsens during annealing in the PP/PP-MA/PA12 = 65/10/25 blend. The mechanism of coarsening of the PA12 dispersed phase is a coalescence process. The intense mixing between the PP component and the PA12 component through reaction of PP-MA and PA12 leads to a change of dynamic mechanical behaviour of the components. A separation method is used to separate the polyolefin parts (precipitated from hot phenol), from PA12 parts (hot phenol filtrate). Of PP/PP-MA/PA12 = 65/10/25 blend, infra-red measurements and elementary analysis show that the precipitate has a lower PA12 content than the feed, whereas the filtrate has a higher PA12 content. From PP-MA/PA12 = 75/25 blend, PA12 contents in the precipitate and the filtrate are the same as in the feed. This implies that all PA12 has reacted with all PP-MA in the latter case while not in the former case. Using the method of interface exposure, interfacial reaction of PP-MA with PA12 is studied by X-ray photoelectron spectrometry (X.p.s.). Copyright (C) 1996 Elsevier Science Ltd.

导电聚哒嗪的电化学合成与表征

本工作用循环伏安法研究了哒嗪的电化学氧化聚合过程以及聚哒嗪的电化学行为,合成了电导率约为1s/cm的聚哒嗪,并采用光谱、能谱方法对它进行了表征,FTIR谱表明聚哒嗪中3,6-二取代哒嗪结构引起的吸收带位于1330,1120,1100和840cm~(-1),掺杂聚哒嗪的双极子能带的两个光吸收峰分别位于1.8,0.9eV。

热带印度洋低频Rossby波及其对上层热结构的影响

Rossby波是地球物理流体动力学中非常重要的一种波动，海洋斜压长Rossby波在海洋动力过程中起着相当重要的作用。它维持并影响强西边界流，是海盆内能量传播的主要机制，它所携带的变异信号从大洋的东边界传播到内部，对海气耦合系统起到很重要的作用。热带印度洋是季风爆发的源地，对季风的年际变化具有重要影响。研究热带印度洋对理解季风变率和提高季风预测水平有重要的科学和应用价值。 本文利用TOPEX/Poseidon等高度计资料、美国国家海洋数据中心（NODC）的世界海洋图集（WOA05）长期气候态水文资料、美国Scripps海洋研究所的上层海温资料、中国Argo资料中心提供的Argo资料、美国国家环境预测中心（NCEP）的海表面温度、FSU（Florida State University）月平均风场和海气界面热通量等观测数据，全面分析了热带印度洋低频Rossby波的基本特征，并深入研究了低频Rossby波的生成机制及其对上层海洋热结构的影响。 采用相关分析等统计方法，结合1.5层约化重力模式，研究了热带南印度洋低频Rossby波的生成机制。结果表明： （1）热带南印度洋低频Rossby波分为东边界扰动产生的Rossby波和南印度洋中部风强迫Rossby波；东边界激发的为自由Rossby波，沿12°S波速大约13 cm/s，向西最远传播到80°E左右，之后被局地变量调整；强迫Rossby波在西传的过程中不断加强，波速较快，沿12°S能超过20 cm/s； （2）东边界扰动由印度尼西亚贯通流（ITF）导致的地转调整过程引起；内区风强迫Rossby波生成和加强的关键区为（70°E–95°E，15°S–5°S）；显著的西传Rossby波同太平洋上的厄尔尼诺/南方涛动（ENSO）事件紧密相连，ENSO通过大气的遥驱动机制激发热带南印度洋低频Rossby波； （3）作为东边界低频变量扰动的一个重要因子，ITF的变化与ENSO事件密切相关，总的来讲，El Niño年ITF偏弱，La Niña年ITF偏强，这与前人的研究结果一致；但它在ENSO的不同位相时期，存在一定差异，并具有夏季锁相特征：El Niño事件发生年的春季到秋季，ITF偏强，夏季最强；从El Niño盛期（冬季）到次年秋季，ITF持续偏弱，夏季最弱。上述夏季锁相特征与夏季风的强弱变化相对应。La Niña期间情况相反。 西南印度洋（SWIO）（50°E–75°E，15°S–5°S）以及苏门答腊-爪哇沿岸地区是海表面高度异常（SSHA）和海表面温度异常（SSTA）相关显著的区域，表明内部海洋动力过程在次表层和表层变量的相互关系中起重要作用。本文以2006–2008年期间三个连续的同El Niño或者La Niña同时发生的正印度洋偶极子（IOD）事件为背景，基于Argo观测资料研究了表层和次表层IOD的演变以及二者的区别和联系，并首次采用垂直模态分解方法探讨了Rossby波对上层海洋热力结构影响的动力学特征，得到如下主要结论： （1）在热带印度洋，海洋动力过程一般主要由第一和第二低阶垂直斜压模态控制，而第一斜压模态处于主导地位——在SWIO海区，第一斜压模态运动的方差解释率为第二模态的2–3倍，在赤道和东南印度洋也达到2倍左右；另外，赤道印度洋地区高阶斜压模态运动对该地区的海洋动力过程也具有一定的贡献； （2）低频斜压Rossby波能影响海洋的垂直层结，尤其是强暖Rossby波使同第二斜压模态运动紧密相连的海洋上层层结减弱，加强第二斜压模态的贡献量，导致上层各等压线向下垂直位移增大，最终通过垂直混合过程调整上层海洋的热力结构；而低频斜压冷Rossby波会加强上层垂直层结，抑制该层内变量变化，因此第二斜压模态的贡献依然很小； （3）表层IOD和次表层IOD分布形态不同：表层东部冷异常主要集中在东南印度洋Sumatra-Java沿岸，次表层冷异常基本关于赤道对称；表层西部暖异常基本关于赤道对称，而在次表层赤道以南海温扰动强度远远大于赤道以北； （4）正IOD事件中，东南印度洋冷SSTA首先出现于Java沿岸，沿岸东南风引起的潜热释放增加以及沿岸上升流是该初始冷异常建立的主要机制，与之相关的SSTA东西梯度加强大气环流变化，并进一步强迫随后的海洋运动；1–2个月后，SST冷异常中心北跳到Sumatra沿岸并向西扩展，同时不断增强，其中Sumatra沿岸上升流、来自赤道印度洋的冷Kelvin波及其反射的西传冷Rossby波是这一演变过程的动力机制，而沿岸上升流起决定作用。