45 resultados para 1851-1875


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The medium effect of nucleon-nucleon cross section sigma(med)(NN) (alpha(m)) on the isoscaling parameter a is investigated for two central nuclear reactions Ca-40+Ca-40, Ca-60+Ca-60. within isospin-dependent quantum molecular dynamics at beam energies from 40 to 50 MeV/nucleon. It is found that there is the very obvious medium effects of nucleon-nucleon cross section sigma(med)(NN)(alpha(m)) on the isoscaling parameters a. In this case the isoscaling parameter a is a possible probe of the medium effect of nucleon-nucleon cross section sigma(med)(NN)(alpha(m)) in the heavy ion collisions. The mechanism of the above-mentioned properties is studied and discussed.

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<正>随着我国经济体制改革的不断深入,财会制度改革也不断深化,特别是《中共中央关于制定国民经济和社会发展第十一个五年规划的建议》,明确提出要推进财政税收体制改革,加快公共财政体系建设,继续深化部门预算,国库集中支付,政府采购和收支两条线管理制度改革,随之,我国科研事业单位财会制度改革又有了新的进展。近年来由于国家对科研工作的高度重视,国家对科研项目的投资规模很大。为了保证科研项

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Two kinds of ethylene copolymers with controllable structures were synthesized and the molecular parameters were characterized by FTIR, GPC, H-1 NMR and C-13 NMR systematically. Effects of molecular and the content of branched short chains on the crystalline properties of the resultant ethylene copolymers were investigated by DSC, respectively. First, polybutadienes with M-w ranging from 20000 to 110000, low polydispersity index(PDI = 1.1) and almost the same content of vinyl (molar fraction about 7%) were synthesized by anionic polymerization. After hydrogenation, the melting point and crystallinity of the obtained model ethylene/1-butene copolymers decreased with the increase in M-w of the copolymers.

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Herein, we describe a simple and inexpensive method for forming superhydrophobic cloths with the highest water contact angle of close to 180 degrees, in which normal commercial cloths serving as pristine materials are modified with suitable gold micro/nanostructures.

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A series of monodisperse oligo(9,9-di-n-octylfluorene-2,7-vinylene)s (OFVs) with fluorene units up to 11 has been synthesized following a divergent approach. Chain length was found to affect not only photophysical properties but also thermal properties. Absorption and photoluminescence spectra are red-shifted with increasing chain length. The effective conjugated length has been extrapolated to be as long as 19 fluorene vinylene units, indicative of a well-conjugated system. With the number of fluorene units > 5, the oligomers exhibit nematic mesomorphism. Glass transition temperature (T-g) and clearing point temperature (T-c) increase with increasing molecular length and with those of OFV11 up to 71 and 230 degrees C, respectively. The oligomers can form uniform films by solution casting for fabrication of light-emitting diodes. With a device structure of ITO/ PEDOT:PSS/OFV11/Ca/Al, a current efficiency of 0.8 cd.A(-1) at a brightness of 1300 cd.m(-2) along with a maximum brightness of 2690 cd.m(-2) have been realized. This performance is notably superior to that of the corresponding polymer.

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A Series of novel homo- and copolyimides containing pyridine units were prepared from the heteroaromatic diamines, 2,5-bis (4-aminophenyl) pyridine and 2-(4aminophenyl)-5-aminopyridine, with pyromelltic dianhydride (PMDA), and 3,3',4,4'-biphenyl tertracarboxylic dianhydride (BPDA) via a conventional two-step thermal imidizaton method. The poly(amic acid) precursors have inherent viscosities of 1.60-9.64 dL/g (c = 0.5 g/dL in DMAC, 30 degrees C) and all of them can be cast and thermally converted into flexible and tough polyimide films. All of the polyimides show excellent thermal stability and mechanical properties. The polyimides have 10% weight loss temperature in the range of 548-598 degrees C in air. The glass transition temperatures of the PMDA-based samples are in the range of 395-438 degrees C, while the BPDA-based polyimides show two glass transition temperatures (T(g)1 and T(g)2), ranging from 268 to 353 degrees C and from 395 to 418 degrees C, respectively. The flexible films possess tensile modulus in the range of 3.42-6.39 GPa, strength in the range of 112-363 MPa and an elongation at break in the range of 1.2-69%. The strong reflection peaks in the wide-angle X-ray diffraction patterns indicate that the polyimides have a high packing density and crystallinity.

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The method of creating enriched microsatellite libraries can supply an abundant source of microsatellite sequences at a considerably reduced cost. Here we report the development of 15 polymorphic microsatellite loci from the bay scallop, Argopecten irradians, using enrichment protocol. Polymorphism was assessed in a sample of hatchery population (n = 38) revealing three to seven alleles per locus. The expected and observed heterozygosities ranged from 0.198 to 0.813 and from 0.083 to 0.833, respectively. These markers will be useful for genetic variation monitoring and parentage analysis.

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Seven new cadinane sesquiterpenes, (-)-(1R,6S,7S,10R)-1-hydroxycadinan-3-en-5-one (1), (+)-(1R,5S,6R,7S, 10R)-cadinan-3-ene-1,5-diol (2), (+)-(1R,5R,6R,7S,10R)-cadinan-3-ene-1,5-diol (3), (+)-(1R,5S,6R,7S,10R)-cadinan-4(11)-ene-1,5-diol (4), (+)-(1R,5R,6R,7R,10R)-cadinan-4(11)-ene-1,5,12-triol (5), (-)-(1R,4R,5S,6R,7S, 10R)-cadinan-1,4,5-triol (6), and (-)-(1R,6R,7S,10R)-11-oxocadinan-4-en-1-ol (7), together with nine known compounds were isolated from the brown alga Dictyopteris divaricata. The structures of the new natural products, as well as their absolute configuration, were established by means of spectroscopic data including IR, HRMS, 1D and 2D NMR, single-crystal X-ray diffraction, and CD. All compounds were inactive against several human cancer cell lines including lung adenocarcinoma (A549), stomach cancer (BGC-823), breast cancer (MCF-7), hepatoma (Bel7402), and colon cancer (HCT-8) cell lines.

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本文通过对指纹模式特点的研究,揭示了同指特征集间的近似仿射变换(?)系,提出了比较度量不变量的指纹比对原理,并借助图进行比对.实验结果表明本文提出的指纹比对方法是可行的.

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地球的大气圈,水圈的形成在太阳系中具有独特性,大气圈,水圈的物质组成呈现阶段性的演化特征。在不同的演化阶段,地球表生地质作用表现出不同的特征和状况,显示出地球大气圈,水圈化学变化对其的控制作用。在长时间尺度范围内,大气和海洋化学变化直接影响表生系统的岩石风化强度和特点,沉积物类型,矿产时空分布规律。在短时间尺度范围内,大气物质组成的变化引起气候变化,间接地,综合地影响和改变表生地质作用的状况,同时,表生地质作用反过来又影响大气圈,水圈的物质组成演化,两者相互作用,相互影响,构成地球表生系统的相互耦合关系。

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通过构造地质学、矿床学、地球化学研究,认为燕山早期环太平洋板块的俯冲碰撞与小江深断裂带、曲靖-昭通隐伏断裂带的左行走滑运动为深源流体的形成和贯入提供了有利的构造背景,成矿物质主要来源于深源流体和蒸发岩层,矿体本身是富含铅锌锗等的成矿流体沿构造贯入的产物,矿床定位直接受北东构造带控制。在此基础上,提出“深源流体贯入-蒸发岩层萃取-构造控制”的成矿模式。