~(20)Na的β~+延发α粒子测量

利用兰州放射性次级束流线提供的2 0 Na束流 ,通过2 0 Na β+2 0 Ne →16 O+α过程 ,测量了2 0 Na的衰变半衰期T1/2 及衰变α粒子能谱 .结果表明 ,除了Ed≥ 2 .688MeV的 9条较高激发能级的衰变α粒子外 ,实验中还观察到衰变能量Ed 为 0 .890和 1 .0 54MeV ,1 .991MeV ,2 .4 2 4和 2 .4 57MeV的2 0 Ne低激发能级的 3条α谱线 .

Retrieval of Electron Return Time from High-order Harmonics Generated in a Mixture of He and Ne Gases

In terms of single-atom induced dipole moment by Lewenstein model, we present the macroscopic high-order harmonic generation from mixed He and Ne gases with different mixture ratios by solving three-dimensional Maxwell's equation of harmonic field. And then we show the validity of mixture formulation by Wagner et al. [Phys. Rev. A 76 (2007) 061403(R)] in macroscopic response level. Finally, using least squares fitting we retrieve the electron return time of short trajectory by formulation in Kanai et al. [Phys. Rev. Lett. 98 (2007) 153904] when the gas jet is put after the laser focus.

Characterization of metal-containing molecular sieves and their catalytic properties in the selective oxidation of cyclohexane

Three types of metal-containing molecular sieves with AFI, AEL and CHA structures (Me = Co, Mn, Cr and V) were synthesized hydrothermally and characterized by XRD, XRF, TG, TPR, NH3-TPD and FT-IR. It was revealed that metals were incorporated into the framework of molecular sieves and induced the presence of charge centers. Both cobalt and manganese in the framework of AIPO-5, AlPO-11 and SAPO-34 were not reducible before the structure collapse. The redox behaviours of these catalysts in cyclohexane oxidation at 403 K using O-2 as oxidant were examined. CoAPO-11 exhibited best activity and good selectivities for the monofunctional oxidation products (88.5%). Cyclohexanol was the major product over most catalysts, whereas for Cr-containing molecular sieves, high selectivity of cyclohexanone was observed. Investigation of reaction mechanism based on CoAPO-11 and CrAPO-5 catalysts indicated that the decomposition of cyclohexyl hydroperoxide (CHHP), the intermediate in cyclohexane oxidation, followed the pathway: cyclohexanone <-- CHHP --> cyclohexanol -->cyclohexanone. (C) 2004 Elsevier B.V. All rights reserved.

东部山区次生林林窗小气候变化动态——以辽东山区次生林人工小林窗为例(英文)

林窗的产生使森林环境发生了变化,进而影响森林生态系统的更新演替。本文选取东北地区具有典型性的次生林生态系统中人工小林窗(林窗直径与边缘木高之比小于0.5)为对象,对林窗内部及其附近林分的光量子通量密度(PPFD),距地面10cm的空气温度,土壤温度和土壤含水量(0-15cm,15-30cm)进行了观测。实验在林窗形成后的第二年进行,时间为2006年5-9月。结果表明:PPFD最高值出现在林窗北部边缘,尤其在生长季初期的五月份最为明显;晴天时PPFD到达最大值的时间较阴天提前;林窗北部的气温较高,南部的气温较低。土壤温度在林窗内变化剧烈,范围为1-8℃,最大值出现在林窗北部,且与气温最大值显著相关(R=0.735,P<0.05)。表层土壤水分高于下层土壤水分,但差异不显著(p>0.05);这主要是受林窗面积和地表植被的影响所致。上述结果表明,辽东山区次生林小林窗光量子最大值出现的位置与以往在北半球林窗观测结果基本一致,但出现最大值的时间在不同的纬度间存在着差异。空气温度和土壤温度的最大值也都出现在林窗北部,体现了光照对温度变化的影响。由于面积因素的影响,七月份温度变化与其它月份不同。土壤水分在雨季和旱季变化不大,这可能与林窗大小和所处地理位置有关。在本次观测的形状不规则小林窗中,小气候因子的变化对物种更新产生怎样的影响,需要开展进一步的研究。图5参44。

论市场经济体制下自然资源的合理利用

论市场经济体制下自然资源的合理利用李法云，范志平（中科院沈阳应用生态研究所）一、计划经济体制下自然资源利用中存在的问题经济社会中的资源配置是指各种生产要素的优化组合，是自然资源与社会资源之间的协调；在计划经济体制下，由于没有形成标志资源稀缺性的合理价...

Europium complexes immobilization on titania via chemical modification of titanium alkoxide

We report a facile strategy to tether lanthanide complexes to organic-inorganic hybrid titania materials via sol-gel processing by employing chemically modified titanium alkoxide as the precursor where the organic ligand sensitizing the luminescence of lanthanide ions is bonded to titanium.