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REE geochemistry data from the Fanshan alunite deposit indicated that its ore-forming materials came chiefly from the country rocks, with δCe〉0 for alunite ores. According to the differences in δEu, the alunite ores were divided into three types: weak negative Eu anomaly, weak positive Eu anomaly and remarkable positive Eu anomaly. The phenomena of Ce-enrichment in the ores indicated that the Fanshan alunite deposit was formed in an oxidizing environment. Variations in fO2 are corresponding to those in δEu: Eu anomaly varies from negative to positive with increasing fO2. And two other important factors may impact the occurrence of Eu anomalies: the contents of alkaline feldspar and the protolith structure in the mineralization period.